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Flexible electronics, also referred to as printable electronics, represent an interesting technology for implementing electronic circuits via depositing electronic devices onto flexible substrates, boosting their possible applications. Among all flexible electronics, interdigitated electrodes (IDEs) are currently being used for different sensor applications since they offer significant benefits beyond their functionality as capacitors, like the generation of high output voltage, fewer fabrication steps, convenience of application of sensitive coatings, material imaging capability and a potential of spectroscopy measurements via electrical excitation frequency variation. This review examines the role of IDEs in printed and flexible electronics since they are progressively being incorporated into a myriad of applications, envisaging that the growth pattern will continue in the next generations of flexible circuits to come.
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Here, we propose a microfluidic paper-based analytical device (µPAD) implemented with a near-field communication (NFC) tag as a portable, simple and fast colorimetric method for glutathione (GSH) determination. The proposed method was based on the fact that Ag+ could oxidize 3,3',5,5'-tetramethylbenzidine (TMB) into oxidized blue TMB. Thus, the presence of GSH could cause the reduction of oxidized TMB, which resulted in a blue color fading. Based on this finding, we developed a method for the colorimetric determination of GSH using a smartphone. A µPAD implemented with the NFC tag allowed the harvesting of energy from a smartphone to activate the LED that allows the capture of a photograph of the µPAD by the smartphone. The integration between electronic interfaces into the hardware of digital image capture served as a means for quantitation. Importantly, this new method shows a low detection limit of 1.0 µM. Therefore, the most important features of this non-enzymatic method are high sensitivity and a simple, fast, portable and low-cost determination of GSH in just 20 min using a colorimetric signal.
Subject(s)
Colorimetry , Glutathione , Colorimetry/methods , Benzidines , Smartphone , Limit of DetectionABSTRACT
Functional nanomaterials have become one of the most fascinating fields in nanotechnology [...].
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This case report presents a real example of a study which introduces the use of reconfigurable platforms in the teaching of electronics engineering to establish a bridge between theory and practice. This gap is one of the major concerns of the electronics engineering students. Different strategies, such as simulation tools or breadboard implementations, have been followed so far to make it easier for students to practice what they study in lectures. However, many students still claim to have problems when they face real practical implementations. The use of reconfigurable platforms as a teaching tool is proposed to provide the students the possibility of fast experimentation, reducing both development time and the learning curve. In addition, reconfigurable platforms available on the market make this methodology suitable to be applied throughout the different courses of their curricula. The feasibility of this approach is demonstrated in a course at the M.Eng. level, where the objective is the study, design and development of electronic sensor nodes. We firmly consider, based on the students' results and reflections collected during the course, that this methodology helps students to address the theoretical framework from a practical viewpoint, as well as to acquire some of the fundamental skills for their professional careers, such as the usage of communication protocols and embedded systems programming, in a more intuitive way when compared to traditional teaching methodologies.
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Herein, we present the syntheses of a novel coordination polymer (CP) based on the perylene-3,4,9,10-tetracarboxylate (pery) linkers and sodium metal ions. We have chosen sodium metal center with the aim of surmising the effect that the modification of the metal ion may have on the relative humidity (RH) experimental measurements of the material. We confirm the role of the ions in the functionalization of the deposited layer by modifying their selectivity towards moisture content, paving the way to the generation of sensitive and selective chemical sensors.
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Tetracycline (TC) is a widely known antibiotic used worldwide to treat animals. Its residues in animal-origin foods cause adverse health effects to consumers. Low-cost and real-time measuring systems of TC in food samples are, therefore, extremely needed. In this work, a three-electrode sensitive and label-free sensor was developed to detect TC residues from milk and meat extract samples, using CO2 laser-induced graphene (LIG) electrodes modified with gold nanoparticles (AuNPs) and a molecularly imprinted polymer (MIP) used as a synthetic biorecognition element. LIG was patterned on a polyimide (PI) substrate, reaching a minimum sheet resistance (Rsh) of 17.27 ± 1.04 Ω/sq. The o-phenylenediamine (oPD) monomer and TC template were electropolymerized on the surface of the LIG working electrode to form the MIP. Surface morphology and electrochemical techniques were used to characterize the formation of LIG and to confirm each modification step. The sensitivity of the sensor was evaluated by differential pulse voltammetry (DPV), leading to a limit of detection (LOD) of 0.32 nM, 0.85 nM, and 0.80 nM in buffer, milk, and meat extract samples, respectively, with a working range of 5 nM to 500 nM and a linear response range between 10 nM to 300 nM. The sensor showed good LOD (0.32 nM), reproducibility, and stability, and it can be used as an alternative system to detect TC from animal-origin food products.
