Self-Perceptional Soft Robotics by a Dielectric Elastomer.

Soft robotics has been a rapidly growing field in recent decades due to its advantages of softness, deformability, and adaptability to various environments. However, the separation of perception and actuation in soft robot research hinders its progress toward compactness and flexibility. To address this limitation, we propose the use of a dielectric elastomer actuator (DEA), which exhibits both an actuation capability and perception stability. Specifically, we developed a DEA array to localize the 3D spatial position of objects. Subsequently, we integrate the actuation and sensing properties of DEA into soft robots to achieve self-perception. We have developed a system that integrates actuation and sensing and have proposed two modes to achieve this integration. Furthermore, we demonstrated the feasibility of this system for soft robots. When the robots detect an obstacle or an approaching object, they can swiftly respond by avoiding or escaping the obstacle. By eliminating the need for separate perception and motion considerations, self-perceptional soft robots can achieve an enhanced response performance and enable applications in a more compact and flexible field.

Synthesis and drag reduction properties of a hydrophobically associative polymer containing ultra-long side chains.

Different from common hydrophobic associative polymers, a new hydrophobic associative polyacrylamide (HAPAM) with ultra-long side chains was synthesized and aimed to be used as drag reducer in this work. Firstly, a water-soluble hydrophobic monomer (named AT114) was obtained by alcoholysis reaction with acryloyl chloride and triton 114, then the drag reducer was obtained by radical copolymerization of AM, AMPS and AT114. The structures of AT114 and drag reducer were characterized by IR and NMR. Slick water was obtained by dissolving a small amount drag reducer in water. Although the viscosity of slick water varied greatly in fresh water and brine, the drag reduction rate always remained at a high level when flowing in pipelines. When the concentration of the drag reducer was 0.03% in fresh water, drag reduction rate can be up to 76.7%, while in high concentration brine, still as high as 76.2%. It shows that salt has no obvious negative impact on the drag reduction rate. That is also to say, in the case of low viscosity, the viscosity change has no obvious impact on drag reduction rate. From the Cryo-TEM observation, it can be concluded that the drag reducer forms sparse network structures in water, which is the direct reason for drag reducing effect. This finding provides knowledge regarding the development of new drag reducers.

A processable, high-performance dielectric elastomer and multilayering process.

Dielectric elastomers (DEs) can act as deformable capacitors that generate mechanical work in response to an electric field. DEs are often based on commercial acrylic and silicone elastomers. Acrylics require prestretching to achieve high actuation strains and lack processing flexibility. Silicones allow for processability and rapid response but produce much lower strains. In this work, a processable, high-performance dielectric elastomer (PHDE) with a bimodal network structure is synthesized, and its electromechanical properties are tailored by adjusting cross-linkers and hydrogen bonding within the elastomer network. The PHDE exhibits a maximum areal strain of 190% and maintains strains higher than 110% at 2 hertz without prestretching. A dry stacking process with high efficiency, scalability, and yield enables multilayer actuators that maintain the high actuation performance of single-layer films.

A unimorph nanocomposite dielectric elastomer for large out-of-plane actuation.

Dielectric elastomer actuators (DEAs) feature large, reversible in-plane deformation, and stacked DEA layers are used to produce large strokes in the thickness dimension. We introduce an electrophoretic process to concentrate boron nitride nanosheet dispersion in a dielectric elastomer precursor solution onto a designated electrode surface. The resulting unimorph nanocomposite dielectric elastomer (UNDE) has a seamless bilayer structure with 13 times of modulus difference. The UNDE can be actuated to large bending curvatures, with enhanced breakdown field strength and durability as compared to conventional nanocomposite dielectric elastomer. Multiple UNDE units can be formed in a simple electrophoretic concentration process using patterned electrode areas. A disc-shaped actuator comprising six UNDE units outputs large bidirectional stroke up to 10 Hz. This actuator is used to demonstrate a high-speed lens motor capable of varying the focal length of a two-lens system by 40 times.

Recent Advances in Multiresponsive Flexible Sensors towards E-skin: A Delicate Design for Versatile Sensing.

Multiresponsive flexile sensors with strain, temperature, humidity, and other sensing abilities serving as real electronic skin (e-skin) have manifested great application potential in flexible electronics, artificial intelligence (AI), and Internet of Things (IoT). Although numerous flexible sensors with sole sensing function have already been reported since the concept of e-skin, that mimics the sensing features of human skin, was proposed about a decade ago, the ones with more sensing capacities as new emergences are urgently demanded. However, highly integrated and highly sensitive flexible sensors with multiresponsive functions are becoming a big thrust for the detection of human body motions, physiological signals (e.g., skin temperature, blood pressure, electrocardiograms (ECG), electromyograms (EMG), sweat, etc.) and environmental stimuli (e.g., light, magnetic field, volatile organic compounds (VOCs)), which are vital to real-time and all-round human health monitoring and management. Herein, this review summarizes the design, manufacturing, and application of multiresponsive flexible sensors and presents the future challenges of fabricating these sensors for the next-generation e-skin and wearable electronics.

Nanofibrillar Poly(vinyl alcohol) Ionic Organohydrogels for Smart Contact Lens and Human-Interactive Sensing.

