Decoration of dandelion-like manganese-doped iron oxide microflowers on plasma-treated biochar for alleviation of heavy metal pollution in water.

Carbon-based biowaste incorporated with inorganic oxides as a composite is an enticing option to mitigate heavy metal pollution in water resources due to its more economical and efficient performance. With this in mind, we constructed manganese-doped iron oxide microflowers resembling the dandelion-like structure on the surface of cold plasma-treated carbonized rice husk (MnFe2O3/PCRH). The prepared composite exhibited 45% and 19% higher removal rates for Cu2+ and Cd2+, respectively than the pristine CRH. The MnFe2O3/PCRH composite was characterized using XRD, FTIR, FESEM, EDX, HR-TEM, XPS, BET, TGA, and zeta potential, while the adsorption capacities were investigated as a function of pH, time, and initial concentration in batch trials. As for the kinetics, the pseudo-second-order was the rate-limiting over the pseudo-first-order and Elovich model, demonstrating that the chemisorption process governed the adsorption of Cu2+ and Cd2+. Additionally, the maximum adsorption capacities of the MnFe2O3/PCRH were found to be 122.8 and 102.5 mg/g for Cu2+ and Cd2+, respectively. Based on thorough examinations by FESEM-EDS, FTIR, and XPS, the possible mechanisms for the adsorption can be ascribed to surface complexation by oxygen-containing groups, a dissolution-precipitation of the ions with -OH groups, electrostatic attraction between metal ions and the adsorbent's partially charged surface, coordination of Cu2+ and Cd2+ with π electrons by aromatic/graphitic carbon in the MnFe2O3/PCRH, and pore filling and diffusion. Lastly, the adsorption efficiencies were maintained at about 70% of its initial adsorption even after five adsorption-desorption cycles, displaying its remarkable stability and reusability.

Low-Cost Hydrogen Production from Alkaline/Seawater over a Single-Step Synthesis of Mo3 Se4 -NiSe Core-Shell Nanowire Arrays.

The rational design and steering of earth-abundant, efficient, and stable electrocatalysts for hydrogen generation is highly desirable but challenging with catalysts free of platinum group metals (PGMs). Mass production of high-purity hydrogen fuel from seawater electrolysis presents a transformative technology for sustainable alternatives. Here, a heterostructure of molybdenum selenide-nickel selenide (Mo3 Se4 -NiSe) core-shell nanowire arrays constructed on nickel foam by a single-step in situ hydrothermal process is reported. This tiered structure provides improved intrinsic activity and high electrical conductivity for efficient charge transfer and endows excellent hydrogen evolution reaction (HER) activity in alkaline and natural seawater conditions. The Mo3 Se4 -NiSe freestanding electrodes require small overpotentials of 84.4 and 166 mV to reach a current density of 10 mA cm-2 in alkaline and natural seawater electrolytes, respectively. It maintains an impressive balance between electrocatalytic activity and stability. Experimental and theoretical calculations reveal that the Mo3 Se4 -NiSe interface provides abundant active sites for the HER process, which modulate the binding energies of adsorbed species and decrease the energetic barrier, providing a new route to design state-of-the-art, PGM-free catalysts for hydrogen production from alkaline and seawater electrolysis.

Cold plasma-assisted regeneration of biochar for dye adsorption.

Environmental remedies, including adsorption-based water purification, are now being asked to meet the requirement for a low-carbon circular economy requiring low energy and low material consumption. In this regard, we tested the possibility of regenerating adsorbents via cold plasma (CP) treatment for less use of adsorbents and no washing solution. In the adsorption of methylene blue (MB) using carbonized rice husk (CRH) and five successive regeneration cycles by CP treatment, the removal efficiencies were maintained at a moderate level (∼70% of the initial performance), unlike five consecutive adsorption without CP treatment (∼9-13% of the initial performance). The regeneration of CRH by CP treatment was also double-checked by the FESEM, EDS, BET, FTIR, XPS, and surface zeta potential measurements. The successfully recovered adsorption capability is related to the remediation of adsorption sites. It is also worth noting that the required power consumption for recycling by CP treatment was about 6.4 times lower than carbonizing new rice husks. This work provides insights into recovering adsorbents using CP without rigorous, costly, and energy-intensive processes.

Chitosan polymer matrix-derived nanocomposite (CuS/NSC) for non-enzymatic electrochemical glucose sensor.

In this study, N and S co-doped chitosan polymer matrix-derived composite (CuS/NSC) was synthesized via a one-step hydrothermal technique using a low-cost copper complex of chitosan polymer. Cyclic voltammetry and chronoamperometry revealed excellent electrocatalytic performance. The glucose sensor exhibited a linear range of 160 µM to 11.76 mM, a low detection limit 2.72 µM and a sensitivity of 13.62 mA mM-1 cm-2 with an excellent linear response. Furthermore, the sensor also displayed selectivity for glucose over potential interfering agents and exhibited a satisfactory recovery percentage using real sample in human serum. The results demonstrate that, CuS/NSC is an efficient nanocomposite material for non-enzymatic glucose sensors and is applicable for glucose detection in biological fluids.