Subject(s)
Graphite , Metal Nanoparticles , Molecular Imprinting , Animals , Anti-Bacterial Agents , Electrochemical Techniques , Electrodes , Gold , Lasers , Limit of Detection , Meat , Milk , Molecularly Imprinted Polymers , Polymers , Reproducibility of Results , TetracyclineABSTRACT
In this letter, we present the extension of a previous work on a cost-effective method for fabricating highly sensitive humidity sensors on flexible substrates with a reversible response, allowing precise monitoring of the humidity threshold. In that work we demonstrated the use of three-dimensional metal-organic framework (MOF) film deposition based on the perylene-3,4,9,10-tetracarboxylate linker, potassium as metallic center and the interspacing of silver interdigitated electrodes (IDEs) as humidity sensors. In this work, we study one of the most important issues in efficient and reproducible mass production, which is to optimize the most important processes' parameters in their fabrication, such as controlling the thickness of the sensor's layers. We demonstrate this method not only allows for the creation of humidity sensors, but it also is possible to change the humidity value that changes the actuator state.
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This work presents an innovative application of carbon dots (Cdots) nanoparticles as sensing layer for relative humidity detection. The developed sensor is based on interdigitated capacitive electrodes screen printed on a flexible transparent polyethylene terephthalate (PET) film. Cdots are deposited on top of these electrodes. An exhaustive characterization of the nanoparticles has been conducted along with the fabrication of the sensor structure. The accompanied experiments give all the sensibility to the Cdots, showing its dependence with temperature and exciting frequency. To the best of our knowledge, this work paves the path to the use of these kind of nanoparticles in printed flexible capacitive sensors aimed to be employed in the continuously expanding Internet of Things ecosystem.
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Although the number of Internet of Things devices increases every year, efforts to decrease hardware energy demands and to improve efficiencies of the energy-harvesting stages have reached an ultra-low power level. However, no current standard of wireless communication protocol (WCP) can fully address those scenarios. Our focus in this paper is to introduce treNch, a novel WCP implementing the cross-layer principle to use the power input for adapting its operation in a dynamic manner that goes from pure best-effort to nearly real time. Together with the energy-management algorithm, it operates with asynchronous transmissions, synchronous and optional receptions, short frame sizes and a light architecture that gives control to the nodes. These features make treNch an optimal option for wireless sensor networks with ultra-low power demands and severe energy fluctuations. We demonstrate through a comparison with different modes of Bluetooth Low Energy (BLE) a decrease of the power consumption in 1 to 2 orders of magnitude for different scenarios at equal quality of service. Moreover, we propose some security optimizations, such as shorter over-the-air counters, to reduce the packet overhead without decreasing the security level. Finally, we discuss other features aside of the energy needs, such as latency, reliability or topology, brought again against BLE.
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Capacitive sensors are an active research area with multiple advantages and great applicability [...].
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This work demonstrates a cost-effective manufacturing method of flexible and fully printed microheaters, using carbon nanotubes (CNTs) as the heating element. Two different structures with different number of CNT layers have been characterized in detail. The benchmarking has been carried out in terms of maximum operating temperature, as well as nominal resistance and input power for different applied voltages. Their performances have been compared with previous reports for similar devices, fabricated with other technologies. The results have shown that the heaters presented can achieve high temperatures in a small area at lower voltages and lower input power. In particular, the fully printed heaters fabricated on a flexible substrate covering an area of 3.2 mm2 and operating at 9.5 V exhibit a maximum temperature point above 70 °C with a power consumption below 200 mW. Therefore, we have demonstrated that this technology paves the way for a cost-effective large-scale fabrication of flexible microheaters aimed to be integrated in flexible sensors.
