Regulation of quantum spin conversions in a single molecular radical.

Free radicals, generally formed through the cleavage of covalent electron-pair bonds, play an important role in diverse fields ranging from synthetic chemistry to spintronics and nonlinear optics. However, the characterization and regulation of the radical state at a single-molecule level face formidable challenges. Here we present the detection and sophisticated tuning of the open-shell character of individual diradicals with a donor-acceptor structure via a sensitive single-molecule electrical approach. The radical is sandwiched between nanogapped graphene electrodes via covalent amide bonds to construct stable graphene-molecule-graphene single-molecule junctions. We measure the electrical conductance as a function of temperature and track the evolution of the closed-shell and open-shell electronic structures in real time, the open-shell triplet state being stabilized with increasing temperature. Furthermore, we tune the spin states by external stimuli, such as electrical and magnetic fields, and extract thermodynamic and kinetic parameters of the transition between closed-shell and open-shell states. Our findings provide insights into the evolution of single-molecule radicals under external stimuli, which may proof instrumental for the development of functional quantum spin-based molecular devices.

Elucidating the structure of donor-acceptor conjugated polymer aggregates in liquid solution.

High-spin donor-acceptor conjugated polymers are extensively studied for their potential applications in magnetic and spintronic devices. Inter-chain charge transfer among these high-spin polymers mainly depends on the nature of the local structure of the thin film and π-stacking between the polymer chains. However, the microscopic structural details of high-spin polymeric materials are rarely studied with an atomistic force field, and the molecular-level local structure in the liquid phase remains ambiguous. Here, we have examined the effects of oligomer chain length, side chain, and processing temperature on the organization of the high-spin cyclopentadithiophene-benzobisthiadiazole donor-acceptor conjugated polymer in chloroform solvent. We find that the oligomers display ordered aggregates whose structure depends on their chain length, with an average π-stacking distance of 3.38 ± 0.03 Å (at T = 298 K) in good agreement with the experiment. Also, the oligomers with longer alkyl side chains show better solvation and a shorter π-stacking distance. Furthermore, the clusters grow faster at higher temperature with more ordered aggregation between the oligomer chains.

Non-Aufbau orbital ordering and spin density modulation in high-spin donor-acceptor conjugated polymers.

High-spin ground-state organic materials with unique spin topology can significantly impact molecular magnetism, spintronics, and quantum computing devices. However, strategies to control the spin topology and alignment of the unpaired spins in different molecular orbitals are not well understood. Here, we report modulating spin distribution along the molecular backbone in high-spin ground-state donor-acceptor (D-A) conjugated polymers. Density functional theory calculations indicate that substitution of different heteroatoms (such as C, Si, N, and Se) alters the aromatic character in the thiadiazole unit of the benzobisthiadiazole (BBT) acceptor and modulates the oligomer length to result in high-spin triplet ground-state, orbital and spin topology. The C, Si, and Se atom substituted polymers show a localized spin density at the two opposite ends of the polymers. However, a delocalized spin distribution is observed in the N substituted polymer. We find that the hybridization (sp3vs. sp2) of the substituent atom plays an important role in controlling the electronic structure of these materials. This study shows that atomistic engineering is an efficient technique to tune the spin topologies and electronic configurations in the high-spin ground-state donor-acceptor conjugated polymers, compelling synthetic targets for room-temperature magnetic materials.

Evolution of the electronic structure in open-shell donor-acceptor organic semiconductors.

Most organic semiconductors have closed-shell electronic structures, however, studies have revealed open-shell character emanating from design paradigms such as narrowing the bandgap and controlling the quinoidal-aromatic resonance of the π-system. A fundamental challenge is understanding and identifying the molecular and electronic basis for the transition from a closed- to open-shell electronic structure and connecting the physicochemical properties with (opto)electronic functionality. Here, we report donor-acceptor organic semiconductors comprised of diketopyrrolopyrrole and naphthobisthiadiazole acceptors and various electron-rich donors commonly utilized in constructing high-performance organic semiconductors. Nuclear magnetic resonance, electron spin resonance, magnetic susceptibility measurements, single-crystal X-ray studies, and computational investigations connect the bandgap, π-extension, structural, and electronic features with the emergence of various degrees of diradical character. This work systematically demonstrates the widespread diradical character in the classical donor-acceptor organic semiconductors and provides distinctive insights into their ground state structure-property relationship.

Donor-Acceptor Conjugated Macrocycles with Polyradical Character and Global Aromaticity.

Polyradical character and global aromaticity are fundamental concepts that govern the rational design of cyclic conjugated macromolecules for optoelectronic applications. Here, we report donor-acceptor (D-A) conjugated macromolecules with and without π-spacer derivatives to tune the antiferromagnetic couplings between the unpaired electrons. The macromolecules without π-spacer have a closed-shell electronic configuration and show global nonaromatic character in the singlet and lowest triplet states. However, the derivatives with π-spacer develop a nearly pure open-shell diradical and a very high polyradical character, not reported for D-A type macromolecules. Furthermore, the π-spacer derivatives display global nonaromaticity in the singlet ground state, but global aromaticity in the lowest triplet state, according to Baird's rule. The absorption spectra of the open-shell macromolecules calculated with time-dependent density functional theory indicate intensive light absorption in the near-infrared region and broadening to 2,500 nm, making these materials suitable for numerous optoelectronic applications.

Iodine binding with thiophene and furan based dyes for DSCs.

Iodine binding to thiophene rings in dyes for dye-sensitized solar cells (DSCs) has been hypothesized to be performance degrading in a number of literature cases. Binding of iodine to dyes near the semiconductor surface can promote undesirable electron transfers and lower the overall efficiency of devices. Six thiophene or furan containing dye analogs were synthesized to analyze iodine binding to the dyes via Raman spectroscopy, UV-Vis studies, device performance metrics and density functional theory (DFT) based computations. Evidence suggests I2 binds thiophene-based dyes stronger than furan-based dyes. This leads to higher DSC device currents and voltages from furan analogues, and longer electron lifetimes in DSC devices using furan based dyes. Raman spectrum of the TiO2 surface-bound dyes reveals additional and more instense peaks for thiophene dyes in the presence of I2 relative to no I2. Additionally, broader and shifted UV-Vis peaks are observed for thiophene dyes in the presence of I2 on TiO2 films suggesting significant interaction between the dye molecules and I2. These observations are also supported by DFT and TD-DFT calculations which indicate the absence of a key geometric energy minimum in the dye-I2 ground state for furan dyes which are readily observed for the thiophene based analogues.