Feasibility of using diamond-like carbon films in total joint replacements: a review.

Diamond-like Carbon (DLC) has been used as a coating material of choice for a variety of technological applications owing to its favorable bio-tribo-thermo-mechanical characteristics. Here, the possibility of bringing DLC into orthopedic joint implants is examined. With ever increasing number of patients suffering from osteoarthritis as well as with the ingress of the osteoarthritic joints' malaise into younger and more active demographics, there is a pressing need to augment the performance and integrity of conventional total joint replacements (TJRs). Contemporary joint replacement devices use metal-on-polymer articulations to restore function to worn, damaged or diseased cartilage. The wear of polymeric components has been addressed using crosslinking and antioxidants; however, in the context of the metallic components, complications pertaining to corrosion and metal ion release inside the body still persist. Through this review article, we explore the use of DLC coatings on metallic bearing surfaces and elucidate why this technology might be a viable solution for ongoing electrochemical challenges in orthopedics. The different characteristics of DLC coatings and their feasibility in TJRs are examined through assessment of tribo-material characterization methods. A holistic characterization of the coating-substrate interface and the wear performance of such systems are discussed. As with all biomaterials used in TJRs, we need mindful consideration of potential in-vivo challenges. We present a few caveats for DLC coatings including delamination, hydrophobicity, and other conflicting as well as outdating findings in the literature. We recommend prudently exploring DLC films as potential coatings on metallic TJR components to solve the problems pertaining to wear, metal ion release, and corrosion. Ultimately, we advise bringing DLC into clinical use only after addressing all challenges and concerns outlined in this article.

Novel Au/Cu2NiSnS4 Nano-Heterostructure: Synthesis, Structure, Heterojunction Band Offset and Alignment, and Interfacial Charge Transfer Dynamics.

Considering the importance of physics and chemistry at material interfaces, we have explored the coupling of multinary chalcogenide semiconductor Cu2NiSnS4 nanoparticles (CNTS NPs) for the first time with the noble metal (Au) to form Au-CNTS nano-heterostructures (NHSs). The Au-CNTS NHSs is synthesized by a simple facile hot injection method. Synergistic experimental and theoretical approaches are employed to characterize the structural, optical, and electrical properties of the Au-CNTS NHSs. The absorption spectra demonstrate enhanced and broadened optical absorption in the ultraviolet-visible-near-infrared (UV-Vis-NIR) region, which is corroborated by cyclic voltammetry (CV) readings. CV measurements show type II staggered band alignment, with a conduction band offset (CBO) of 0.21 and 0.23 eV at the Au-CNTS/CdS and CNTS/CdS interface, respectively. Complementary first-principles density functional theory (DFT) calculations predict the formation of a stable Au-CNTS NHSs, with the Au nanoparticle transferring its electrons to the CNTS. Moreover, our interface analysis using ultrafast transient absorption experiments demonstrate that the Au-CNTS NHSs facilitates efficient transport and separation of photoexcited charge carriers when compared to pristine CNTS. The transient measurements further reveal a plasmonic electronic transfer from the Au nanoparticle to CNTS. Our advanced analysis and findings will prompt investigations into new functional materials and their photo/electrocatalysis and optoelectronic device applications in the future.

Heterostructured WO3-TiVO4 thin-film photocatalyst for efficient photoelectrochemical water splitting.

