Synthesis and investigation on synergetic effect of activated carbon loaded silver nanoparticles with enhanced photocatalytic and antibacterial activities.

In this study, we synthesized silver nanoparticle-loaded cashew nut shell activated carbon (Ag/CNSAC). The synthesized samples were characterized by XRD, XPS, SEM with EDS, FT-IR, and BET analysis. The XRD, XPS, and EDS data provided convincing proof that Ag loaded on CNSAC is formed. The energy dispersive spectrum analysis and X-ray diffraction pattern both supported the face-centered cubic and amorphous structures of Ag/CNSAC. The SEM micrographs showed the inner surface development of Ag NPs and many tiny pores in CNSAC. The photodegradation of methylene blue (MB) dye by the Ag/CNSAC photocatalyst was investigated. This effective degradation of MB dye by Ag/CNSAC is attributed to the cooperative action of Ag as a photocatalyst and CNSAC as a catalytic support and adsorbent. In tests with gram-positive and negative bacteria including Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus), the as-synthesized Ag/CNSAC showed outstanding antibacterial efficiency. Additionally, this study demonstrates a workable procedure for creating an affordable and efficient Ag/CNSAC for the photocatalytic eradication of organic contaminants.

Development of biohybrid Ag2CrO4/rGO based nanocomposites with stable flotation properties as enhanced Photocatalyst for sewage treatment and antibiotic-conjugated for antibacterial evaluation.

The proposed research outlines a facile method to synthesize Silver Chromate/reduced graphene oxide nanocomposites (Ag2CrO4/rGO NCs) with a narrow dissemination size for the ecological treatment of hazardous organic dyes. The photodegradation performance toward the decontamination of model artificial methylene blue dye was assessed under solar light irradiation. The crystallinity, particle size, recombination of photogenerated charge carriers, energy gap and surface morphologies of synthesized nanocomposites were determined. The experiment objective is to use rGO nanocomposites to increase Ag2CrO4 photocatalytic efficiency in the solar spectrum. Tauc plots of ultraviolet-visible (UV-vis) spectrum were used to calculate the optical bandgap energy of the produced nanocomposites ∼1.52 eV, which resulted in a good photodegradation percentage of ∼92 % after 60 min irradiation of Solar light. At the same time, pure Ag2CrO4 and rGO nanomaterials showed ∼46 % and âˆ¼ 30 %, respectively. The ideal circumstances were discovered by investigating the effects of several parameters, including catalyst loading and different pH levels, on the degradation of dyes. However, the final composites maintain their ability to degrade for up to five cycles. According to the investigations, Ag2CrO4/rGO NCs are an effective photocatalyst and can be used as the ideal material to prevent water pollution. Furthermore, antibacterial efficacy for the hydrothermally synthesized nanocomposite was tested against gram-positive (+ve) bacteria viz. Staphylococcus aureus and gram-negative (-ve) bacteria viz. Escherichia coli. The maximum zone of inhibition for S. aureus and E. coli were 18.5 and 17 mm, respectively.

Effect of metal doping and non-metal loading on light energy driven degradation of organic dye using ZnO nanocatalysts.

Photocatalytic degradation of azo dyes is seen as a viable technique for addressing environmental and energy concerns simultaneously. Therefore, the primary requirement is the creation of a better catalyst with adequate product selectivity for removal efficiency under solar light. Herein, pure ZnO and Cu (0.10 M) doped cotton stalk activated carbons with ZnO (Cu-doped ZnO/CSAC) were produced, and these are labelled as CZ1, CZ2, CZ3, and CZ3/CSAC, respectively. The optoelectronic and photodegradation efficiencies were examined regarding the impact of doping and loading samples. The XRD patterns confirmed that the CZ3/CSAC sample exhibited a hexagonal wurtzite structure. The XPS survey confirmed that Cu ions were incorporated into the ZnO lattice in a Cu2+ oxidation state. The band gap value (CZ3/CSAC) was reduced (2.38 eV) compared to pure ZnO and CZ3. Moreover, PL and EIS analysis proved more efficient at separating photoinduced charged carriers for CZ3/CSAC than all other samples. The CZ3/CSAC sample showed improved photocatalytic degradation efficiency (93.09%) compared to the pure ZnO and CZ3 samples using brilliant green (BG) dye under sunlight irradiation.

Sustainable development through the bio-fabrication of ecofriendly ZnO nanoparticles and its approaches to toxicology and environmental protection.

