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1.
Sci Adv ; 10(1): eadi6678, 2024 Jan 05.
Article in English | MEDLINE | ID: mdl-38170772

ABSTRACT

Chaetognaths, with their characteristic grasping spines, are the oldest known pelagic predators, found in the lowest Cambrian (Terreneuvian). Here, we describe a large stem chaetognath, Timorebestia koprii gen. et sp. nov., from the lower Cambrian Sirius Passet Lagerstätte, which exhibits lateral and caudal fins, a distinct head region with long antennae and a jaw apparatus similar to Amiskwia sagittiformis. Amiskwia has previously been interpreted as a total-group chaetognathiferan, as either a stem-chaetognath or gnathostomulid. We show that T. koprii shares a ventral ganglion with chaetognaths to the exclusion of other animal groups, firmly placing these fossils on the chaetognath stem. The large size (up to 30 cm) and gut contents in T. koprii suggest that early chaetognaths occupied a higher trophic position in pelagic food chains than today.


Subject(s)
Biological Evolution , Food Chain , Animals , Fossils , Hand Strength , Phylogeny
2.
Anal Chem ; 96(1): 170-178, 2024 Jan 09.
Article in English | MEDLINE | ID: mdl-38155534

ABSTRACT

Characterization of the elemental distribution of samples with rough surfaces has been strongly desired for the analysis of various natural and artificial materials. Particularly for pristine and rare analytes with micrometer sizes embedded on specimen surfaces, non-invasive and matrix effect-free analysis is required without surface polishing treatment. To satisfy these requirements, we proposed a new method employing the sequential combination of two imaging modalities, i.e., microenergy-dispersive X-ray fluorescence (micro-XRF) and Raman micro-spectroscopy. The applicability of the developed method is tested by the quantitative analysis of cation composition in micrometer-sized carbonate grains on the surfaces of intact particles sampled directly from the asteroid Ryugu. The first step of micro-XRF imaging enabled a quick search for the sparsely scattered and micrometer-sized carbonates by the codistributions of Ca2+ and Mn2+ on the Mg2+- and Fe2+-rich phyllosilicate matrix. The following step of Raman micro-spectroscopy probed the carbonate grains and analyzed their cation composition (Ca2+, Mg2+, and Fe2+ + Mn2+) in a matrix effect-free manner via the systematic Raman shifts of the lattice modes. The carbonates were basically assigned to ferroan dolomite bearing a considerable amount of Fe2+ + Mn2+ at around 10 atom %. These results are in good accordance with the assignments reported by scanning electron microscopy-energy-dispersive X-ray spectroscopy, where the thin-sectioned and surface-polished Ryugu particles were applicable. The proposed method requires neither sectioning nor surface polishing; hence, it can be applied to the remote sensing apparatus on spacecrafts and planetary rovers. Furthermore, the non-invasive and matrix effect-free characterization will provide a reliable analytical tool for quantitative analysis of the elemental distribution on the samples with surface roughness and chemical heterogeneity at a micrometer scale, such as art paintings, traditional crafts with decorated shapes, as well as sands and rocks with complex morphologies in nature.

3.
Science ; 379(6634): eabn7850, 2023 Feb 24.
Article in English | MEDLINE | ID: mdl-35679354

ABSTRACT

Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measured the mineralogy and bulk chemical and isotopic compositions of Ryugu samples. The samples are mainly composed of materials similar to those of carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominantly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37° ± 10°C, about [Formula: see text] million (statistical) or [Formula: see text] million (systematic) years after the formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above ~100°C. The samples have a chemical composition that more closely resembles that of the Sun's photosphere than other natural samples do.

4.
Sci Adv ; 8(46): eadd8141, 2022 Nov 18.
Article in English | MEDLINE | ID: mdl-36264823

ABSTRACT

Little is known about the origin of the spectral diversity of asteroids and what it says about conditions in the protoplanetary disk. Here, we show that samples returned from Cb-type asteroid Ryugu have Fe isotopic anomalies indistinguishable from Ivuna-type (CI) chondrites, which are distinct from all other carbonaceous chondrites. Iron isotopes, therefore, demonstrate that Ryugu and CI chondrites formed in a reservoir that was different from the source regions of other carbonaceous asteroids. Growth and migration of the giant planets destabilized nearby planetesimals and ejected some inward to be implanted into the Main Belt. In this framework, most carbonaceous chondrites may have originated from regions around the birthplaces of Jupiter and Saturn, while the distinct isotopic composition of CI chondrites and Ryugu may reflect their formation further away in the disk, owing their presence in the inner Solar System to excitation by Uranus and Neptune.