Photoelectrochemical water splitting via solar irradiation has garnered significant interest due to its potential in large-scale renewable hydrogen production. Heterostructure materials have emerged as an effective strategy, demonstrating enhanced performance in photoelectrochemical water-splitting applications compared to individual photocatalysts. In this study, to augment the performance of sprayed TiVO4 thin films, a hydrothermally prepared WO3 underlayer was integrated beneath the spray pyrolised TiVO4 film. The consequent heterostructure demonstrated notable enhancements in optical, structural, microstructural attributes, and photocurrent properties. This improvement is attributed to the strategic deposition of WO3 underlayer, forming a heterostructure composite electrode. This led to a marked increase in photocurrent density for the WO3/TiVO4 photoanode, reaching a peak of 740 µA/cm2 at an applied potential of 1.23 V vs RHE, about nine-fold that of standalone TiVO4. Electrochemical impedance spectroscopy revealed a reduced semicircle for the heterostructure, indicating improved charge transfer compared to bare TiVO4. The heterostructure photoelectrode exhibited enhanced charge carrier conductivity at the interface and sustained stability over 3 h. The distinct attributes of heterostructure photoelectrode present significant opportunities for devising highly efficient sunlight-driven water-splitting systems.

Shape-Stabilized PEGylated Silica Aerogel-Composite as an Energy Saving Building Material.

Balancing thermal and visual comfort in buildings necessitates effective insulation to counteract heat loss and gain, especially with temperature variances. One promising approach is to combine phase change materials, such as poly(ethylene glycol) (PEG), with high-performance insulators like silica aerogel (Siag). To bolster opto-thermal performance in building envelopes, we introduce a smart insulation composite material through PEG integration, i.e., PEGalyation with Siag. Central to this thermal behavior is the PEG's phase change properties, which foster a shape-stabilized framework with Siag through their porous confinement. Preliminary observations indicate notable capabilities of obstructing near-infrared light while preserving satisfactory visible transparency. An optimized Siag@PEG composite with 5% loading of PEG has the visible range transmission of ∼92%, a decrease of ∼72% in thermal conductivity which is lower than pure glass and PEG, leading to a temperature dependent switchable hydrophobic to hydrophilic wettability characteristics. As a prototype window, the thermal performance evaluation of the synthesized composite, through experimental and computational studies, shows a decrease in indoor temperature of ∼20% with a higher temperature difference of ∼20 °C between outdoor and indoor weather conditions. This lightweight composite can act as sponge media to fill inside the double-paned window and for retrofitting existing glazing to boost the energy efficiency of buildings with facile manufacturing and scalability.

Interfacial band offset engineering with barium-doping towards enhanced performance of all inorganic CsPbI2Br perovskite solar cells.

This study investigates the incorporation of Ba2+ at a low concentration into CsPbI2Br, resulting in the formation of mixed CsPb1-xBaxI2Br perovskite films. Photovoltaic devices utilizing these Ba-doped CsPbI2Br (Ba-CsPbI2Br) perovskite films achieved a higher stabilized power conversion efficiency of 14.07% compared to 11.60% for pure CsPbI2Br films. First-principles density functional theory calculations indicate that the improved device performance can be attributed to the efficient transport of conduction electrons across the interface between Ba-CsPbI2Br and the TiO2 electron transporting layer (ETL). The Ba-CsPbI2Br/TiO2 interface exhibits a type-II staggered band alignment with a smaller conduction band offset (CBO) of 0.25 eV, in contrast to the CsPbI2Br/TiO2 interface with a CBO of 0.48 eV. The reduced CBO at the Ba-CsPbI2Br/TiO2 interface diminishes the barrier for conduction electrons to transfer from the Ba-CsPbI2Br layer to the TiO2 layer, facilitating efficient charge transport.

Fabrication and Characterization of Tantalum-Iron Composites for Photocatalytic Hydrogen Evolution.

