Fluorescence sensing and adsorption kinetics of Gd-doped AgInS2 I-III-VI quantum dots - A case study of Ag+ ions interactions.

The poor fluorescence properties of magneto-fluorescent paramagnetic-ion (Gd, Mn, or Co) doped I-III-VI quantum dots (QDs) at higher paramagnetic-ion doping concentrations have limited their use in magnetic-driven water-based applications. This work presents, for the first time, the use of stable magneto-fluorescent Gd-doped AgInS2 QDs at high Gd mole ratios of 16, 20, and 30 for the fluorescence detection and adsorption of Ag+ ions in water environments. The effect of pH, initial concentration, contact time, and adsorbent dosage were systematically evaluated. The AgInS2 QDs with the least Gd mole ratio (16) exhibited the best fluorescence characteristics (LOD = 0.88, R2 = 0.9549) while all materials showed good adsorption properties under optimized conditions (pH of 2, initial concentration of 30 ppm, contact time of 10 min and adsorbent dosage of 0.02 g) and a pseudo 2nd order reaction was followed. The adsorption mechanism was proposed to be a combination of ion-exchange, electrostatic interaction, complexation, and diffusion processes. Application in environmental wastewater samples revealed complete removal of Ag + ions alongside Ti2+ Pb2+, Ni2+, Cr3+, and Zn2+ ions.

A review on I-III-VI ternary quantum dots for fluorescence detection of heavy metals ions in water: optical properties, synthesis and application.

Heavy metal contamination remains a major threat to the environment. Evaluating the concentrations of heavy metals in water environments is a crucial step towards a viable treatment strategy. Non-cadmium photo-luminescent I-III-VI ternary QDs have attracted increasing attention due to their low toxicity and extraordinary optical properties, which have made them popular in biological applications. Recently, ternary I-III-VI-QDs have gained growing interest as fluorescent detectors of heavy metal ions in water. Here, we review the research progress of ternary I-III-VI QDs for the fluorescence detection of heavy metal ions in water. First, we summarize the optical properties and synthesis methodologies of ternary I-III-VI QDs. Then, we present various detection mechanisms involved in the fluorescence detection of heavy metal ions, which are mostly attributed to direct interaction between these unique QDs and the metal ions, seen in the form of fluorescence quenching and fluorescence enhancement. We also display the potential applications in environmental remediation such as water treatment and associated challenges of I-III-VI QDs in the fluorescence detection of Cu2+ and other metal ions.

Photocatalytic Nanofiber Membranes for the Degradation of Micropollutants and Their Antimicrobial Activity: Recent Advances and Future Prospects.

This review paper systematically evaluates current progress on the development and performance of photocatalytic nanofiber membranes often used in the removal of micropollutants from water systems. It is demonstrated that nanofiber membranes serve as excellent support materials for photocatalytic nanoparticles, leading to nanofiber membranes with enhanced optical properties, as well as improved recovery, recyclability, and reusability. The tremendous performance of photocatalytic membranes is attributed to the photogenerated reactive oxygen species such as hydroxyl radicals, singlet oxygen, and superoxide anion radicals introduced by catalytic nanoparticles such as TiO2 and ZnO upon light irradiation. Hydroxyl radicals are the most reactive species responsible for most of the photodegradation processes of these unwanted pollutants. The review also demonstrates that self-cleaning and antimicrobial nanofiber membranes are useful in the removal of microbial species in water. These unique materials are also applicable in other fields such as wound dressing since the membrane allows for oxygen flow in wounds to heal while antimicrobial agents protect wounds against infections. It is demonstrated that antimicrobial activities against bacteria and photocatalytic degradation of micropollutants significantly reduce membrane fouling. Therefore, the review demonstrates that electrospun photocatalytic nanofiber membranes with antimicrobial activity form efficient cost-effective multifunctional composite materials for the removal of unwanted species in water and for use in various other applications such as filtration, adsorption and electrocatalysis.

Microwave-assisted synthesis of titania-amorphous carbon nanotubes/amorphous nitrogen-doped carbon nanotubes nanohybrids for photocatalytic degradation of textile wastewater.

