A comprehensive assessment of the economic and technical viability of a zero liquid discharge (ZLD) hybrid desalination system for water and salt recovery.

Brine, a by-product of desalination and industrial facilities, is becoming more and more of an environmental issue. This comprehensive techno-economic assessment (TEA), focusing on the technical and economic aspects, investigates the performance and viability of a novel hybrid desalination brine treatment system known as zero liquid discharge (ZLD). Notably, this research represents the first instance of evaluating the feasibility and effectiveness of integrating three distinct desalination processes, namely brine concentrator (BC), high-pressure reverse osmosis (HPRO), and membrane-promoted crystallization (MPC), within a ZLD framework. The findings of this study demonstrate an exceptional water recovery rate of 97.04%, while the energy requirements stand at a reasonable level of 17.53 kWh/m3. Financially, the ZLD system proves to be at least 3.28 times more cost-effective than conventional evaporation ponds and offers comparable cost efficiency to alternatives such as land application and deep-well injection. Moreover, the ZLD system exhibits profitability potential by marketing both drinking water and solid salt or solely desalinated water. The daily profit from the sale of generated water varies from US$194.08 to US$281.41, with Greece and Cyprus attaining the lowest and highest profit, respectively. When considering the sale of both salt and water, the profit rises by 8% across all locations.

Decarbonized and circular brine management/valorization for water & valuable resource recovery via minimal/zero liquid discharge (MLD/ZLD) strategies.

Brine (saline wastewater/water) from desalination, salt lakes, and industrial activities (e.g., pharmaceutical industries, oil & gas industries) has received a lot of attention around the world due to its adverse impact on the environment. Currently, several disposal methods have been applied; however, these methods are nowadays unsustainable. To tackle this problem, brine treatment and valorization is considered a promising strategy to eliminate brine discharge and recover valuable resources such as water, minerals, salts, metals, and energy. Brine valorization and resource recovery can be achieved via minimal and zero liquid discharge (MLD & ZLD) desalination systems. Commercially successful technologies such as reverse osmosis (RO) and distillation cannot be adopted as standalone technologies due to restrictions (e.g., osmotic pressure, high-energy/corrosion). Nonetheless, novel technologies such as forward osmosis (FO), membrane distillation (MD) can treat brine of high salinity and present high recovery rates. The extraction of several ions from brines is technically feasible. The minerals/salts composed of major ions (i.e., Na+, Cl-, Mg2+, Ca2+) can be useful in a variety of sectors, and their sale prices are reasonable. On the other hand, the extraction of scarce metals such as lithium, rubidium, and cesium can be extremely profitable as their sale prices are extremely higher compared to the sale prices of common salts. Nonetheless, the extraction of such precious metals is currently restricted to a laboratory scale. The MLD/ZLD systems have high energy consumption and thus are associated with high GHGs emissions as fossil fuels are commonly burned to produce the required energy. To make the MLD/ZLD systems more eco-friendly and carbon-neutral, the authors suggest integrating renewable energy sources such as solar energy, wind energy, geothermal energy, etc. Besides water, minerals, salts, metals, and energy can be harvested from brine. In particular, salinity gradient power can be generated. Salinity gradient power technologies have shown great potential in several bench-scale and pilot-scale implementations. Nonetheless, several improvements are required to promote their large-scale feasibility and viability. To establish a CO2-free and circular global economy, intensive research and development efforts should continue to be directed toward brine valorization and resource recovery using MLD/ZLD systems.

Techno-economic assessment of zero liquid discharge (ZLD) systems for sustainable treatment, minimization and valorization of seawater brine.

The challenge of brine disposal has sparked a lot of interest in advanced strategies for valorizing them through freshwater and salt recovery. This research article examines the technical and economic aspects of zero liquid discharge (ZLD) desalination systems using two different crystallization processes, namely brine crystallizer (BCr) in scenario 1 and wind-aided intensified evaporation (WAIV) in scenario 2 for sustainable treatment, minimization, and valorization of seawater brine. The results indicated that scenario 1 has a higher water recovery (99.14%) than scenario 2 (85.75%) as the crystallization process in scenario 2 (i.e., WAIV) does not recover freshwater; however, water is evaporated through WAIV technology and thus both systems have low brine volumes (<1 m3/day), achieving ZLD conditions. The total energy and cost demands of scenario 1 (22.15 kWh/m3 & US$100.5/day) are greater than those of scenario 2 (15.34 kWh/m3 & US$85.3/day). Both scenarios are viable, with profits ranging from US$180.49/day to US$225.85/day depending on whether only desalinated water or both desalinated water and solid salt are sold. The insight given in this techno-economic analysis will aid in the sustainable valorization and management of brine from several brine-generating industries.

