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Acta Crystallogr Sect E Struct Rep Online ; 70(Pt 3): o334, 2014 Mar 01.
Article in English | MEDLINE | ID: mdl-24765029

ABSTRACT

The asymmetric unit of the title cyclic thio-urea derivative, C10H12N2S, comprises two mol-ecules, each of which has a twist about the CH2-CH2 bond within the five-membered ring. The major difference between the independent mol-ecules is manifested in the relative orientations of the five- and six-membered rings [dihedral angles between the least-squares planes = 28.03 (11) and 41.54 (11)°]. A network of C-H⋯π inter-actions consolidates the three-dimensional crystal packing.

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