Artificial Intelligence-Enhanced Metasurfaces for Instantaneous Measurements of Dispersive Refractive Index.

Measurements of the refractive index of liquids are in high demand in numerous fields such as agriculture, food and beverages, and medicine. However, conventional ellipsometric refractive index measurements are too expensive and labor-intensive for consumer devices, while Abbe refractometry is limited to the measurement at a single wavelength. Here, a new approach is proposed using machine learning to unlock the potential of colorimetric metasurfaces for the real-time measurement of the dispersive refractive index of liquids over the entire visible spectrum. The platform with a proof-of-concept experiment for measuring the concentration of glucose is further demonstrated, which holds a profound impact in non-invasive medical sensing. High-index-dielectric metasurfaces are designed and fabricated, while their experimentally measured reflectance and reflected colors, through microscopy and a standard smartphone, are used to train deep-learning models to provide measurements of the dispersive background refractive index with a resolution of ≈10-4, which is comparable to the known index as measured with ellipsometry. These results show the potential of enabling the unique optical properties of metasurfaces with machine learning to create a platform for the quick, simple, and high-resolution measurement of the dispersive refractive index of liquids, without the need for highly specialized experts and optical procedures.

Integrated triboelectric nanogenerator and radiative cooler for all-weather transparent glass surfaces.

Sustainable energies from weather are the most ubiquitous and non-depleted resources. However, existing devices exploiting weather-dependent energies are sensitive to weather conditions and geographical locations, making their universal applicability challenging. Herein, we propose an all-weather sustainable glass surface integrating a triboelectric nanogenerator and radiative cooler, which serves as a sustainable device, harvesting energy from raindrops and saving energy on sunny days. By systematically designing transparent, high-performance triboelectric layers, functioning as thermal emitters simultaneously, particularly compatible with radiative cooling components optimized with an evolutionary algorithm, our proposed device achieves optimal performance for all-weather-dependent energies. We generate 248.28 Wm-2 from a single droplet with an energy conversion ratio of 2.5%. Moreover, the inner temperature is cooled down by a maximum of 24.1 °C compared to pristine glass. Notably, as the proposed device is realized to provide high transparency up to 80% in the visible range, we are confident that our proposed device can be applied to versatile applications.

The rise of electrically tunable metasurfaces.

Metasurfaces, which offer a diverse range of functionalities in a remarkably compact size, have captured the interest of both scientific and industrial sectors. However, their inherent static nature limits their adaptability for their further applications. Reconfigurable metasurfaces have emerged as a solution to this challenge, expanding the potential for diverse applications. Among the series of tunable devices, electrically controllable devices have garnered particular attention owing to their seamless integration with existing electronic equipment. This review presents recent progress reported with respect to electrically tunable devices, providing an overview of their technological development trajectory and current state of the art. In particular, we analyze the major tuning strategies and discuss the applications in spatial light modulators, tunable optical waveguides, and adaptable emissivity regulators. Furthermore, the challenges and opportunities associated with their implementation are explored, thereby highlighting their potential to bridge the gap between electronics and photonics to enable the development of groundbreaking optical systems.

Waveguide-integrated metasurfaces for multi-channel crosstalk-free holography.

Limited information capacity and inter-channel crosstalk in metaholograms hinder their practical use in display applications. Leveraging waveguide-based metasurfaces, the integration of spin and angle-of-incidence multiplexing facilitates the generation of broadband six-channel metaholograms free from crosstalk.

Metasurface-Embedded Contact Lenses for Holographic Light Projection.