Photocatalytic hydrogen evolution represents a transformative avenue in addressing the challenges of fossil fuels, heralding a renewable and pristine alternative to conventional fossil fuel-driven energy paradigms. Yet, a formidable challenge is crafting a high-efficacy, stable photocatalyst that optimizes solar energy transduction and charge partitioning even under adversarial conditions. Within the scope of this investigation, tantalum-iron heterojunction composites characterized by intricate, discoidal nanostructured materials were meticulously synthesized using a solvothermal-augmented calcination protocol. The X-ray diffraction, coupled with Rietveld refinements delineated the nuanced alterations in phase constitution and structural intricacies engendered by disparate calcination thermal regimes. An exhaustive study encompassing nano-morphology, electronic band attributes, bandgap dynamics, and a rigorous appraisal of their photocatalytic prowess has been executed for the composite array. Intriguingly, the specimen denoted as 1000-1, a heterojunction composite of TaO2/Ta2O5/FeTaO4, manifested an exemplary photocatalytic hydrogen evolution capacity, registering at 51.24 µmol/g, which eclipses its counterpart, 1100-1 (Ta2O5/FeTaO4), by an impressive margin. Such revelations amplify the prospective utility of these tantalum iron matrices, endorsing their candidacy as potent agents for sustainable hydrogen production via photocatalysis.

Effective Hydrogen Production from Alkaline and Natural Seawater using WO3-x@CdS1-x Nanocomposite-Based Electrocatalysts.

Offshore hydrogen production through water electrolysis presents significant technical and economic challenges. Achieving an efficient hydrogen evolution reaction (HER) in alkaline and natural seawater environments remains daunting due to the sluggish kinetics of water dissociation. To address this issue, we synthesized electrocatalytic WO3-x@CdS1-x nanocomposites (WCSNCs) using ultrasonic-assisted laser irradiation. The synthesized WCSNCs with varying CdS contents were thoroughly characterized to investigate their structural, morphological, and electrochemical properties. Among the samples tested, the WCSNCs with 20 wt % CdS1-x in WO3-x (Wx@Sx-20%) exhibited superior electrocatalytic performance for hydrogen evolution in a 1 M KOH solution. Specifically, the Wx@Sx-20% catalyst demonstrated an overpotential of 0.191 V at a current density of -10 mA/cm2 and a Tafel slope of 61.9 mV/dec. The Wx@Sx-20% catalysts demonstrated outstanding stability and durability, maintaining their performance after 24 h and up to 1000 CV cycles. Notably, when subjected to natural seawater electrolysis, the Wx@Sx-20% catalysts outperformed in terms of electrocatalytic HER activity and stability. The remarkable performance enhancement of the prepared electrocatalyst can be attributed to the combined effect of sulfur vacancies in CdS1-x and oxygen vacancies in WO3-x. These vacancies promote the electrochemically active surface area, enhance the rate of charge separation and transfer, increase the number of electrocatalytic active sites, and accelerate the HER process in alkaline and natural seawater environments.

Synergistic Photoelectrochemical and Photocatalytic Properties of the Cobalt Nanoparticles-Embedded TiVO4 Thin Film.

To optimize the semiconductor properties of TiVO4 thin films and enhance their performance, we incorporated cobalt nanoparticles as an effective co-catalyst consisting of a non-noble metal. Through an investigation into the impact of cobalt loading on spray pyrolyzed TiVO4 thin films, we observed a significant enhancement in the photoelectrochemical (PEC) performance. This was accomplished by carefully optimizing the concentrations of Co2+ (3 mM) to fabricate a composite electrode, resulting in a higher photocurrent density for the TiVO4:Co photoanode. When an applied potential of 1.23 V (vs RHE) was used, the photocurrent density reached 450 µA/cm2, approximately 5 times higher than that of bare TiVO4. We conducted a thorough characterization of the composite structure and optical properties. Additionally, electrochemical impedance spectroscopy analysis indicated that the TiVO4/Co thin film exhibited a smaller semicircle, indicating a significant improvement in charge transfer at the interface. In comparison to bare TiVO4, the TiVO4/Co composite exhibited a notable improvement in photocatalytic activity when degrading methylene blue (MB) dye, a widely employed model dye. Under light illumination, a TiVO4/Co thin film exhibited a notable dye degradation rate of 97% within a 45 min duration. The scalability of our fabrication method makes it suitable for large-area devices intended for sunlight-driven PEC seawater splitting studies.