The synthesis of TiO2 nanohybrids fabricated using amorphous carbon nanotubes (aCNTs) and amorphous nitrogen doped carbon nanotubes (aNCNTs) via a microwave-assisted hydrothermal method is reported. The photocatalytic removal of Reactive Red 120 (RR 120) and organics from industrial textile wastewater using these nanohybrids is discussed. The synthesis process was shown to promote the removal of nano graphitic flakes from the outer walls of the aNCNTs and aCNTs and subsequent incorporation of these carbonaceous materials into TiO2 nanocrystals as such enabling a stronger interaction between the TiO2 and the carbonaceous material. This enabled the production of a surface plasmon resonance on the TiO2 and NTiO2 nanocrystals. The carbon residue was confirmed to be aCNTs and aNCNTs by TGA and DTA analyses. XPS analysis for the TiO2-aNCNT nanohybrids confirmed the C and N doping of TiO2 due to the amorphous residues from the aNCNTs. In addition, XPS and FTIR spectroscopic analysis confirmed the presence of surface oxygen-based groups. TEM micrograph analysis showed that aCNTs and aNCNTs promote the formation of monodispersed and small TiO2 particles; all below 7.4 nm. The NTiO2-aNCNT nanohybrids have the lowest energy band gap at 2.97 eV and the lowest PL intensity. The TiO2-aNCNT nanohybrids had superior adsorptive (98.2%) and photocatalytic (99%) removal for 20 ppm RR 120 dye solution at k 1app 3.44 × 10-2 min-1. Lastly, all the nanohybrids demonstrate the formation of visible-light absorbing intermediates from VAT-dyed textile wastewater. The work demonstrates the possibility of the use of these nanohybrids to derive new products through photocatalytic nanohybrids.

Microwave Irradiation-Assisted Synthesis of Zeolites from Coal Fly Ash: An Optimization Study for a Sustainable and Efficient Production Process.

Class F South African coal fly ash was used as a precursor for the synthesis of zeolite A via complete microwave irradiation. To attain optimal conditions for the synthesis of zeolite A with minimum impurities, the microwave synthesis time, irradiation power, and Si/Al ratio were varied. Sodalite with fly ash phases were obtained when the Si/Al ratio in the coal fly ash was not adjusted and when the microwave irradiated coal fly ash slurry was used instead of the extract solution. Increased microwave irradiation time power and time favored the crystallization of zeolite A phase due to sufficient energy needed to ensure the dissolution of Al and Si from coal fly ash. A Brunauer-Emmett-Teller surface area of 29.54 m2/g and a cation exchange capacity of 3.10 mequiv/g were achieved for zeolite A, suggesting its potential application as an adsorbent and cation exchange material for environmental remediation. Complete microwave irradiation offers a greener approach toward zeolite synthesis from coal fly ash compared to conventional hydrothermal and fusion methods that consume a lot of energy and require longer reaction times.

Poly (ether) sulfone electrospun nanofibrous membranes embedded with graphene oxide quantum dots with antimicrobial activity.

This work describes the development of novel electrospun nanofibrous membranes (ENMs) prepared by embedding graphene oxide quantum dots (GOQDs) into poly (ether) sulfone (PES). FTIR and Raman spectroscopy confirmed the successful incorporation of the GOQDs into the PES membranes. The optimal electrospinning polymer concentration that showed no defects or bead formation was at 26 wt% of the PES polymer. Spectroscopy, microscopy and contact angle were some of the techniques used to characterize the ENMs. SEM images showed smooth and unbranched ENMs. The average diameter upon incorporation of the GOQDs was determined to be 2.45 µm. XRD revealed that the GOQDs were structurally close to graphite with an interlaying space of 0.36 nm. The antimicrobial effect of the GOQDs-PES electrospun nanofibrous membranes was assessed against three bacterial strains (Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) and Bacillus cereus (B. cereus)) using the disc diffusion method. The electrospun nanofibres containing 10 wt% of GOQDs showed the most active antimicrobial activity against all three bacterial strains tested. The zones of inhibition ranged from 9 to 40 mm. The minimum inhibitory concentration (MIC) was determined to be 0.5 mg/mL, 0.3 mg/mL and 0.2 mg/mL for E. coli, B. cereus and S. aureus, respectively. The results demonstrated that incorporating GOQDs in the PES nanofibre gives rise to new antimicrobial properties, and as a result, the GOQDs-PES nanofibrous membrane can be used in antimicrobial applications such as water treatment.

Microwave-assisted synthesis of coal fly ash-based zeolites for removal of ammonium from urine.

Zeolites synthesized from biomass waste materials offer a great opportunity in the sustainable utilization of the waste. In this work, energy-efficient processes (i.e. microwave and ultrasound irradiation) were used to synthesize pure phase sodalite (zeolite) from coal fly ash obtained from a power plant in South Africa. The pure-phase sodalite was obtained with a comparatively higher surface area (16 m2 g-1) and cation exchange capacity (2.92 meq. g-1) with 40 min total reaction time. The removal of ammonium from urine was carried out using (i) the coal fly ash-derived sodalite, (ii) raw coal fly ash and (iii) a commercially available natural zeolite (clinoptilolite). The pure phase sodalite exhibited the highest removal efficiency of about 82% and 73% in synthetic and real hydrolyzed urine respectively. The adsorption process followed the pseudo second-order kinetic model and the Freundlich adsorption isotherm, indicating that the adsorption process occurred on a heterogeneous surface.

Mechanistic pathways for the degradation of SMX drug and floatation of degraded products using F-Pt co-doped TiO2 photocatalysts.