Contact lenses have been instrumental in vision correction and are expected to be utilized in augmented reality (AR) displays through the integration of electronic and optical components. In optics, metasurfaces, an array of sub-wavelength nanostructures, have offered optical multifunctionality in an ultra-compact form factor, facilitating integration into various imaging, and display systems. However, transferring metasurfaces onto contact lenses remains challenging due to the non-biocompatible materials of extant imprinting methods and the structural instability caused by the swelling and shrinking of the wetted surface. Here, a biocompatible method is presented to transfer metasurfaces onto contact lenses using hyaluronic acid (HA) as a soft mold and to allow for holographic light projection. A high-efficiency metahologram is obtained with an all-metallic 3D meta-atom enhanced by the anisotropy of a rectangular structure, and a reflective background metal layer. A corrugated metal layer on the HA mold is supported with a SiO2 capping layer, to avoid unwanted wrinkles and to ensure structural stability when transferred to the surface of pliable and wettable contact lenses. Biocompatible method of transferring metasurfaces onto contact lenses promises the integration of diverse optical components, including holograms, lenses, gratings and more, to advance the visual experience for AR displays and human-computer interfaces.

Ultrafast Metaphotonic PCR Chip with Near-Perfect Absorber.

Polymerase chain reaction (PCR) is the gold standard for nucleic acid amplification and quantification in diverse fields such as life sciences, global health, medicine, agricultural science, forensic science, and environmental science for global sustainability. However, implementing a cost-effective PCR remains challenging for rapid preventive medical action to the widespread pandemic diseases due to the absence of highly efficient and low-cost PCR chip-based POC molecular diagnostics. Here, this work reports an ultrafast metaphotonic PCR chip as a solution of a cost-effective and low-power-consumption POC device for the emerging global challenge of sustainable healthcare. This work designs a near-perfect photonic meta-absorber using ring-shaped titanium nitride to maximize the photothermal effect and realize rapid heating and cooling cycles during the PCR process. This work fabricates a large-area photonic meta-absorber on a 6-inch wafer cost-effectively using simple colloidal lithography. In addition, this work demonstrates 30 thermocycles from 65 (annealing temperature) to 95 °C (denaturation temperature) within 3 min 15 s, achieving an average 16.66 °C s-1 heating rate and 7.77 °C s-1 cooling rate during thermocycling, succeeding rapid metaphotonic PCR. This work believes a metaphotonic PCR chip can be used to create a low-cost, ultrafast molecular diagnostic chip with a meta-absorber.

Printable Spin-Multiplexed Metasurfaces for Ultraviolet Holographic Displays.

Multiplexed ultraviolet (UV) metaholograms, which are capable of displaying multiple holographic images from a single-layer device, are promising for enhancing tamper resistance and functioning as optical encryption devices. Despite considerable interest in optical security, the commercialization of UV metaholograms encounters obstacles, such as high-resolution patterning and material choices. Here, we realize spin-multiplexed UV metaholograms using a high-throughput printable platform that incorporates a zirconium dioxide (ZrO2) particle-embedded resin (PER). Utilizing ZrO2 PER, which is transparent and exhibits a refractive index of approximately 1.8 at 320 nm, we fabricated a single device capable of encoding dual holographic information depending on polarization states is fabricated. We demonstrate UV metaholograms achieving efficiencies of 56.23% with left circularly polarized incident beams and 57.28% with right circularly polarized incident beams. These multiplexed UV metaholograms fabricated using a one-step platform enable real-world applications in anticounterfeiting and encryption.

Chemically and geometrically programmable photoreactive polymers for transformational humidity-sensitive full-color devices.

Humidity-sensitive structural color has emerged as a promising technology due to its numerous advantages that include fast response, intuitiveness, stand-alone capability, non-toxicity, as well as resistance to thermal and chemical stresses. Despite immense technological advancements, these structural colors lack the ability to present independent multiple images through transformation. Herein, we present an approach to address this constraint by introducing a chemically and geometrically programmable photoreactive polymer which allows preparation of transformational humidity-sensitive full-color devices. Utilizing azido-grafted carboxymethyl cellulose (CMC-N3) allows adjustments in swelling properties based on the grafting ratio (Γ) of azido groups upon UV-induced crosslinking. Also, the distinctive photo-curability of the polymer enables precise geometric control to achieve vivid colors in combination with disordered plasmonic cavities. Our work culminates in the development of an advanced anti-counterfeiting multiplexer capable of displaying different full-color images with variation in humidity levels. The showcased color displays signify pivotal breakthroughs in tunable optical technologies, illustrating how chemical modifications in hydrogels provides additional degrees of freedom in the design of advanced optical devices.