Study and evaluation of the characteristics of saline wastewater (brine) produced by desalination and industrial plants.

Desalination and industrial plants all around the world generate large amounts of saline wastewater (brine). The discharge of brine from facilities poses a severe environmental threat, while at the same time, the opportunity to recover resources is being lost as discharged brine is rich in valuable metals that could be recovered as salts/minerals. To this aim, this study presents and analyzes for the first time the characteristics of different brine effluents (from industries such as desalination, oil and gas production, petrochemical, aquaculture, pharmaceutical, textile) to prevent environmental pollution and to recover valuable resources (i.e., salts, minerals, metals, chemicals) enabling the concept of waste-to-resource (circular water economy model). The results revealed that the common salinity values in brine effluents range from 0.5 to 150 g/L, while the only exception is the produced water from the oil and gas industry (up to 400 g/L). Brine effluents from all sectors contain sodium, chloride, calcium, and potassium ions in high concentrations, while the production of common salts such as NaCl, CaCl2, and MgCl2 from brine can be economically profitable. Besides common ions, precious metals such as lithium, rubidium, and cesium are present in low concentrations (<25 mg/L); however, their extraction from brine effluents can be significantly profitable due to their very high sale price. The treatment and valorization of brine can be implemented by the hybridization of membrane-based, chemical, biological, and thermal-based technologies/processes in minimal and zero liquid discharge (MLD/ZLD) systems.

Water-energy nexus: desalination technologies and renewable energy sources.

Rapid population growth and industrialization have contributed to a dramatic decline in the supply of freshwater. As a result, desalination is an important choice to solve the global problem of water scarcity. Nevertheless, the hyper-saline by-product, the high capital costs, and the high energy demands currently met by fossil fuels are key obstacles to the widespread adoption of desalination systems. Furthermore, desalination plants powered by fossil fuels have negative environmental impacts due to greenhouse gases (GHGs) emissions. In contrast to fossil fuels, renewable energy is abundant and clean and is therefore a promising alternative for powering desalination plants. This is why the water-energy nexus is a crucial step towards a sustainable future. Therefore, the integration of renewable energy sources (RES) into desalination is very important. The main objective of this review to analyze and evaluate desalination technologies (thermal-based and membrane-based) and RES (solar, wind, hydropower, geothermal, and biomass) that could be combined as an integrated process. Social-economic factors, environmental concerns, current challenges, and future research areas for both desalination and RES are discussed.

Environmental impacts of desalination and brine treatment - Challenges and mitigation measures.

Desalination is perceived as an effective and reliable process for obtaining freshwater from aqueous saline solutions such as brackish water, seawater and brine. This can be clarified by the fact that >300 million people worldwide rely on desalinated water for their daily needs. Although the desalination process offers many advantages, there are rising concerns about possible adverse environmental impacts. Generally, environmental impacts can be generated both in the construction and operation of desalination plants. A major issue of desalination is the co-produced waste called 'brine' or 'reject' which has a high salinity along with chemical residuals and is discharged into the marine environment. In addition to brine, other main issues are the high energy consumption of the desalination and brine treatment technologies as well as the air pollution due to emissions of greenhouse gasses (GHGs) and air pollutants. Other issues include entrainment and entrapment of marine species, and heavy use of chemicals. The purpose of this review is to analyze the potential impacts of desalination and brine treatment on the environment and suggest mitigation measures.

Desalination brine disposal methods and treatment technologies - A review.

Brine, also known as concentrate, is the by-product of the desalination process that has an adverse impact on the environment due to its high salinity. Hence, viable and cost-effective brine management systems are needed to reduce environmental pollution. Currently, various disposal methods have been practiced, including surface water discharge, sewer discharge, deep-well injection, evaporation ponds and land application. However, these brine disposal methods are unsustainable and restricted by high capital costs and non-universal application. Nowadays, brine treatment is considered one of the most promising alternatives to brine disposal, since treatment results in the reduction of environmental pollution, minimization of waste volume and production of freshwater with high recovery. This review article evaluates current practices in brine management, including disposal methods and treatment technologies. Based upon the side-by-side comparison of technologies, a brine treatment technology framework is introduced to outline the Zero Liquid Discharge (ZLD) approach through high freshwater recovery and wastewater volume minimization. Furthermore, an overview of brine characteristics and its sources, as well as its negative impact on the environment is discussed. Finally, the paper highlights future research areas for brine treatment technologies aiming to enhance the effectiveness and viability of desalination.