Improving the Device Performance of CZTSSe Thin-Film Solar Cells via Indium Doping.

Cation incorporation emerges as a promising approach for improving the performance of the kesterite Cu2ZnSn(S,Se)4 (CZTSSe) device. Herein, we report indium (In) doping using the chemical bath deposition (CBD) technique to enhance the optoelectronic properties of CZTSSe thin-film solar cells (TFSCs). To incorporate a small amount of the In element into the CZTSSe absorber thin films, an ultrathin (<10 nm) layer of In2S3 is deposited on soft-annealed precursor (Zn-Sn-Cu) thin films prior to the sulfo-selenization process. The successful doping of In improved crystal growth and promoted the formation of larger grains. Furthermore, the CZTSSe TFSCs fabricated with In doping exhibited improved device performance. In particular, the In-CZTSSe-2-based device showed an improved power conversion efficiency (PCE) of 9.53%, open-circuit voltage (Voc) of 486 mV, and fill factor (FF) of 61% compared to the undoped device. Moreover, the small amount of In incorporated into the CZTSSe absorber demonstrated reduced nonradiative recombination, improved carrier separation, and enhanced carrier transport properties. This study suggests a simple and effective way to incorporate In to achieve high efficiency and low Voc loss.

Status review of nickel phosphides for hybrid supercapacitors.

Transition metal phosphides are a new class of materials that have attracted enormous attention as a potential electrode for supercapacitors (SCs) compared to metal oxides/hydroxides and metal sulfides due to their strong redox-active behaviour, good electrical conductivity, layered structure, low cost, and high chemical and thermal stability. Recently, several efforts have been made to develop nickel phosphides (NixPy) (NPs) for high-performance SCs. The electrochemical properties of NPs can be easily tuned by several innovative approaches, such as heteroatom doping, defect engineering, and developing a hollow architecture. The prospects of NPs as a positive electrode in hybrid SCs are summarized to understand the material's practical relevance. Finally, the challenges and perspectives are provided for the development of high-performance NPs for SCs. The thorough elucidation of the structure-property-performance relationship offers a guide for developing NP-based next-generation energy-storage devices.