ABSTRACT
Methyl formate (MF; CH3OCHO) is the smallest representative of esters, which are common components of biodiesel. The present study characterizes the thermal dissociation kinetics of the radicals formed by H atom abstraction from MFâCH3OCO and CH2OCHOâthrough a combination of modeling, experiment, and theory. For the experimental effort, excimer laser photolysis of Cl2 was used as a source of Cl atoms to initiate reactions with MF in the gas phase. Time-resolved species profiles of MF, Cl2, HCl, CO2, CH3, CH3Cl, CH2O, and CH2ClOCHO were measured and quantified using photoionization mass spectrometry at temperatures of 400-750 K and 10 Torr. The experimental data were simulated using a kinetic model, which was informed by ab initio-based theoretical kinetics calculations and included chlorine chemistry and secondary reactions of radical decomposition products. We calculated the rate coefficients for the H-abstraction reactions Cl + MF â HCl + CH3OCO (R1a) and Cl + MF â HCl + CH2OCHO (R1b): k1a,theory = 6.71 × 10-15·T1.14·exp(-606/T) cm3/molecule·s; k1b,theory = 4.67 × 10-18·T2.21·exp(-245/T) cm3/molecule·s over T = 200-2000 K. Electronic structure calculations indicate that the barriers to CH3OCO and CH2OCHO dissociation are 13.7 and 31.6 kcal/mol and lead to CH3 + CO2 (R3) and CH2O + HCO (R5), respectively. The master equation-based theoretical rate coefficients are k3,theory (P = ∞) = 2.94 × 109·T1.21·exp(-6209/T) s-1 and k5,theory (P = ∞) = 8.45 × 108·T1.39·exp(-15132/T) s-1 over T = 300-1500 K. The calculated branching fractions into R1a and R1b and the rate coefficient for R5 were validated by modeling of the experimental species time profiles and found to be in excellent agreement with theory. Additionally, we found that the bimolecular reactions CH2OCHO + Cl, CH2OCHO + Cl2, and CH3 + Cl2 were critical to accurately model the experimental data and constrain the kinetics of MF-radicals. Inclusion of the kinetic parameters determined in this study showed a significant impact on combustion simulations of larger methyl esters, which are considered as biodiesel surrogates.
ABSTRACT
The concentration of formic acid in Earth's troposphere is underestimated by detailed chemical models compared to field observations. Phototautomerization of acetaldehyde to its less stable tautomer vinyl alcohol, followed by the OH-initiated oxidation of vinyl alcohol, has been proposed as a missing source of formic acid that improves the agreement between models and field measurements. Theoretical investigations of the OH + vinyl alcohol reaction in excess O2 conclude that OH addition to the α carbon of vinyl alcohol produces formaldehyde + formic acid + OH, whereas OH addition to the ß site leads to glycoaldehyde + HO2. Furthermore, these studies predict that the conformeric structure of vinyl alcohol controls the reaction pathway, with the anti-conformer of vinyl alcohol promoting α OH addition, whereas the syn-conformer promotes ß addition. However, the two theoretical studies reach different conclusions regarding which set of products dominate. We studied this reaction using time-resolved multiplexed photoionization mass spectrometry to quantify the product branching fractions. Our results, supported by a detailed kinetic model, conclude that the glycoaldehyde product channel (arising mostly from syn-vinyl alcohol) dominates over formic acid production with a 3.6:1.0 branching ratio. This result supports the conclusion of Lei et al. that conformer-dependent hydrogen bonding at the transition state for OH-addition controls the reaction outcome. As a result, tropospheric oxidation of vinyl alcohol creates less formic acid than recently thought, increasing again the discrepancy between models and field observations of Earth's formic acid budget.
ABSTRACT
It is well-documented that photodissociation of SO2 at λ = 193 nm produces O(3Pj) + SO X(3Σ-). We provide experimental evidence of a new product channel from one-photon absorption producing S(3Pj) + O2 X(3Σg-) in 2-4% yield. We probe the reactant and all products with time-resolved photoelectron photoion coincidence spectroscopy. High-level ab initio calculations suggest that the new product channel can only occur on the ground-state potential energy surface through internal conversion from the excited state, followed by isomerization to a transient SOO intermediate. Classical trajectories on the ground-state potential energy surface with random initial conditions qualitatively reproduce the experimental yields. This unexpected photodissociation pathway may help reconcile discrepancies in sulfur mass-independent fractionation mechanisms in Earth's geologic history, which shape our understanding of the Archean atmosphere and the Great Oxygenation Event in Earth's evolution.