5.
Sci Rep ; 12(1): 12015, 2022 Jul 14.
Article in English | MEDLINE | ID: mdl-35835802

ABSTRACT

A broadband metasurface flat lens is proposed as a polarization-independent wideband superstrate for wave focusing and gain enhancement at Ka-band. The proposed metasurface structure consists of four metal layers and is designed with diagonally symmetric unit cells to accommodate both the vertical and horizontal polarizations. The focusing ability of the proposed metasurface flat lens is validated via simulation and measurement, where normally incident plane waves are shown to be enhanced by up to 11 dB as a result of wave focusing. Also, the radiation gain enhancement due to the proposed metasurface flat lens is demonstrated via simulation and measurement, where a gain enhancement of up to 10.5 dB is achieved. The results show that the proposed structure maintains the wave focusing and gain enhancement characteristics over a bandwidth of 28-32 GHz. Furthermore, to demonstrate the utility of the proposed metasurface for circular polarization (CP), the gain enhancement of a CP patch antenna as a result of implementing the proposed metasurface as a superstrate is demonstrated via simulation and measurement. It is shown that the proposed metasurface superstrate provides a CP gain enhancement of nearly 10 dB.

6.
Sci Rep ; 11(1): 12671, 2021 Jun 16.
Article in English | MEDLINE | ID: mdl-34135393

ABSTRACT

Metasurfaces allow the rapid development of compact and flat electromagnetic devices owing to their capability in manipulating the wavefront of electromagnetic waves. Particularly, with respect to the metasurface lenses, wide operational bandwidth and wide incident angle behavior are critically required for practical applications. Herein, a single-layer phase gradient metasurface lens is presented to achieve millimeter-wave focusing at a focal point of 13 mm regardless of the incident angle. The proposed metasurface lens is fabricated by constructing subwavelength-thick (< λ/10) phase elements composed of two metallic layers separated by a single dielectric substrate that exhibits low-Q resonance properties and a wide phase modulation range with satisfactory transmissivity. By controlling the spatial phase distribution, the proposed metasurface lens successfully realises effective wavefront manipulation properties and high-performance electromagnetic-wave-focusing characteristics over a wide operating frequency range from 35 to 40 GHz with incident angle independency up to 30°.

7.
Rapid Commun Mass Spectrom ; 33(7): 641-649, 2019 Apr 15.
Article in English | MEDLINE | ID: mdl-30669180

ABSTRACT

RATIONALE: The three oxygen isotopes in terrestrial/extraterrestrial silicates can provide geochemical and cosmochemical information about their origin and secondary processes that result from isotopic exchange. A laser fluorination technique has been widely used to extract oxygen from silicates for δ17 O and δ18 O measurements by isotope ratio mass spectrometry. Continued improvement of the techniques is still important for high-precision measurement of oxygen-isotopic ratios. METHODS: We adopted an automated lasing technique to obtain reproducible fluorination of silicates using a CO2 laser-BrF5 fluorination system connected online to an isotope ratio mass spectrometer. The automated lasing technique enables us to perform high-precision analysis of the three oxygen isotopes of typical reference materials (e.g., UWG2 garnet, NBS28 quartz and San Carlos olivine) and in-house references (mid-ocean ridge basalt glass and obsidian). The technique uses a built-in application of laser control with which the laser power can be varied in a programmed manner with a defocused beam which is in a fixed position. RESULTS: The oxygen isotope ratios of some international reference materials analyzed by the manual lasing technique were found to be isotopically lighter with wider variations in δ18 O values, whereas those measured by the automated lasing technique gave better reproducibility (less than 0.2‰, 2SD). The Δ17 O values, an excess of the δ17 O value relative to the fractionation line, also showed high reproducibility (±0.02‰, 2SD). CONCLUSIONS: The system described herein provides high-precision δ17 O and δ18 O measurements of silicate materials. The use of the automated lasing technique followed by careful and controlled purification procedures is preferred to achieve satisfactory isotopic ratio results.