Polarization-independent edge detection based on the spin-orbit interaction of light.

In previous edge detection schemes based on the spin-orbit interaction of light, the direction and intensity of the edge-enhanced images are influenced by the incident polarization state. In this study, we develop an edge detection strategy that is insensitive to changes in both the incident polarization and the incident angle. The output intensity and transfer function remain entirely impervious to changes in incident polarization, being explicitly formulated as functions of the incident angle, specifically in terms of cot 2⁡θ i and cot⁡θ i , respectively. This behavior is attributed to the opposing nature of the polarization components E~r H-H and E~r V-V in the x-direction after undergoing mapping through the Glan polarizer, while the sum of polarization components E~r H-V and E~r V-H in the y-direction can be simplified to terms independent of incident polarization. Furthermore, we propose a metasurface design to achieve the required optical properties in order to realize the derived edge detection scheme.

Printable Light-Emitting Metasurfaces with Enhanced Directional Photoluminescence.

Nanoimprint lithography is gaining popularity as a cost-efficient way to reproduce nanostructures in large quantities. Recent advances in nanoimprinting lithography using high-index nanoparticles have demonstrated replication of photonic devices, but it is difficult to confer special properties on nanostructures beyond general metasurfaces. Here, we introduce a novel method for fabricating light-emitting metasurfaces using nanoimprinting lithography. By utilizing quantum dots embedded in resin, we successfully imprint dielectric metasurfaces that function simultaneously as both emitters and resonators. This approach to incorporating quantum dots into metasurfaces demonstrates an improvement in photoluminescence characteristics compared to the situation where quantum dots and metasurfaces are independently incorporated. Design of the metasurface is specifically tailored to support photonic modes within the emission band of quantum dots with a large enhancement of photoluminescence. This study indicates that nanoimprinting lithography has the capability to construct nanostructures using functionalized nanoparticles and could be used in various fields of nanophotonic applications.

3D Intelligent Cloaked Vehicle Equipped with Thousand-Level Reconfigurable Full-Polarization Metasurfaces.

A crucial aspect in shielding a variety of advanced electronic devices from electromagnetic detection involves controlling the flow of electromagnetic waves, akin to invisibility cloaks. Decades ago, the exploration of transformation optics heralded the dawn of modern invisibility cloaks, which has stimulated immense interest across various physical scenarios. However, most prior research is simplified to low-dimensional and stationary hidden objects, limiting their practical applicability in a dynamically changing world. This study develops a 3D large-scale intelligent cloak capable of remaining undetectable even in non-stationary conditions. By employing thousand-level reconfigurable full-polarization metasurfaces, this work has achieved an exceptionally high degree of freedom in sculpting the scattering waves as desired. Serving as the core computational unit, a hybrid inverse design enables the cloaked vehicle to respond in real-time, with a rapid reaction time of just 70 ms. These experiments integrate the cloaked vehicle with a perception-decision-control-execution system and evaluate its performance under random static positions and dynamic travelling trajectories, achieving a background scattering matching degree of up to 93.3%. These findings establish a general paradigm for the next generation of intelligent meta-devices in real-world settings, potentially paving the way for an era of "Electromagnetic Internet of Things."

Azimuthal rotation-controlled nanoinscribing for continuous patterning of period- and shape-tunable asymmetric nanogratings.

We present an azimuthal-rotation-controlled dynamic nanoinscribing (ARC-DNI) process for continuous and scalable fabrication of asymmetric nanograting structures with tunable periods and shape profiles. A sliced edge of a nanograting mold, which typically has a rectangular grating profile, slides over a polymeric substrate to induce its burr-free plastic deformation into a linear nanopattern. During this continuous nanoinscribing process, the "azimuthal angle," that is, the angle between the moving direction of the polymeric substrate and the mold's grating line orientation, can be controlled to tailor the period, geometrical shape, and profile of the inscribed nanopatterns. By modulating the azimuthal angle, along with other important ARC-DNI parameters such as temperature, force, and inscribing speed, we demonstrate that the mold-opening profile and temperature- and time-dependent viscoelastic polymer reflow can be controlled to fabricate asymmetric, blazed, and slanted nanogratings that have diverse geometrical profiles such as trapezoidal, triangular, and parallelogrammatic. Finally, period- and profile-tunable ARC-DNI can be utilized for the practical fabrication of diverse optical devices, as is exemplified by asymmetric diffractive optical elements in this study.