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Herein, we present, for the first time, a 2D-MOF based on copper and 4-hydroxypyrimidine-5-carbonitrile as the linker. Each MOF layer is perfectly flat and neutral, as is the case for graphene. High pressure X-ray diffraction measurements reveal that this layered structure can be modulated between 3.01 to 2.78 Å interlayer separation, with an evident piezochromism and varying conductive properties. An analysis of the band structure indicates that this material is conductive along different directions depending on the application of pressure or H doping. These results pave the way for the development of novel layered materials with tunable and efficient properties for pressure-based sensors.
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In this review paper, we summarize the latest advances in the field of capacitive sensors fabricated by printing techniques. We first explain the main technologies used in printed electronics, pointing out their features and uses, and discuss their advantages and drawbacks. Then, we review the main types of capacitive sensors manufactured with different materials and techniques from physical to chemical detection, detailing the main substrates and additives utilized, as well as the measured ranges. The paper concludes with a short notice on status and perspectives in the field.
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In this paper, we present a simple, fast, and cost-effective method for the large-scale fabrication of high-sensitivity humidity sensors on flexible substrates. These sensors consist of a micro screen-printed capacitive structure upon which a sensitive layer is deposited. We studied two different structures and three different sensing materials by modifying the concentration of poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT:PSS) in a graphene oxide (GO) solution. The results show that the aggregation of the PEDOT:PSS to the GO can modify its electrical properties, boosting the performance of the capacitive sensors in terms of both resistive losses and sensitivity to relative humidity (RH) changes. Thus, in an area less than 30 mm2, the GO/PEDOT:PSS-based sensors can achieve a sensitivity much higher (1.22 nF/%RH at 1 kHz) than other similar sensors presented in the literature which, together with their good thermal stability, time response, and performance over bending, demonstrates that the manufacturing approach described in this work paves the way for the mass production of flexible humidity sensors in an inexpensive way.
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Solid-state gas sensors are a cost-effective and well-spread alternative to conventional gas sensing, employable in most environments, ranging from homes and offices to harsh industrial scenarios. The emergence of carbon nanotubes (CNTs) as sensing material in solid-state gas sensors paved the way to a new class of devices, which are semitransparent, flexible, and with a remarkably low environmental impact. These devices, however, lack selectivity to other gases and concurring physical phenomena, such as temperature and pressure changes. In this contribution, we show how by measuring the impedance of CNT-based gas sensors at different frequencies, it is possible to evaluate sensitivity coefficient for the immediate compensation of moisture content in the air, while still preserving in the considered ranges of average sensitivities as high as 0.045, 0.112, 7.842 × 10-5, and 0.041 % Z/ppm for ammonia, carbon dioxide, carbon monoxide and ethanol gas, respectively. With this simple approach, it will be possible to develop simple sensor read-out systems, with reduced external electronic, simplifying the route to low-cost and low-power sensor nodes for the internet of things.
Subject(s)
Ammonia/analysis , Carbon Dioxide/analysis , Carbon Monoxide/analysis , Ethanol/analysis , Humidity , Nanotubes, Carbon/chemistry , Electrochemical Techniques/instrumentation , Electrochemical Techniques/methods , ElectrodesABSTRACT
In this paper, we demonstrate the feasibility of realization of transparent gas sensors based on carbon nanotubes (CNTs). Both sensing layer and electrodes consist of CNTs deposited by spray deposition. The transparent sensor-with a transmittance higher than 60% in both sensing layer and electrodes-is characterized towards NH3 and CO2 and compared with a reference sensor with the same active layer but evaporated Au electrodes. In particular, the sensitivity towards NH3 is virtually identical for both reference and transparent sensors, whereas the transparent device exhibits higher sensitivity to CO2 than the reference electrode. The effect of the spacing among consecutive electrodes is also studied, demonstrating that a wider spacing in fully CNT based sensors results in a higher sensitivity because of the higher sensing resistance, whereas this effect was not observed in gold electrodes, as their resistance can be neglected with respect to the resistance of the CNT sensing layer. Overall, the transparent sensors show performance comparable-if not superior-to the traditionally realized ones, opening the way for seamlessly integrated sensors, which do not compromise on quality.