Hydrogel bioelectronics as one of the next-generation wearable and implantable electronics ensures excellent biocompatibility and softness to link the human body and electronics. However, volatile, opaque, and fragile features of hydrogels due to the sparse and microscale three-dimensional network seriously limit their practical applications. Here, we report a type of smart and robust nanofibrillar poly(vinyl alcohol) (PVA) organohydrogels fabricated via one-step physical cross-linking. The nanofibrillar network cross-linked by numerous PVA nanocrystallites enables the formation of organohydrogels with high transparency (90%), drying resistance, high toughness (3.2 MJ/m3), and tensile strength (1.4 MPa). For strain sensor application, the PVA ionic organohydrogel after soaking in NaCl solution shows excellent linear sensitivity (GF = 1.56, R2 > 0.998) owing to the homogeneous nanofibrillar PVA network. We demonstrate the potential applications of the nanofibrillar PVA-based organohydrogel in smart contact lens and emotion recognition. Such a strategy paves an effective way to fabricate strong, tough, biocompatible, and ionically conductive organohydrogels, shedding light on multifunctional sensing applications in next-generation flexible bioelectronics.

Flexible Anti-Biofouling MXene/Cellulose Fibrous Membrane for Sustainable Solar-Driven Water Purification.

Solar-driven interfacial water evaporation is regarded as an effective, renewable, and environment-friendly technology for clean water production. However, biofouling caused by the nonspecific interaction between the steam generator and biofoulants generally hinders the efficient application of wastewater treatment. Herein, this work reports a facile strategy to fabricate flexible anti-biofouling fibrous photothermal membrane consisting of a MXene-coated cellulose membrane for highly efficient solar-driven water steam evaporation toward water purification applications. The as-prepared MXene/cellulose photothermal membrane exhibits light absorption efficiency as high as ∼94% in a wide solar spectrum range and a water evaporation rate up to 1.44 kg m-2 h-1 under one solar illumination. Also, the MXene/cellulose membrane shows very high antibacterial efficiency (above 99.9%) owing to the MXene coating as a highly effective bacteriostatic agent. Such a flexible, anti-biofouling, and high-efficiency photothermal membrane sheds light on practical applications in long-term wastewater treatments.

Human Skin-Inspired Electronic Sensor Skin with Electromagnetic Interference Shielding for the Sensation and Protection of Wearable Electronics.

Increasingly serious electromagnetic radiation pollution puts higher demands on wearable devices. Electronic sensor skin capable of shielding electromagnetic radiation can provide extra protection in emerging fields such as electronic skins, robotics, and artificial intelligence, but combining the sensation and electromagnetic shielding performance together remains a great challenge. Here, inspired by the structure and functions of the human skin, a multifunctional electronic skin (M-E-skin) with both tactile sensing and electromagnetic radiation shielding functions is proposed. The tactile sensing of human skin is mimicked with irregular dermislike rough surfaces, and the electromagnetic shielding performance not available on natural skin is introduced by mimicking the ultraviolet electromagnetic radiation absorption of melanin in epidermis. The M-E-skin shows superior sensitivity (9.8 × 104 kPa-1 for the pressure range 0-0.2 kPa and 3.5 × 103 kPa-1 within 0.2-20 kPa), broad operating range (0-20 kPa), fast response and relaxation times (<62.5 ms), great pressuring-relaxing stability (10 kPa, 1000 cycles), low operating voltage (0.1 V), low power consumption (1.5 nW), and low detection limit (5 Pa). Besides, a broad range of electromagnetic wave (0.5-7.5 GHz) is shielded more than 99.66% by the M-E-skin. This work holds great potential to enlarge the application scope of current electronic skins.

2D end-to-end carbon nanotube conductive networks in polymer nanocomposites: a conceptual design to dramatically enhance the sensitivities of strain sensors.

New generation wearable devices require mechanically compliant strain sensors with a high sensitivity in a full detecting range. Herein, novel 2D end-to-end contact conductive networks of multi-walled carbon nanotubes (MWCNTs) were designed and realized in an ethylene-α-octene block copolymer (OBC) matrix. The prepared strain sensor showed a high gauge factor (GF) of 248 even at a small strain (5%) and a linear resistance response throughout the whole strain range. The sensors also exhibited very good stretchability up to 300% and high cycling durability. This novel design solved the intrinsic problem of sensors based on carbon nanotube bundles, i.e., a long sliding phase before the disconnection of CNTs in a cost-effective and scalable way. This study rationalizes the 2D end-to-end contact concept to improve the sensitivity of the existing sensors and has great potential to be used in a wide variety of polymer based sensors.

Effect of phase coarsening under melt annealing on the electrical performance of polymer composites with a double percolation structure.

The effect of phase coarsening on the evolution of the carbon black (CB) nanoparticle network under quiescent melt annealing and the electrical performance of polypropylene/polystyrene/carbon black (PP/PS/CB) composites with a double percolation structure was investigated. The results showed that when the CB content is low, the coarsening process of PP/PS/CB blends can be divided into two stages. In the first stage, the coarsening rate is fast before the formation of the CB nanoparticle network, and after annealing for a certain time, the evolution of the co-continuous morphology can drive the CB nanoparticles to self-assemble into a complete nanoparticle network. In the second stage, the coarsening rate is slow after the formation of the CB nanoparticle network. When the CB content is high, the CB nanoparticle network can be maintained throughout the whole annealing process, so that the conductivity and morphology of the PP/PS/CB composites are stable. Moreover, the electrical conductivity of the PP/PS/CB composites greatly increases after annealing for a certain time, and a percolation threshold as low as 0.07 vol% can be obtained. These results reveal the relationship between the evolution of the morphology and the conductivity in the conductive polymer composites with a double percolation structure, and provide a more in-depth and comprehensive understanding of the double percolation structure.