Robust control of water quality in horizontal sub-surface flow wetlands using decentralized quantitative feedback theory based controller.

This paper addresses the regulation of water quality influencers such as Organic Nitrogen, Ammonia Nitrogen, Nitrate Nitrogen, Dissolved Organic Carbon and Dissolved Oxygen for a sub-surface flow horizontal wetland in a controlled environment. The plant uncertainty is quantified by using measurement data. The robust control of the process is achieved using a decentralized quantitative feedback theory based control strategy. The control structure also employs a feed-forward mechanism to minimize loop interactions and feedback control to ensure stability, tracking and disturbance rejection. The numerical simulations and hardware-in-loop implementation show that the performance specifications are robustly met.

Advancing Thermoelectric Materials: A Comprehensive Review Exploring the Significance of One-Dimensional Nano Structuring.

Amidst the global challenges posed by pollution, escalating energy expenses, and the imminent threat of global warming, the pursuit of sustainable energy solutions has become increasingly imperative. Thermoelectricity, a promising form of green energy, can harness waste heat and directly convert it into electricity. This technology has captivated attention for centuries due to its environmentally friendly characteristics, mechanical stability, versatility in size and substrate, and absence of moving components. Its applications span diverse domains, encompassing heat recovery, cooling, sensing, and operating at low and high temperatures. However, developing thermoelectric materials with high-performance efficiency faces obstacles such as high cost, toxicity, and reliance on rare-earth elements. To address these challenges, this comprehensive review encompasses pivotal aspects of thermoelectricity, including its historical context, fundamental operating principles, cutting-edge materials, and innovative strategies. In particular, the potential of one-dimensional nanostructuring is explored as a promising avenue for advancing thermoelectric technology. The concept of one-dimensional nanostructuring is extensively examined, encompassing various configurations and their impact on the thermoelectric properties of materials. The profound influence of one-dimensional nanostructuring on thermoelectric parameters is also thoroughly discussed. The review also provides a comprehensive overview of large-scale synthesis methods for one-dimensional thermoelectric materials, delving into the measurement of thermoelectric properties specific to such materials. Finally, the review concludes by outlining prospects and identifying potential directions for further advancements in the field.

An overview of the tribological and mechanical properties of PEEK and CFR-PEEK for use in total joint replacements.

Poly-ether-ether-ketone (PEEK) and PEEK composites are outstanding candidates for biomedical applications, such as orthopedic devices, where biocompatibility and modulus match with surrounding tissue are requisite for long-term success. The mechanical properties can be optimized by incorporating fillers such as continuous and chopped carbon fibers. While much is known about the mechanical and tribological behavior of PEEK composites, there are few articles that summarize the viability of using PEEK reinforced with carbon fibers in orthopedic implants. This paper reviews biocompatibility, tribological, and mechanical studies on PEEK and their composites with carbon fibers, notably PEEK reinforced with polyacrylonitrile (PAN)-based carbon fibers and PEEK reinforced with pitch-based carbon fibers, for application in orthopedics and total joint replacements (TJRs). The main objectives of this review are two-fold. Firstly, this paper aims to assist designers in making informed decisions on the suitability of using PEEK and PEEK composites in orthopedic applications; as it is not well understood how these materials perform on the whole in orthopedics and TJRs. Secondly, this paper aims to serve as a centralized paper in which researchers can gain information on the tribological and mechanical advancements of PEEK and PEEK composites.

Effectual visible light photocatalytic reduction of para-nitro phenol using reduced graphene oxide and ZnO composite.