This work presents smart pathways to enhance the photocatalytic activity of TiO2 via co-doping with fluorine (F) and platinum (Pt) to form F-Pt co-doped TiO2 photocatalysts and investigates the unique and unusual fluorination of the floated products. Our investigations indicate that the crystalline structure of the photocatalysts was a mixture of anatase and brookite phases and that the nanoparticles of the synthesized nanocomposites had nanometric sizes (4-25 nm). The F-Pt co-doped TiO2 nano-photocatalysts demonstrated degradation of sulfamethoxazole (SMX) drug of >93% within 90 min under direct solar light and 58% degradation within 360 min under a solar simulator. Thus, co-doping TiO2 with F and Pt atoms to form F-Pt co-doped TiO2 nanocomposite is an efficient pathway to achieve high photocatalytic performance escorted with the formation of floating metal-fluoropolymer, unlike pristine TiO2 which has less photocatalytic degradation and no generation of a floating polymer. Our photocatalytic protocol demonstrates that the degradation of SMX started with redox reactions of oxygen and water absorbed on the surface of the prepared nanocomposites to form superoxide anions (O2˙-) and hydroxy radicals (˙OH) which have oxidation superpower. The resultant products were subsequently fluorinated by fluoride radical ions and floated as metal-fluoropolymer.

Fluoride removal studies using virgin and Ti (IV)-modified Musa paradisiaca (plantain pseudo-stem) carbons.

The preparation of carbons in virgin and Ti-modified forms under controlled conditions at low temperature from plantain pseudo-stem (Musa paradisiaca) was achieved. These prepared carbons were characterized for instrumental studies such as BET, FTIR, XRD, SEM with EDS and TGA to understand the chemistry and modification. The determination of IEP and pHZPC established the presence of positive surface sites on the virgin (VMPC) and Ti-modified (TiMPC) carbons to facilitate the sorption of fluoride. The fluoride removal efficiency as a function of time, pH, dose, initial fluoride concentration, temperature, and co-ion intervention was studied. The maximum fluoride removal of about 81.2 and 97.7% was achievable with VMPC and TiMPC, respectively, after 20 min at the pH of 2.04 and continued for the equilibrium of 60 min. Temperature was found to be influential both by way of initial increase followed by a decrease in the fluoride uptake of MPCs. Regeneration was very consistent up to 7 cycles with the residual fluoride concentration below the WHO guide line of 1.5 mg L-1. Highest intervention due to hydrogen carbonate ions was observed during the fluoride removal process. Kinetic (pseudo-first-order, pseudo-second-order, and intra-particle diffusion) and isotherm models (Langmuir, Freundlich, and DKR) were checked for their compliance with the present sorption system. These low temperature synthesized MPCs are found to be effective candidates in the process of fluoride abatement in water.

Facile Synthesis of Nitrogen Doped Graphene Oxide from Graphite Flakes and Powders: A Comparison of Their Surface Chemistry.

Nitrogen-doped graphene oxide (NGO) nanosheets were prepared via a facile one-pot modified Hummer's approach at low temperatures using graphite powder and flakes as starting materials in the presence of a nitrogen precursor. It was found that the morphology, structure, composition and surface chemistry of the NGO nanosheets depended on the nature of the graphite precursor used. GO nanosheets doped with nitrogen atoms exhibited a unique structure with few thin layers and wrinkled sheets, high porosity and structural defects. NGO sheets made from graphite powder (NGOp) exhibited excellent thermal stability and remarkably high surface area (up to 240.53 m2 ·g-1) compared to NGO sheets made from graphite flakes (NGOf) which degraded at low temperatures and had an average surface area of 24.70 m2 ·g-1. NGOf sheets had a size range of 850 to 2200 nm while NGOp sheets demonstrated obviously small sizes (460-1600 nm) even when exposed to different pH conditions. The NGO nanosheets exhibited negatively charged surfaces in a wide pH range (1 to 12) and were found to be stable above pH 6. In addition, graphite flakes were found to be more suitable for the production of NGO as they produced high N-doping levels (0.65 to 1.29 at.%) compared to graphite powders (0.30 to 0.35 at.%). This study further demonstrates that by adjusting the amount of N source in the host GO, one can tailor its thermal stability, surface morphology, surface chemistry and surface area.

The Occurrence and Diversity of Waterborne Fungi in African Aquatic Systems: Their Impact on Water Quality and Human Health.

Currently, there is a worldwide growing interest in the occurrence and diversity of fungi and their secondary metabolites in aquatic systems, especially concerning their role in water quality and human health. However, this concern is hampered by the scant information that is available in the literature about aquatic fungi and how they affect water quality. There are only few published reports that link certain species of aquatic fungi to human health. The common aquatic fungal species that have been reported so far in African aquatic systems belong to the hyphomycetes kingdom. This paper thus aims to survey the information about the occurrence and factors that control the distribution of different species of fungi in African aquatic systems, as well as their effect on water quality and the possible metabolic pathways that lead to the formation of toxic secondary metabolites that are responsible for the deterioration of water quality. This review will also investigate the analytical and bioanalytical procedures that have been reported for the identification of different species of waterborne fungi and their secondary metabolites.