1.
Inorg Chem
; 60(17): 12681-12684, 2021 Sep 06.
Article
in English
| MEDLINE
| ID: mdl-34382784
ABSTRACT
Aquacobalamin binds hydrogen peroxide reversibly to form a cobalt(III) hydroperoxo adduct with a 0.25 mM dissociation constant, as evidenced by UV-vis absorption spectroscopy and corroborated by NMR, Raman spectroscopy, stopped-flow UV-vis measurements, and density functional theory calculations.