Removing wastewater pollutants using semiconducting-based heterogeneous photocatalysis is an advantageous technique because it provides strong redox power charge carriers under sunlight irradiation. In this study, we synthesized a composite of reduced graphene oxide (rGO) and zinc oxide nanorods (ZnO) called rGO@ZnO. We established the formation of type II heterojunction composites by employing various physicochemical characterization techniques. To evaluate the photocatalytic performance of the synthesized rGO@ZnO composite, we tested it for reducing a common wastewater pollutant, para-nitro phenol (PNP), to para-amino phenol (PAP) under both ultraviolet (UV) and visible light irradiances. The rGOx@ZnO (x = 0.5-7 wt%) samples, comprising various weights of rGO, were investigated as potential photocatalysts for the reduction of PNP to PAP under visible light irradiation. Among the samples, rGO5@ZnO exhibited remarkable photocatalytic activity, achieving a PNP reduction efficiency of approximately 98% within a short duration of four minutes. These results demonstrate an effective strategy and provide fundamental insights into removing high-value-added organic water pollutants.

Certified high-efficiency "large-area" perovskite solar module for Fresnel lens-based concentrated photovoltaics.

The future of energy generation is well in tune with the critical needs of the global economy, leading to more green innovations and emissions-abatement technologies. Introducing concentrated photovoltaics (CPVs) is one of the most promising technologies owing to its high photo-conversion efficiency. Although most researchers use silicon and cadmium telluride for CPV, we investigate the potential in nascent technologies, such as perovskite solar cell (PSC). This work constitutes a preliminary investigation into a "large-area" PSC module under a Fresnel lens (FL) with a "refractive optical concentrator-silicon-on-glass" base to minimize the PV performance and scalability trade-off concerning the PSCs. The FL-PSC system measured the solar current-voltage characteristics in variable lens-to-cell distances and illuminations. The PSC module temperature was systematically studied using the COMSOL transient heat transfer mechanism. The FL-based technique for "large-area" PSC architectures is a promising technology that further facilitates the potential for commercialization.

Role of vanadium ions substitution on spinel MnCo2O4 towards enhanced electrocatalytic activity for hydrogen generation.

Improving efficient electrocatalysts (ECs) for hydrogen generation through water splitting is of significant interest in tackling the upcoming energy crisis. Sustainable hydrogen generation is the primary prerequisite to realizing the future hydrogen economy. This work examines the electrocatalytic activity of hydrothermally prepared vanadium doped MnCo spinel oxide microspheres (MC), MnVxCo2-xO4 (Vx-MnCo MC, where x ≤ 0.4) in the HER (hydrogen evolution reaction) process. Magnetization measurements demonstrated a paramagnetic (at high temperatures) to a ferrimagnetic (at low temperatures) transition below the Curie temperature (Tc) in all the samples. The magnetization is found to intensify with the rising vanadium content of MCs. The optimized catalyst Vx-MnCo MCs (x = 0.3) outperformed other prepared ECs with a Tafel slope of 84 mV/dec, a low onset potential of 78.9 mV, and a low overpotential of 85.9 mV at a current density of 10 mA/cm2, respectively. The significantly improved HER performance of hydrothermally synthesized Vx-MnCo MCs (x = 0.3) is principally attributable to many exposed active sites, accelerated electron transport at the EC/electrolyte interface, and remarkable electron spectroscopy for chemical analysis (ECSA) value was found ~ 11.4 cm2. Moreover, the Vx-MnCo MCs (x = 0.3) electrode exhibited outstanding electrocatalytic stability after exposure to 1000 cyclic voltametric cycles and 36 h of chronoamperometric testing. Our results suggest a feasible route for developing earth-abundant transition metal oxide-based EC as a superior electrode for future water electrolysis applications.

Fabrication of TiVO4 photoelectrode for photoelectrochemical application.