8.
Article in English | MEDLINE | ID: mdl-30195928

ABSTRACT

Confocal Raman spectroscopy is effective in unveiling structures of minerals without destruction from surface to certain depth. In this study, we introduce an application of confocal Raman spectroscopy on minerals in a primitive chondritic meteorite. The experimental lateral resolution on silicate minerals in this study is ~1.0 µm. Raman spectrum of mesostasis in a named "Tear Drop" chondrule, a spherule object from a primitive chondrite, of Elephant Moraine 14017 (EET 14017) shows a broad feature indicating amorphous phase, which is a common characteristic of primitive chondrule mesostasis. Weak intensities of 825 and 858 cm-1 peaks were observed in the glassy mesostasis, probably originated from olivine below the surface. A plagioclase-rich chondrule (PRC-1) of EET 14017 was investigated with Raman spectroscopy, which contains two different occurrences of plagioclase: lath-shaped and interstitial grains. The strong intensity of 488 and 505 cm-1 (plagioclase) and weak intensity of 461 cm-1 band were observed on the lath-shaped plagioclase. The weak 461 cm-1 peak from the plagioclase is probably from the subsurface quartz. Raman spectrum of interstital plagioclase in PRC-1 shows 488 and 505 cm-1 bands and weak pyroxene bands. Depth profiling conducted on the interstitial plagioclase clearly shows that pyroxene exists below the surface. High-lateral resolution and well-resolved depth profiling with the confocal Raman spectroscopy allows us to identify tiny grains and investigate hidden phases underneath the surface without destruction of extraterrestrial materials.


Subject(s)
Meteoroids , Minerals/analysis , Spectrum Analysis, Raman/methods , Silicates/analysis , Surface Properties
9.
Nat Commun ; 9(1): 1019, 2018 03 09.
Article in English | MEDLINE | ID: mdl-29523785

ABSTRACT

Recent discoveries of fossil nervous tissue in Cambrian fossils have allowed researchers to trace the origin and evolution of the complex arthropod head and brain based on stem groups close to the origin of the clade, rather than on extant, highly derived members. Here we show that Kerygmachela from Sirius Passet, North Greenland, a primitive stem-group euarthropod, exhibits a diminutive (protocerebral) brain that innervates both the eyes and frontal appendages. It has been surmised, based on developmental evidence, that the ancestor of vertebrates and arthropods had a tripartite brain, which is refuted by the fossil evidence presented here. Furthermore, based on the discovery of eyes in Kerygmachela, we suggest that the complex compound eyes in arthropods evolved from simple ocelli, present in onychophorans and tardigrades, rather than through the incorporation of a set of modified limbs.


Subject(s)
Arthropods/anatomy & histology , Biological Evolution , Brain/anatomy & histology , Compound Eye, Arthropod/anatomy & histology , Eye/anatomy & histology , Fossils/anatomy & histology , Animals , Aquatic Organisms/classification , Arthropods/classification , Greenland
10.
ScientificWorldJournal ; 2014: 967181, 2014.
Article in English | MEDLINE | ID: mdl-25045755

ABSTRACT

We propose a mode-locking method optimized for the cascode structure of an RF CMOS power amplifier. To maximize the advantage of the typical mode-locking method in the cascode structure, the input of the cross-coupled transistor is modified from that of a typical mode-locking structure. To prove the feasibility of the proposed structure, we designed a 2.4 GHz CMOS power amplifier with a 0.18 µm RFCMOS process for polar transmitter applications. The measured power added efficiency is 34.9%, while the saturated output power is 23.32 dBm. The designed chip size is 1.4 × 0.6 mm(2).

11.
Science ; 333(6046): 1116-9, 2011 Aug 26.
Article in English | MEDLINE | ID: mdl-21868668

ABSTRACT

Meteorite studies suggest that each solar system object has a unique oxygen isotopic composition. Chondrites, the most primitive of meteorites, have been believed to be derived from asteroids, but oxygen isotopic compositions of asteroids themselves have not been established. We measured, using secondary ion mass spectrometry, oxygen isotopic compositions of rock particles from asteroid 25143 Itokawa returned by the Hayabusa spacecraft. Compositions of the particles are depleted in (16)O relative to terrestrial materials and indicate that Itokawa, an S-type asteroid, is one of the sources of the LL or L group of equilibrated ordinary chondrites. This is a direct oxygen-isotope link between chondrites and their parent asteroid.

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