Intrinsically topological second Chern insulator via synthetic dimensions.

Exploring Hidden Dimensions: Unveiling Topological Crystals in a 4D Space.

Angle-Resolved Polarimetry with Quasi-Bound States in the Continuum Plasmonic Metamaterials via 3D Aerosol Nanoprinting.

Three-dimensional (3D) plasmonic metamaterials, featuring well-arranged subwavelength nanostructures, facilitate effective coupling between electrical dipoles and incident electromagnetic waves. This coupling allows for unique optical responses including localized surface plasmon resonance (LSPR) and quasi-bound states in the continuum (q-BIC). While 3D plasmonic metamaterials with LSPR and q-BIC have been independently explored for sensors, achieving simultaneous optical responses in the near-infrared region remains challenging. Here, we present 3D plasmonic metamaterials that integrate LSPR and q-BIC within a single π-shaped plasmonic structure, fabricated using a 3D aerosol nanoprinting technique. This printing technique controls the local electrostatic field to precisely position charged metallic nanoaerosols, enabling parallel printing of π-shaped plasmonic structures under ambient conditions. The printed π-shaped plasmonic structures exhibit two distinct optical modes: x-polarization-sensitive LSPR and transverse magnetic mode-sensitive q-BIC within the near-infrared region. Exploiting these dual optical responses, we demonstrate simultaneous polarization detection and incident angle analysis by integrating the π-shaped plasmonic structures into commercial Fourier-transform infrared spectroscopy, termed "numerical aperture-detective polarimetry". This approach holds promise for evaluating alignment in optical and imaging systems with light distribution analysis. Furthermore, the 3D aerosol nanoprinting technique provides an avenue for fabricating 3D plasmonic metamaterials with intricate geometries and optical properties, expanding their potential applications in nano-optics.

A water-soluble label for food products prevents packaging waste and counterfeiting.

Sustainability, humidity sensing and product origin are important features of food packaging. While waste generated from labelling and packaging causes environmental destruction, humidity can result in food spoilage during delivery and counterfeit-prone labelling undermines consumer trust. Here we introduce a food label based on a water-soluble nanocomposite ink with a high refractive index that addresses these issues. By patterning the nanocomposite ink using nanoimprint lithography, the resultant metasurface shows bright and vivid structural colours. This method makes it possible to quickly and inexpensively create patterns on large surfaces. A QR code is also developed that can provide up-to-date information on food products. Microprinting hidden in the QR code protects against counterfeiting, cannot be physically detached or replicated and may be used as a humidity indicator. Our proposed food label can reduce waste while ensuring customers receive accurate product information.

Tailoring high-refractive-index nanocomposites for manufacturing of ultraviolet metasurfaces.

Nanoimprint lithography (NIL) has been utilized to address the manufacturing challenges of high cost and low throughput for optical metasurfaces. To overcome the limitations inherent in conventional imprint resins characterized by a low refractive index (n), high-n nanocomposites have been introduced to directly serve as meta-atoms. However, comprehensive research on these nanocomposites is notably lacking. In this study, we focus on the composition of high-n zirconium dioxide (ZrO2) nanoparticle (NP) concentration and solvents used to produce ultraviolet (UV) metaholograms and quantify the transfer fidelity by the measured conversion efficiency. The utilization of 80 wt% ZrO2 NPs in MIBK, MEK, and acetone results in conversion efficiencies of 62.3%, 51.4%, and 61.5%, respectively, at a wavelength of 325 nm. The analysis of the solvent composition and NP concentration can further enhance the manufacturing capabilities of high-n nanocomposites in NIL, enabling potential practical use of optical metasurfaces.