Photoelectrochemical (PEC) water splitting is one of the promising, environmentally friendly, carbon emission-free strategies for the cost-effective production of hydrogen. The interest in developing effective approaches for solar-to-hydrogen production with stable and visible light active semiconductors directed many researchers to develop stable and efficient materials. For the first time, a nanostructured TiVO4 photoanode was fabricated at a substrate temperature of 250 °C and further annealed at 600 °C using the spray pyrolysis technique and it obtained an optical band gap of ∼2.18 eV. The photoanode underwent photoelectrochemical testing, where it exhibited a high photocurrent density of 0.080 mA cm-2 at 1.23 V (vs. reversible hydrogen electrode), which can be stable up to 110 min. Further, various physicochemical characterizations were employed to understand the phase purity and thin film growth mechanism. A systematic substrate and annealed temperatures were monitored during the fabrication process. The transmission electron microscopy (TEM) studies revealed agglomeration of TiVO4 nanoparticles with an average size of ∼100 nm accompanying dendritic orientation at the outer edge. This study envisages the design and development of a novel photocatalyst for water splitting under visible light irradiation, an ideal route to a cost-effective, large-scale, sustainable route for hydrogen production.

An enduring in vitro wound healing phase recipient by bioactive glass-graphene oxide nanocomposites.

Bioactive glass (BG) is an interesting topic in soft tissue engineering because of its biocompatibility and bonding potential to increase fibroblast cell proliferation, synthesize growth factors, and stimulate granulation tissue development. The proposed BG with and without sodium (Na), prepared by the sol-gel method, is employed in wound healing studies. The BG/graphene oxide (GO) and BG (Na-free)/GO nanocomposites were investigated against fibroblast L929 cells in vitro; the 45S5 BG nanocomposites exhibited desired cell viability (80%), cell proliferation (30%), cell migration (25%), metabolic activity, and wound contraction due to extracellular matrix (ECM) production and enhanced protein release by fibroblast cells. Additionally, the antioxidant assays for BG, BG (Na-free), GO, and BG/GO, BG (Na-free)/GO were evaluated for effective wound healing properties. The results showed decreased inflammation sites in the wound area, assessed by the (2,2-diphenyl-1-picryl-hydrazyl-hydrate) (DPPH) assay with ~ 80% radical scavenging activity, confirming their anti-inflammatory and improved wound healing properties.

A nonenzymatic reduced graphene oxide-based nanosensor for parathion.

Organophosphate-based pesticides (e.g., parathion (PT)) have toxic effects on human health through their residues. Therefore, cost-effective and rapid detection strategies need to be developed to ensure the consuming food is free of any organophosphate-residue. This work proposed the fabrication of a robust, nonenzymatic electrochemical-sensing electrode modified with electrochemically reduced graphene oxide (ERGO) to detect PT residues in environmental samples (e.g., soil, water) as well as in vegetables and cereals. The ERGO sensor shows a significantly affected electrocatalytic reduction peak at -0.58 V (vs Ag/AgCl) for rapid quantification of PT due to the amplified electroactive surface area of the modified electrode. At optimized experimental conditions, square-wave voltammetric analysis exhibits higher sensitivity (50.5 µA·µM-1·cm-2), excellent selectivity, excellent stability (≈180 days), good reproducibility, and repeatability for interference-free detection of PT residues in actual samples. This electrochemical nanosensor is suitable for point-of-care detection of PT in a wide dynamic range of 3 × 10-11-11 × 10-6 M with a lower detection limit of 10.9 pM. The performance of the nanosensor was validated by adding PT to natural samples and comparing the data via absorption spectroscopy. PT detection results encourage the design of easy-to-use nanosensor-based analytical tools for rapidly monitoring other environmental samples.

Synergistic Effect of Paraffin-Incorporated In2O3/ZnO Multifold Smart Glazing Composite for the Self-Cleaning and Energy-Saving Built Environment.

