Identification of water transitions using a combination of moisture sorption characteristics and dielectric properties of different parts of jasmine rice (Oryza sativa).

BACKGROUND: In this work, water transition points (first transition: monolayer-multilayer water; and second transition: multilayer-free and solvent water) of different parts of jasmine rice including white rice, brown rice and bran were identified through the integration of sorption isotherm and dielectric properties data. Desorption isotherm data were fitted to four established models to select the optimal model for describing the sorption behaviors. Then, dielectric properties such as dielectric constant (ε') and dielectric loss factor (ε″) were measured across various moisture content levels within the frequency range of 200-20 000 MHz. RESULTS: A type III isotherm was observed for all samples and the Peleg model was the best fit with the experimental data. Monolayer moisture content of the samples, estimated using the GAB model, ranged from 3.25% to 4.17% dry basis. For dielectric properties, frequency and moisture dependencies were evident for all sample types. Moreover, the sorption isotherm models effectively described the relationship between water activity (aw) and dielectric properties as reflected by their goodness of fit, and their strong correlation through principal component analysis and Pearson's correlation results. CONCLUSION: The first water transition occurs at aw values of 0.11, 0.12, and 0.22, while the second transition appears at aw values of 0.9, 0.9 and 0.75-0.85 for white rice, brown rice and bran, respectively. This knowledge will be useful for food processors, providing insights into the optimization of food processing and storage conditions to extend food products' shelf life. © 2024 Society of Chemical Industry.

Structural change kinetics, drying characteristics, antioxidant properties, and the correlation between quality parameters of dried duckweed (Wolffia arrhiza (L.) Wimm) affected by different levels of microwave power.

BACKGROUND: Duckweed is considered as a future food material due to its fast growth, high yield, high nutritional value, and low impact on land use. However, in its fresh form, it has high moisture content (95% wet basis), resulting in a short shelf life. In this study, microwave drying (MWD) was conducted to produce a shelf-stable duckweed with minimal loss of quality. Drying characteristics and quality aspects of dried duckweed were assessed. Reaction order kinetics, including zero and first order, was applied to describe structural changes during drying process. Hierarchical cluster analysis (HCA) was used to select the appropriate drying conditions. RESULTS: Of five drying models, the Midilli-Kucuk model was the one that best described the drying process. Drying at high microwave power could reduce energy consumption and increase energy efficiency. Increasing both microwave power and drying time increased the structural shrinkage rate as described by first-order reaction kinetics. High correlations among quality parameters were observed using Pearson's correlation. Drying treatments were differentiated into two main clusters by HCA and the results showed that MWD at 720 and 900 W provided samples that were closer in terms of quality to a freeze dried sample (the positive control) than samples that had been subjected to MWD at 450 W. CONCLUSION: Drying behaviors of duckweed were well-described by the Midilli-Kucuk model. Microwave drying at 900 W gave the lowest energy consumption and displayed the most efficient use of energy. The first-order equation could be used effectively to describe the structural changes in the duckweed. Microwave drying at 720 and 900 W was the appropriate drying condition according to the HCA classification. © 2023 Society of Chemical Industry.

New insights into moisture sorption characteristics, nutritional composition, and antioxidant and morphological properties of dried duckweed [Wolffia arrhiza (L.) Wimm].

BACKGROUND: Duckweed has been considered as an alternative future food material as a result of its high nutritional values, although it also has a high moisture content resulting in a short shelf life. Moisture sorption isotherms are used to design dehydration and storage conditions to prolong the shelf life food products. To date, information regarding the sorption isotherm of duckweed has not been reported. Scanning electron microscopy (SEM) is frequently used to study food microstructure. However, this technique has to be performed under high-vacuum conditions and takes a long time. In the present study, two-photon imaging microscopy was selected to investigate the microstructure of dried duckweed instead of SEM. RESULTS: Among five sorption isotherm models, the Peleg model gave the highest goodness of fit. The monolayer moisture content (M0 ) of duckweed was in the range 7.43-7.92% dry basis (d.b.) and 8.87-8.86% d.b. for the GAB and BET multilayer kinetic models, respectively. The moisture changing behavior at each relative humidity step could be described by two exponential and reaction order kinetics. A clear cell structure (hexagonal shape) and stomata, as well as structural images (both 2D and 3D), were obtained using the two-photon microscopy technique. CONCLUSION: The Peleg model best described the moisture sorption behaviors of dried duckweed and the shape of sorption isotherms were classified as type III isotherm. The M0 of dried duckweed ranged from 7.43 to 8.86% d.b. Two-photon microscopy was a potent tool for investigating the microstructure and composition of dried duckweed. © 2021 Society of Chemical Industry.

Effect of packaging types and storage conditions on quality aspects of dried Thunbergia laurifolia leaves and degradation kinetics of bioactive compounds.

Thunbergia laurifolia leaves were dried by freeze drying (FD) and microwave heat pump dehumidified air drying (MHPD). The dried leaves were stored in polypropylene (PP) or aluminum laminated pouches (ALP) at 15, 25 or 35 °C and 60% RH. The samples were held for 180 days to observe changes in moisture content, color, total phenolics, antioxidant activity, catechin and caffeic acid. In general, samples in PP had a greater increase in moisture. Total phenolics content and ferric-reducing antioxidant power values increased for 120 days, then decreased thereafter. After 180 days, both FD and MHPD samples packaged in ALP and stored at 15 °C had the greatest total phenolics, antioxidant activity and bioactive compounds amongst the storage conditions. The first-order equation best described degradation behavior of catechin and caffeic acid for both drying technologies investigated.

Effects of steam-microwave blanching and different drying processes on drying characteristics and quality attributes of Thunbergia laurifolia Linn. leaves.

BACKGROUND: Dried Thunbergia laurifolia leaves are usually prepared using tray drying, resulting in products that have lost substantial amounts of bioactive compounds and antioxidant activity. The maturity of the raw material, blanching techniques and drying methods were investigated in order to select the best condition to produce high qualities of dried T. laurifolia leaves. RESULTS: The 1st stage of maturity was selected and steam-microwave blanching (SMB) for 4 min was adequate for blanching leading to the maximum recovery of bioactive compounds. The modified Halsey model was the best desorption isotherm model. A new drying model proposed in this study was the best to fit the drying curves as compared to five common drying models. Moisture diffusivities were increased with the increase of drying temperature when combining SMB and heat pump-dehumidified drying. Microwave heat pump-dehumidified drying (MHPD) provided the shortest drying time, high specific moisture extraction rate (SMER) and could reduce drying time by 67.5% and increase caffeic acid and quercetin by 51.24% and 60.89%, respectively. CONCLUSION: MHPD was found to be the best drying method and provided the highest antioxidant activity and bioactive compounds content, high SMER and short drying time. © 2016 Society of Chemical Industry.