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In this paper, we present a simple and inexpensive method for the fabrication of high-performance graphene-based heaters on different large-scale substrates through the laser photothermal reduction of graphene oxide (laser-reduced graphene-oxide, LrGO). This method allows an efficient and localized high level of reduction and therefore a good electrical conductivity of the treated films. The performance of the heaters is studied in terms of steady-state temperature, power consumption, and time response for different substrates and sizes. The results show that the LrGO heaters can achieve stable steady-state temperatures higher than 200 °C when a voltage of 15 V is applied, featuring a time constant of around 4 s and a heat transfer coefficient of ~200 °C cm2/W. These characteristics are compared with other technologies in this field, demonstrating that the fabrication approach described in this work is competitive and promising to fabricate large-scale flexible heaters with a very fast response and high steady-state temperatures in a cost-effective way. This technology can be easily combined with other fabrication methods, such as screen printing or spray-deposition, for the manufacturing of complete sensing systems where the temperature control is required to adjust functionalities or to tune sensitivity or selectivity.
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In this work, we report on a fabrication protocol to produce fully inkjet-printed temperature sensors on a bendable polyethylene terephthalate (PET) substrate. The sensing layer is made of polymer-based Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) ink that is electrically contacted by an underlying interdigitated electrode (IDE) structure based on a silver nanoparticle (AgNP) ink. Both inks are available commercially, and no further ink processing is needed to print them using a cost-effective consumer printer with standard cartridges. The fabricated sensor modules are tested for different IDE dimensions and post-deposition treatments of the AgNP film for their response to a temperature range of 20 to 70 °C and moisture range of 20 to 90% RH (relative humidity). Attributed to the higher initial resistance, sensor modules with a larger electrode spacing of 200 µm show a higher thermal sensitivity that is increased by a factor of 1.8 to 2.2 when compared to sensor modules with a 150 µm-spacing. In all cases, the sensors exhibit high linearity towards temperature and a response comparable to state of the art.
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In this article, we report on an efficient post-treatment protocol for the manufacturing of pristine single-walled carbon nanotube (SWCNT) films. To produce an ink for the deposition, the SWCNTs are dispersed in an aqueous solution with the aid of a carboxymethyl cellulose (CMC) derivative as the dispersing agent. On the basis of this SWCNT-ink, ultra-thin and uniform films are then fabricated by spray-deposition using a commercial and fully automated robot. By means of X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), we show that the CMC matrix covering the CNTs can be fully removed by an immersion treatment in HNO3 followed by thermal annealing at a moderate temperature of 100 °C, in the ambient air. We propose that the presented protocols for the ink preparation and the post-deposition treatments can in future serve as a facile and efficient platform for the fabrication of high-quality and residual-free SWCNT films. The purity of SWCNT films is of particular importance for sensing applications, where residual-induced doping and dedoping processes distort the contributions from the sensing specimen. To study the usability of the presented films for practical applications, gas sensors are fabricated and characterized with the CNT-films as the sensing material, screen printed silver-based films for the interdigitated electrode (IDE) structure, and polyimide as a flexible and robust substrate. The sensors show a high and stable response of 11% to an ammonia (NH3) test gas, at a concentration of 10 ppm.
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In this work, we report on the fabrication and characterization of sub-300 nm electrode films based on solution-processed silver nanoparticles (AgNPs). Following the deposition of the electrode material using a scalable and homogenous spray process, the films are treated with thermal or photonic sintering to promote the coalescence of the nanoparticles and in turn decrease the resistivity of the films. After sintering, a resistivity of 63 ± 13 nΩ m is achieved for the AgNP films, which is only by a factor of four larger than the literature value for bulk silver. Both post-deposition treatments show a similar performance with regard to the achieved resistivity. However, photonic sintering avoids the need for thermal annealing at substrate temperatures of 150 °C and above. In addition, the photonic sintering process can easily be embedded in a roll-to-roll process and is extremely fast with light exposure times below 3 ms. Thus, this manufacturing technique paves the way for the use of flexible substrates in electronics. As a simple and practical application, we present the use of AgNP films for antennas operating in the 5 GHz band on flexible polyethylene terephthalate substrate. An original coplanar design is employed for the fabrication of antennas with a single conductive layer that exhibit a maximum return loss and radiation of -27 dB and 95%, respectively.