Review on Synthesis and Properties of Lithium Lanthanum Titanate.

The rapid development of portable electronic devices and the efforts to find alternatives to fossil fuels have triggered the rapid development of battery technology. The conventional lithium-ion batteries have reached a high degree of sophistication. However, improvements related to specific capacity, charge rate, safety and sustainability are still required. Solid state batteries try to answer these demands by replacing the organic electrolyte of the standard battery with a solid (crystalline, but also polymer and hybrid) electrolyte. One of the most promising solid electrolytes is Li3xLa2/3-xTiO3 (LLTO). The material nevertheless presents a set of key challenges that must be resolved before it can be used for commercial applications. This review discusses the synthesis methods, the crystallographic and the ionic conduction properties of LLTO and the main limitations encountered through a number of selected studies on this material.

Comparative analysis of denoising techniques in burn depth discrimination from burn hyperspectral images.

This study analyzes and compares the performance of five denoising techniques (Lee filter, gamma filter, principal component analysis, maximum noise fraction, and wavelet transform) in order to identify the most appropriate one that lead to the most accurate classification of burned tissue in hyperspectral images. Fifteen hyperspectral images of burned patients were acquired and denoising techniques were applied to each image. Spectral angle mapper classifier was used for data classification and the confusion matrix was used for quantitative evaluation of the performances of the denoising methods. The results revealed that gamma filter performed better than other denoising techniques with values of overall accuracy and kappa coefficient of 91.18% and 0.8958 respectively. The lowest performance was detected for principal component analysis. In conclusion, the gamma filter could be considered an optimal choice for noise reduction in burn hyperspectral images and could be used for a more accurate diagnosis of burn depth.

Development of 3D ZnO-CNT Support Structures Impregnated with Inorganic Salts.

Carbon-based materials are promising candidates for enhancing thermal properties of phase change materials (PCMs) without lowering its energy storage capacity. Nowadays, researchers are trying to find a proper porous structure as PCMs support for thermal energy storage applications. In this context, the main novelty of this paper consists in using a ZnO-CNT-based nanocomposite powder, prepared by an own hydrothermal method at high pressure, to obtain porous 3D printed support structures with embedding capacity of PCMs. The morphology of 3D structures, before and after impregnation with three PCMs inorganic salts (NaNO3, KNO3 and NaNO3:KNO3 mixture (1:1 vol% saturated solution) was investigated by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX). For structure impregnated with nitrates mixture, SEM cross-section morphology suggest that the inorganic salts impregnation started into micropores, continuing with the covering of the 3D structure surface and epitaxial growing of micro/nanostructured crystals, which led to reducing the distance between the structural strands. The variation of melting/crystallization points and associated enthalpies of impregnated PCMs and their stability during five repeated thermal cycles were studied by differential scanning calorimetry (DSC) and simultaneous DSC-thermogravimetry (DSC-TGA). From the second heating-cooling cycle, the 3D structures impregnated with NaNO3 and NaNO3-KNO3 mixture are thermally stable.

Hydrothermal Synthesis of Nanocrystalline ZrO2-8Y2O3-xLn2O3 Powders (Ln = La, Gd, Nd, Sm): Crystalline Structure, Thermal and Dielectric Properties.

Zirconium dioxide (ZrO2) is one of the ceramic materials with high potential in many areas of modern technologies. ZrO2 doped with 8 wt.% (~4.5 mol%) Y2O3 is a commercial powder used for obtaining stabilized zirconia materials (8 wt.% YSZ) with high temperature resistance and good ionic conductivity. During recent years it was reported the co-doping with multiple rare earth elements has a significant influence on the thermal, mechanical and ionic conductivity of zirconia, due complex grain size segregation and enhanced oxygen vacancies mobility. Different methods have been proposed to synthesize these materials. Here, we present the hydrothermal synthesis of 8 wt.% (~4.5 mol%) YSZ co-doped with 4, 6 and 8 wt.% La2O3, Nd2O3, Sm2O3 and Gd2O3 respectively. The crystalline phases formed during their thermal treatment in a large temperature range were analyzed by X-ray diffraction. The evolution of phase composition vs. thermal treatment temperatures shows as a major trend the formation at temperatures >1000 °C of a cubic solid solutions enriched in the rare earth oxide used for co-doping as major phase. The first results on the thermal conductivities and impedance measurements on sintered pellets obtained from powders co-doped with 8 wt.% Y and 6% Ln (Ln = La, Nd, Sm and Gd) and the corresponding activation energies are presented and discussed. The lowest thermal conductivity was obtained for La co-doped 8 wt.% YSZ while the lowest activation energy for ionic conduction for Gd co-doped 8 wt.% YSZ materials.

Complex Concentrated Alloys for Substitution of Critical Raw Materials in Applications for Extreme Conditions.

The paper is proposing a mini-review on the capability of the new complex concentrated alloys (CCAs) to substitute or reduce the use of critical raw materials in applications for extreme conditions. Aspects regarding the regulations and expectations formulated by the European Union in the most recent reports on the critical raw materials were presented concisely. A general evaluation was performed on the CCAs concept and the research directions. The advantages of using critical metals for particular applications were presented to acknowledge the difficulty in the substitution of such elements with other materials. In order to establish the level of involvement of CCAs in the reduction of critical metal in extreme environment applications, a presentation was made of the previous achievements in the field and the potential for the reduction of critical metal content through the use of multi-component compositions.

Critical Raw Materials Saving by Protective Coatings under Extreme Conditions: A Review of Last Trends in Alloys and Coatings for Aerospace Engine Applications.

Several applications, where extreme conditions occur, require the use of alloys often containing many critical elements. Due to the ever increasing prices of critical raw materials (CRMs) linked to their high supply risk, and because of their fundamental and large utilization in high tech products and applications, it is extremely important to find viable solutions to save CRMs usage. Apart from increasing processes' efficiency, substitution, and recycling, one of the alternatives to preserve an alloy and increase its operating lifetime, thus saving the CRMs needed for its manufacturing, is to protect it by a suitable coating or a surface treatment. This review presents the most recent trends in coatings for application in high temperature alloys for aerospace engines. CRMs' current and future saving scenarios in the alloys and coatings for the aerospace engine are also discussed. The overarching aim of this paper is to raise awareness on the CRMs issue related to the alloys and coating for aerospace, suggesting some mitigation measures without having the ambition nor to give a complete overview of the topic nor a turnkey solution.

Solutions for Critical Raw Materials under Extreme Conditions: A Review.

In Europe, many technologies with high socio-economic benefits face materials requirements that are often affected by demand-supply disruption. This paper offers an overview of critical raw materials in high value alloys and metal-matrix composites used in critical applications, such as energy, transportation and machinery manufacturing associated with extreme working conditions in terms of temperature, loading, friction, wear and corrosion. The goal is to provide perspectives about the reduction and/or substitution of selected critical raw materials: Co, W, Cr, Nb and Mg.