Mosquito control is becoming more difficult as a result of the rise in resistance to toxic chemical insecticides. The insecticides of bio-fabrication sources may serve as a convenient alternative to environmentally acceptable methods in the future. The larvicidal and pupicidal activities of bio-fabricated zinc oxide nanoparticles (ZnO NPs) on the different instar larvae and pupae of Anopheles subpictus Grassi (Malaria vector) and Culex quinquefasciatus Say (lymphatic filariasis) were investigated in this study. The results recorded from XRD, FTIR, SEM-EDX, and TEM analyses confirmed the bio-fabrication of ZnO NPs. Such nanoparticles were nearly spherical and agglomerated with a size of 34.21 nm. GC-MS analysis of methanol extract revealed the compound, stigmasterol (C29H48O) as major one. Mosquito larvae and pupae of targeted mosquito were tested against varied concentrations of the bio-fabricated ZnO NPs and methanol extract of Vitex negundo for 24 h. The maximum activity was recorded from ZnO NPs against the larvae and pupae of A. subpictus LC50 which were 1.70 (I), 1.66 (II), 1.93 (III), 2.48 (IV), and 3.63 mg/L (pupa) and C. quinquefasciatus LC50 were 1.95 (I), 2.63 (II), 2.90 (III), 4.32 (IV), and 4.61 mg/L (pupa) respectively. ZnO NPs exhibited strong DPPH radical and FRAP scavengers compared to the aqueous extract of V. negundo. Also, V. negundo leaf methanol extract (VNLME) and ZnO NPs were evaluated for their cytotoxicity on HeLa cells, which exhibited the IC50 values of 72.35 and 43.70µg/mL, respectively. The methylene blue (MB) dye, which is harmful to both aquatic and terrestrial life, was degraded using the biosynthesized ZnO nanoparticles. At 664 nm, 81.2% of the MB dye had degraded after 120 min of exposure to sunlight. Overall, our results revealed that ZnO NPs are the perfect biological agent and economical for the control of malaria, filariasis vectors, antioxidant, HeLa cells, and MB blue dye degradation under sunlight irradiation.

Study of synergistic effect of cobalt and carbon codoped with TiO2 photocatalyst for visible light induced degradation of phenol.

In this work, we reported synthesis of cobalt and carbon codoped TiO2 (Co-C-TiO2) nanoparticles were prepared using co-precipitation technique. The synthesized catalysts are analyzed by various methods. The powder XRD pattern confirmed that all the samples were polycrystalline of anatase phase and particle size of resultant nanoparticle was reduced correlated with bare TiO2 sample. FTIR measurements exhibit the identification of functional groups present at the surface of TiO2. FESEM micrograph showed that the shape of codoped TiO2 nanoparticles are approximately sphere. The attained energy gap of Co doped and C codoping of TiO2 modifies to a level below the energy gap of TiO2 anatase specifying a high capability to absorb visible light. The recombination rate of photo-induced electrons and holes for Co-C codoped TiO2 nanoparticles is significantly reduced. The synthesized samples are assessed in degradation of phenol by the illumination of visible light. The results confirmed that photocatalytic activity enhanced due to doping and codoping of Co and C. As a result, Co-C codoped TiO2 nanoparticles exhibited a higher visible-light photocatalytic activity in compared with Co-TiO2 and bare TiO2 with the maximum degradation efficiency of 98, 75 and 15%, respectively. And also, the reusability of the catalyst was proved when 95% degradation could be achieved after consecutive batches. It is predictable that this work will provide new insights to increase the visible light active photocatalysts for environmental problems.

Enhanced sun light driven photocatalytic activity of Co doped SnO2 loaded corn cob activated carbon for methylene blue dye degradation.

SnO2 with different Co2+ doping concentrations and Co (0.075 M): SnO2 loaded corn cob activated carbon (Co: SnO2/CCAC) were prepared, and are labelled as CS1, CS2, CS3 and CS2/CCAC, respectively. The CS2/CCAC showed that the particle size (18.76 nm) and band gap (3.50 eV) are reduced with Co2+ doping and CCAC loading. Moreover, CS2/CCAC indicate that the decreased PL intensity and its lower value (2.156 kΩ) of impedance from EIS results which indicates the increased separation of the photogenerated e-/h+ pairs. Thus, the result showed that CS2/CCAC maximum degradation efficiency of MB (95.38%) and the photocatalytic mechanism is also discussed.

Effect of doping and loading Parameters on photocatalytic degradation of brilliant green using Sn doped ZnO loaded CSAC.

Sn doped ZnO loaded cotton stalk activated carbon (Sn-ZnO/CSAC) was prepared by chemical precipitation method, and the products were characterized. The XRD resultants confirm that the presence of hexagonal wurtzite phase of the bare ZnO. Furthermore, particular particle size gradually decreases (21.49 nm) due to doping and loading. UV-Vis absorption intensity of doped/loaded sample was red-shifted and then PL intensity is reduced. The photocatalytic performances of bare, Sn-doped ZnO and Sn-ZnO/CSAC was estimated by photodegradation of brilliant green (BG) under sunlight. The photodegradation of BG dye in 120 min over Sn-doped ZnO/CSAC is nearly 96.52%, which is considerably improved than bare ZnO (72.60%), respectively.