ABSTRACT
We present a new photoelectron photoion coincidence (PEPICO) spectrometer that combines high mass resolution of cations with independently adjustable velocity map imaging of both cations and electrons. We photoionize atoms and molecules using fixed-frequency vacuum ultraviolet radiation. Mass-resolved photoelectron spectra associated with each cation's mass-to-charge ratio can be obtained by inversion of the photoelectron image. The mass-resolved photoelectron spectra enable kinetic time-resolved probing of chemical reactions with isomeric resolution using fixed-frequency radiation sources amenable to small laboratory settings. The instrument accommodates a variety of sample delivery sources to explore a broad range of physical chemistry. To demonstrate the time-resolved capabilities of the instrument, we study the 193 nm photodissociation of SO2 via the CÌ(1B2) â XÌ(1A1) transition. In addition to the well-documented O(3Pj) + SO(3Σ-) channel, we observe direct evidence for a small yield of S(3Pj) + O2(3Σg-) as a primary photodissociation product channel, which may impact sulfur mass-independent fractionation chemistry.
ABSTRACT
The absolute photoionization cross section of vinyl alcohol was determined by multiplexed photoionization mass spectrometry of the Norrish type II photodissociation of butanal at 308 nm. The measured cross sections at 10.005 and 10.205 eV are 7.5 ± 1.9 and 8.1 ± 1.9 MB, respectively. A higher signal-to-noise ratio photoionization spectrum of vinyl alcohol was recorded via the pyrolysis of 2-chloroethanol and scaled to the absolute cross sections measured using the Norrish type II method. From a comparison of our spectrum with previously reported photoelectron spectra we conclude that vinyl alcohol is mainly ionized by direct ionization in the energy range of 9-9.6 eV, whereas autoionization is responsible for the steady rise in the photoionization spectrum above the end of the Franck-Condon envelope at 9.9 eV.
ABSTRACT
Methanol is a benchmark for understanding tropospheric oxidation, but is underpredicted by up to 100% in atmospheric models. Recent work has suggested this discrepancy can be reconciled by the rapid reaction of hydroxyl and methylperoxy radicals with a methanol branching fraction of 30%. However, for fractions below 15%, methanol underprediction is exacerbated. Theoretical investigations of this reaction are challenging because of intersystem crossing between singlet and triplet surfaces - â¼45% of reaction products are obtained via intersystem crossing of a pre-product complex - which demands experimental determinations of product branching. Here we report direct measurements of methanol from this reaction. A branching fraction below 15% is established, consequently highlighting a large gap in the understanding of global methanol sources. These results support the recent high-level theoretical work and substantially reduce its uncertainties.
ABSTRACT
Water is one of the most fundamental molecules in chemistry, biology and astrophysics. It exists as two distinct nuclear-spin isomers, para- and ortho-water, which do not interconvert in isolated molecules. The experimental challenges in preparing pure samples of the two isomers have thus far precluded a characterization of their individual chemical behavior. Capitalizing on recent advances in the electrostatic deflection of polar molecules, we separate the ground states of para- and ortho-water in a molecular beam to show that the two isomers exhibit different reactivities in a prototypical reaction with trapped diazenylium ions. Based on ab initio calculations and a modelling of the reaction kinetics using rotationally adiabatic capture theory, we rationalize this finding in terms of different rotational averaging of ion-dipole interactions during the reaction.
ABSTRACT
Many molecules exhibit multiple conformers that often easily interconvert under thermal conditions. Therefore, single conformations are difficult to isolate which renders the study of their distinct chemical reactivities challenging. We have recently reported a new experimental method for the characterization of conformer-specific effects in chemical reactions [Y.-P. Chang, K. Dlugolecki, J. Küpper, D. Rösch, D. Wild, and S. Willitsch, "Specific chemical reactivities of spatially separated 3-aminophenol conformers with cold Ca(+) ions," Science 342, 98-101 (2013)]. Different conformers are spatially separated using inhomogeneous electric fields and reacted with a Coulomb crystal of cold, spatially localized ions in a trap. As a first application, we studied reactions between the two conformers of 3-aminophenol and Ca(+). We observed a twofold larger rate constant for the cis compared to the trans conformer which was rationalized in terms of the differences in the long-range ion-molecule interactions. The present article provides a detailed description of the new method and a full account of the experimental results as well as the accompanying theoretical calculations.
ABSTRACT
Many molecules exhibit multiple rotational isomers (conformers) that interconvert thermally and are difficult to isolate. Consequently, a precise characterization of their role in chemical reactions has proven challenging. We have probed the reactivity of specific conformers by using an experimental technique based on their spatial separation in a molecular beam by electrostatic deflection. The separated conformers react with a target of Coulomb-crystallized ions in a trap. In the reaction of Ca(+) with 3-aminophenol, we find a twofold larger rate constant for the cis compared with the trans conformer (differentiated by the O-H bond orientation). This result is explained by conformer-specific differences in the long-range ion-molecule interaction potentials. Our approach demonstrates the possibility of controlling reactivity through selection of conformational states.
