Fast self-assembly of macroscopic blue phase 3D photonic crystals.

Blue phase (BP) liquid crystals are materials with unique self-assembling properties. They can be regarded as 3D photonic crystals as they organize in 3D cubic structures with sub-micrometer range periodicity and display selective optical bandgaps. Yet, the obtained BP crystals are usually polycrystalline or micrometer-sized monocrystals. Producing large BP monocrystals has proven to be a challenging and time-consuming endeavor, due to BP crystal growth being notoriously slow and the complex requirements for achieving a reasonable size and monocrystalline structure. In this work we successfully obtained large BP monocrystals (single lattice orientation) by fast self-assembly. Our fabrication process, which is about 100× faster than in previous reported research, uses relatively simple techniques, therefore demonstrating a considerable improvement towards the manufacturing of 3D photonic crystals.

All-organic switching polarizer based on polymer waveguides and liquid crystals.

This paper reports on the design, fabrication and characterization of an all-organic photonic integrated circuit working as a switching polarizer for visible light (630nm), combining organic waveguides and liquid crystals that can be electrically driven. The device was made in commercially available epoxy by laser direct writing lithography. A device with a 2dB loss and a 20dB extinction ratio for both polarizations, was simulated; the manufactured devices proved the working principle of the design. The results have led to the design of a switching polarization splitter, in which a careful choice of waveguide material and liquid crystal can lead to devices working on a wide range of wavelengths.

A 3D-printed device for polymer nanoimprint lithography.

Nanoimprint lithography (NIL) is an imprinting technique which has experienced an increasing popularity due to its versatility in fabrication processes. Commercial NIL machines are readily available achieving high quality results; however, these machines involve a relatively high investment. Hence, small laboratories often choose to perform NIL copies in a more rudimentary and cheaper way. A new simple system is presented in this document. It is based on two devices which can be made in-house in plastic by using a 3D printer or in aluminum. Thus, the overall manufacturing complexity is vastly reduced. The presented system includes pressure control and potentially temperature control. Replicas have been made using a sawtooth grating master with a pitch around half micrometre. High quality patterns with low density of imperfections have been achieved in 2.25 cm2 surfaces. The material chosen for the negative intermediary mould is PDMS. Tests of the imprint have been performed using the commercial hybrid polymer Ormostamp®.

Reorientation of single-wall carbon nanotubes in negative anisotropy liquid crystals by an electric field.

Single-wall carbon nanotubes (SWCNT) are anisotropic nanoparticles that can cause modifications in the electrical and electro-optical properties of liquid crystals. The control of the SWCNT concentration, distribution and reorientation in such self-organized fluids allows for the possibility of tuning the liquid crystal properties. The alignment and reorientation of CNTs are studied in a system where the liquid crystal orientation effect has been isolated. Complementary studies including Raman spectroscopy, microscopic inspection and impedance studies were carried out. The results reveal an ordered reorientation of the CNTs induced by an electric field, which does not alter the orientation of the liquid crystal molecules. Moreover, impedance spectroscopy suggests a nonnegligible anchoring force between the CNTs and the liquid crystal molecules.

Thermally tunable polarization by nanoparticle plasmonic resonance in photonic crystal fibers.

A photonic crystal fiber selectively filled with silver nanoparticles dispersed in polydimethylsiloxane has been numerically studied via finite elements analysis. These nanoparticles possess a localized surface plasmon resonance in the visible region which depends on the refractive index of the surrounding medium. The refractive index of polydimethylsiloxane can be thermally tuned leading to the design of polarization tunable filters. Filters found with this setup show anisotropic attenuation of the x-polarization fundamental mode around α(x) = 1200dB/cm remarkably higher than the y-polarization mode. Moreover, high fiber birefringence and birefringence reversal is observed in the spectral region of the plasmon.