Fabrication of the PES Membrane Embedded with Plasma-Modified Zeolite at Different O2 Pressures.

In this research, the non-thermal glow discharge plasma process was implemented to modify the surface of natural clinoptilolite zeolite before incorporation into the polyethersulfone (PES) membrane. The influence of plasma gas pressure variation on the fouling resistance and separation performance of the prepared membranes was studied. Fourier transform infrared, field emission scanning electron microscopy, and X-ray diffraction analyses of the unmodified and modified clinoptilolites revealed the Si-OH-Al bond's development during plasma treatment and the change in surface characteristics. In terms of performance, increasing the plasma gas pressure during clinoptilolite treatment resulted in the twofold enhancement of water flux from 91.2 L/m2 h of bare PES to 188 L/m2 h of the membrane containing plasma-treated clinoptilolite at 1.0 Torr pressure. Meanwhile, the antifouling behavior of membranes was improved by introducing more hydrophilic functional groups derived from the plasma treatment process. Additionally, the enhanced dye separation of membranes was indicated by the separation of 99 and 94% of reactive green 19 and reactive red 195, respectively.

Simultaneous separation and degradation of methylene blue by a thin film nanocomposite membrane containing TiO2/MWCNTs nanophotocatalyst.

ABSTRACTAn innovative photocatalytic thin film nanocomposite (TFN) membrane was prepared and used for the simultaneous separation/degradation of methylene blue (MB) under UV irradiation. For this purpose, we used the sol-gel method to prepare the TiO2/MWCNTs nanophotocatalyst and added to the 1,3-phenylenediamine (MPD) solution during interfacial polymerization (IP) of 1,3,5-benzenetricarbonyl chloride (TMC) and 1,3-phenylenediamine monomers on the polysulfone (PSF) support. Using scanning electron microscopy (SEM) analysis and studying the cross-sectional images of membrane samples, it was revealed that the polyamide (PA) thin layer was well fabricated over the support membrane. The attendance of the TiO2/MWCNTs nanophotocatalyst in the PA thin layer of TFN samples was also proved using EDX (energy-dispersive X-ray) analysis. According to the results of the contact angle (CA), it is clear that the hydrophilicity of membrane samples first increased and then decreased by enhancing the TiO2/MWCNTs nanophotocatalyst content in the PA thin layer. In comparison with the pristine thin film composite (TFC) membrane, TFN samples showed higher water flux and MB removal when they were exposed to UV light. Finally, it turned out that the TFN membrane comprising 0.2 wt. % TiO2/MWCNTs nanophotocatalyst (TFN 0.2) had the foremost efficiency among TFNs with the water flux of 13 L/m2·hr and dye separation/degradation of almost 100% under UV irradiation.

Fabrication of Ti2SnC-MAX Phase Blended PES Membranes with Improved Hydrophilicity and Antifouling Properties for Oil/Water Separation.

In this research work, the Ti2SnC MAX phase (MP) was synthesized via the reactive sintering procedure. The layered and crystalline structure of this MP was verified by SEM, HRTEM, and XRD analyses. This nano-additive was used for improvement of different features of the polyethersulfone (PES) polymeric membranes. The blended membranes containing diverse quantities of the MP (0-1 wt%) were fabricated by a non-solvent-induced phase inversion method. The asymmetric structure of the membranes with small holes in the top layer and coarse finger-like holes and macro-voids in the sublayer was observed by applying SEM analysis. The improvement of the membrane's hydrophilicity was verified via reducing the contact angle of the membranes from 63.38° to 49.77° (for bare and optimum membranes, respectively). Additionally, in the presence of 0.5 wt% MP, the pure water flux increased from 286 h to 355 L/m2 h. The average roughness of this membrane increased in comparison with the bare membrane, which shows the increase in the filtration-available area. The high separation efficiency of the oil/water emulsion (80%) with an improved flux recovery ratio of 65% was illustrated by the optimum blended membrane.

A review on the applications of ultrasonic technology in membrane bioreactors.

Membrane bioreactors (MBRs) have received increasing attention in the field of wastewater treatment in recent years. However, membrane fouling is the main problem of MBRs, limiting their widespread and large applications. Membrane cleaning methods can be mainly classified into four types including chemical, physical, physico-chemical and biological clean the fouled membrane. In recent years, ultrasonication has been reported as a promising cleaning technique for the membranes fouled in MBRs. Ultrasonic irradiation can clean the fouled membrane by creating important physical phenomena including microjets, microstreams and shock waves. Moreover, the ultrasonic method can be combined with other cleaning methods e.g. chemical cleaning and backwashing in order to improve the cleaning efficiency. It should be noted that the application of ultrasonic in the MBR system is not limited to the cleaning of membrane. The pretreatment of the wastewater by ultrasonic irradiation or ultrasound coupled with other methods, e.g. ozonation, prior to MBR system, can decrease the organic loading of the wastewater and subsequently postpone the fouling of the membrane. This paper critically reviews the recent advances in the applications of ultrasound in MBR systems. Emerging issues associated with application of on-line ultrasound and also hybrid on-line ultrasound for controlling the membrane fouling in MBR systems are critically reviewed. Moreover, application of the ultrasound in ex-situ form for cleaning the fouled membranes and pretreatment of wastewater prior to the MBR system is discussed.

Sonocatalytic performance of Er-doped ZnO for degradation of a textile dye.

Pure and erbium (Er)-doped ZnO samples were synthesized through a sonochemical method and characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-Vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) analysis. The synthesized samples were used as a catalyst for the sonocatalytic decolorization of Reactive Orange 29 (RO29) as a model organic pollutant. The decolorization efficiency was 63%, 68%, 88%, and 75% for undoped, 2%, 4%, and 6% Er-doped ZnO, respectively. The effect of different experimental parameters including catalyst content, dye concentration and ultrasound power was investigated on the sonocatalytic decolorization of RO29. Among several radical scavengers (i.e. chloride, carbonate and sulfate anions and t-butanol), the chloride anion showed the most inhibitive effect on the sonocatalysis performance. Improvement of the sonocatalytic process by K2S2O8 and H2O2 enhancers was also studied. The reusability of the synthesized sonocatalyst was evaluated in several consecutive runs, and a decline of only 4% was observed in the process performance after five runs. The intermediates produced during the degradation of RO29 were identified by GC-MS analysis.

Degrading a mixture of three textile dyes using photo-assisted electrochemical process with BDD anode and O2-diffusion cathode.

In this paper, degradation of a mixture of three azo dyes was studied by the photo-assisted electrochemical process using an O2-diffusion cathode containing carbon nanotubes and boron-doped diamond (BDD) anode. The concentration of three textile dyes (C.I. Acid Orange 8 (AO8), C.I. Acid Orange 10 (AO10), and C.I. Acid Orange 12 (AO12)) was determined simultaneously despite the severe overlap of their spectra. For this purpose, partial least square (PLS), as a multivariate calibration method, was utilized based on recording UV-Vis spectra during the decolorization process. Moreover, the central composite design was used for the modeling of photo-assisted electrochemical decolorization of the aqueous solutions containing three dyes. The investigated parameters were the initial concentration of three dyes, applied current and reaction time. Analysis of variance (ANOVA) revealed that the obtained regression models match the experimental results well with R (Khataee et al. 2010, Clean-Soil Air Water 38 (1):96-103, 2010) of 0.972, 0.971, and 0.957 for AO8, AO10, and AO12, respectively. Three-dimensional surface and contour plots were applied to describe the relation between experimental conditions and the observed response. The results of TOC analysis confirmed good ability of proposed photo-assisted electrochemical process for degradation and mineralization of textile industry wastewater.