ABSTRACT
After flavonol glycosides, monomeric flavan-3-ols, and dimeric and trimeric proanthocyanidins were fractionated from an extract of sea buckthorn (Hippophae rhamnoides) pomace by Sephadex LH-20 gel chromatography, oligomeric proanthocyanidins were eluted. The oligomeric fraction accounted for 84% of the total proanthocyanidins and 75% of the total antioxidant activity of the sea buckthorn pomace extract. To elucidate the structure of the oligomeric fraction, it was depolymerized by acid catalysis in the presence of phloroglucinol. The structure of the resulting flavan-3-ol monomers and flavan-3-ol-phloroglucinol adducts was determined by electrospray ionization mass spectrometry (ESI-MS) and (1)H and (13)C nuclear magnetic resonance (NMR) spectroscopy. Quantitative high-performance liquid chromatography investigations demonstrated (+)-gallocatechin as the predominating subunit in the oligomeric fraction. This observation was confirmed by ESI-MS, matrix-assisted laser desorption/ionization mass spectrometry, and (13)C NMR spectroscopy. The results showed that the majority of the flavan-3-ol subunits possessed a 2,3-trans configuration. The oligomers consisted mainly of prodelphinidin subunits whereas procyanidins were present in smaller amounts, indicating a very uncommon composition of the sea buckthorn proanthocyanidins. The mean degree of polymerization of the oligomeric proanthocyanidins was between 6 and 9.
Subject(s)
Antioxidants/isolation & purification , Hippophae/chemistry , Proanthocyanidins/isolation & purification , Flavonols/chemistry , Flavonols/isolation & purification , Magnetic Resonance Spectroscopy , Molecular Structure , Proanthocyanidins/chemistry , Spectrometry, Mass, Electrospray Ionization , Spectrometry, Mass, Matrix-Assisted Laser Desorption-IonizationABSTRACT
Four flavonol glycosides were isolated from an extract of sea buckthorn pomace (Hippophaë rhamnoides) by Sephadex LH-20 gel chromatography and semipreparative HPLC. Their structures were elucidated by hydrolysis studies, ESI-MS(n), UV, and (1)H and (13)C NMR spectroscopy. The occurrence of the major flavonol glycoside kaempferol 3-O-beta-sophoroside-7-O-alpha-rhamnoside in sea buckthorn is described here for the first time. A further 21 flavonol glycosides of Sephadex LH-20 fractions of sea buckthorn pomace were characterized by HPLC-DAD-ESI-MS. The characteristic MS-MS and MS(3) fragmentation pattern of flavonol glycosides previously identified in sea buckthorn juice and of flavonol glycosides identified by NMR spectroscopy gave valuable indications for their identification. The results demonstrate that loss of the sugar moiety from C-7 of the aglycon is more favored than fission of the glycosidic linkage at the C-3 position. Thus, most of the compounds identified were 7-rhamnosides of isorhamnetin, kaempferol, and quercetin, which exhibit different substitution patterns at the C-3 position, mainly glucosides, rutinosides, and sophorosides. In addition, numerous flavonol glycosides were detected lacking a sugar moiety at C-7. Finally, eight flavonol derivatives were identified that are acylated by hydroxybenzoic or hydoxycinnamic acids.
Subject(s)
Chromatography, High Pressure Liquid , Flavonols/chemistry , Glycosides/chemistry , Hippophae/chemistry , Magnetic Resonance Spectroscopy , Spectrometry, Mass, Electrospray Ionization , Flavonoids/analysis , Flavonoids/chemistry , Flavonols/analysis , Glycosides/analysis , Molecular StructureABSTRACT
The phenolic composition of juice derived from fruits of sea buckthorn (Hippophae rhamnoides) was investigated by high-performance liquid chromatography (HPLC) with diode array and electrochemical detection. Flavonols were found to be the predominating polyphenols while phenolic acids and catechins represent minor components. Of the seven flavonols identified, isorhamnetin 3-O-glycosides were the most important representatives quantitatively. However, because of their structural properties, they were poor radical scavengers as shown by electron spin resonance spectroscopy. Phenolic compounds such as quercetin 3-O-glycosides, catechins, and hydroxybenzoic acids with a catechol structure exhibited good antioxidant capacities, but their concentration in sea buckthorn juice was small. These phenolic compounds, determined by HPLC, accounted for less than 5% of the total antioxidant activity of the filtered juice. Ascorbic acid was shown to be the major antioxidant in sea buckthorn juice. Because of its high concentration of 1.22 g/L, it contributes approximately 75% to total antioxidant activity. The remaining difference can be attributed to higher molecular weight flavan-3-ols (proanthocyanidins), which were determined photometrically after acid depolymerization to colored anthocyanidins.