The thermal performance of window glazing requires improvement for a sustainable built environment at an acceptable cost. The current work demonstrates a multifold smart composite consisting of an optimized In2O3/ZnO-polymethyl methacrylate-paraffin composite to reduce heat exchange through the combined self-cleaning and energy-saving envelope of the smart built environment. This work has attempted to develop a smart composite coating that combines photosensitive metal oxide and phase change materials and investigate their thermal comfort performance as a glazed window. It is observed that the In2O3/ZnO (5 wt %) multifold composite film experienced better transmittance and thermal performance compared to its other wt % composite samples. Moreover, the multifold composite-coated glass integrated into a prototype glazed window was further investigated for its thermal performance, where a steady average indoor temperature of ∼30 °C was achieved when the outside temperature reached ∼55 °C, while maintaining good visibility. Interestingly, the transparency reached ∼86% at 60 °C and exhibited a hydrophobic water contact angle (WCA) of ∼138°. In contrast, a similar film exhibits ∼64% transparency at 22 °C, where the WCA becomes moderately hydrophilic (∼68°). Temperature dependency on transparency and wettability properties was examined for up to 60 cycles, resulting in excellent indoor thermal comfort. In addition, a thermal simulation study was executed for the smart multifold glazing composite. Moreover, this study offers dynamic glazing development options for energy saving in the smart built environment.

Microbial fuel cells for mineralization and decolorization of azo dyes: Recent advances in design and materials.

Microbial fuel cells (MFCs) exhibit tremendous potential in the sustainable management of dye wastewater via degrading azo dyes while generating electricity. The past decade has witnessed advances in MFC configurations and materials; however, comprehensive analyses of design and material and its association with dye degradation and electricity generation are required for their industrial application. MFC models with high efficiency of dye decolorization (96-100%) and a wide variation in power generation (29.4-940 mW/m2) have been reported. However, only 28 out of 104 studies analyzed dye mineralization - a prerequisite to obviate dye toxicity. Consequently, the current review aims to provide an in-depth analysis of MFCs potential in dye degradation and mineralization and evaluates materials and designs as crucial factors. Also, structural and operation parameters critical to large-scale applicability and complete mineralization of azo dye were evaluated. Choice of materials, i.e., bacteria, anode, cathode, cathode catalyst, membrane, and substrate and their effects on power density and dye decolorization efficiency presented in review will help in economic feasibility and MFCs scalability to develop a self-sustainable solution for treating azo dye wastewater.

Cotton soot derived carbon nanoparticles for NiO supported processing temperature tuned ambient perovskite solar cells.

The emergence of perovskite solar cells (PSCs) in a "catfish effect" of other conventional photovoltaic technologies with the massive growth of high-power conversion efficiency (PCE) has given a new direction to the entire solar energy field. Replacing traditional metal-based electrodes with carbon-based materials is one of the front-runners among many other investigations in this field due to its cost-effective processability and high stability. Carbon-based perovskite solar cells (c-PSCs) have shown great potential for the development of large scale photovoltaics. First of its kind, here we introduce a facile and cost-effective large scale carbon nanoparticles (CNPs) synthesis from mustard oil assisted cotton combustion for utilization in the mesoporous carbon-based perovskite solar cell (PSC). Also, we instigate two different directions of utilizing the carbon nanoparticles for a composite high temperature processed electrode (HTCN) and a low temperature processed electrode (LTCN) with detailed performance comparison. NiO/CNP composite thin film was used in high temperature processed electrodes, and for low temperature processed electrodes, separate NiO and CNP layers were deposited. The HTCN devices with the cell structure FTO/c-TiO2/m-TiO2/m-ZrO2/high-temperature NiO-CNP composite paste/infiltrated MAPI (CH3NH3PbI3) achieved a maximum PCE of 13.2%. In addition, high temperature based carbon devices had remarkable stability of ~ 1000 h (ambient condition), retaining almost 90% of their initial efficiency. In contrast, LTCN devices with configuration FTO/c-TiO2/m-TiO2/m-ZrO2/NiO/MAPI/low-temperature CNP had a PCE limit of 14.2%, maintaining ~ 72% of the initial PCE after 1000 h. Nevertheless, we believe this promising approach and the comparative study between the two different techniques would be highly suitable and adequate for the upcoming cutting-edge experimentations of PSC.