Increasing stratification as observed by satellite sea surface salinity measurements.

Changes in the Earth's water cycle can be estimated by analyzing sea surface salinity. This variable reflects the balance between precipitation and evaporation over the ocean, since the upper layers of the ocean are the most sensitive to atmosphere-ocean interactions. In situ measurements lack spatial and temporal synopticity and are typically acquired at few meters below the surface. Satellite measurements, on the contrary, are synoptic, repetitive and acquired at the surface. Here we show that the satellite-derived sea surface salinity measurements evidence an intensification of the water cycle (the freshest waters become fresher and vice-versa) which is not observed at the in-situ near-surface salinity measurements. The largest positive differences between surface and near-surface salinity trends are located over regions characterized by a decrease in the mixed layer depth and the sea surface wind speed, and an increase in sea surface temperature, which is consistent with an increased stratification of the water column due to global warming. These results highlight the crucial importance of using satellites to unveil critical changes on ocean-atmosphere fluxes.

New Radiometric Approaches to Compute Underwater Irradiances: Potential Applications for High-Resolution and Citizen Science-Based Water Quality Monitoring Programs.

Measuring the diffuse attenuation coefficient (Kd) allows for monitoring the water body's environmental status. This parameter is of particular interest in water quality monitoring programs because it quantifies the presence of light and the euphotic zone's depth. Citizen scientists can meaningfully contribute by monitoring water quality, complementing traditional methods by reducing monitoring costs and significantly improving data coverage, empowering and supporting decision-making. However, the quality of the acquisition of in situ underwater irradiance measurements has some limitations, especially in areas where stratification phenomena occur in the first meters of depth. This vertical layering introduces a gradient of properties in the vertical direction, affecting the associated Kd. To detect and characterize these variations of Kd in the water column, it needs a system of optical sensors, ideally placed in a range of a few cm, improving the low vertical accuracy. Despite that, the problem of self-shading on the instrumentation becomes critical. Here, we introduce a new concept that aims to improve the vertical accuracy of the irradiance measurements: the underwater annular irradiance (Ea). This new concept consists of measuring the irradiance in an annular-shaped distribution. We first compute the optimal annular angle that avoids self-shading and maximizes the light captured by the sensors. Second, we use different scenarios of water types, solar zenith angle, and cloud coverage to assess the robustness of the corresponding diffuse attenuation coefficient, Ka. Finally, we derive empirical functions for computing Kd from Ka. This new concept opens the possibility to a new generation of optical sensors in an annular-shaped distribution which is expected to (a) increase the vertical resolution of the irradiance measurements and (b) be easy to deploy and maintain and thus to be more suitable for citizen scientists.