Effect of Aging Treatment on the Strength and Microstructure of 7075-Based Alloys Containing 2% Li and/or 0.12% Sc.

The present study was performed on three versions of 7075 alloy to which Sc or Sc + Li was added. The alloys were subjected to various aging treatments. The microhardness results show that the highest value of hardness was achieved when the alloy containing Li + Sc was aged at 120 °C for 24 h whereas the minimum level was exhibited by the base alloy aged at 280 °C. The results were interpreted in terms of the size and distribution of the main hardening phase (η'(MgZn2)), and the role of the presence of Al and Cu in the used alloy. Precipitation of Al3(Sc, Zr, Ti) phase particles during solidification of the Sc-containing ingots was also discussed. The coarsening and spheroidi-zation of η-phase particles take place through the Ostwald ripening mechanism while smaller par-ticles in solution dissolve and deposit on larger particles. In Sc-containing alloys, star phase particle consists of different layers. The change in the brightness from layer to layer indicates that the Zr and Sc concentrations are varied within the star phase, since the atomic number of Zr (40) is higher than the atomic number of Sc (21). The addition of Sc, as well, leads to marked decrease in the grain size of the as-cast alloys i.e., 300 µm and 45 µm, respectively. The interaction between Li and Sc would reduce the effectiveness of the grain refining effect of Sc. The results of the refining effect of Sc were confirmed using the EBSD technique.

A Review on the Analysis of Thermal and Thermodynamic Aspects of Grain Refinement of Aluminum-Silicon-Based Alloys.

The present analysis addresses the solidification and thermodynamic parameters involved during the solidification of aluminum (Al)-based alloys as presented in the literature using different systems viz., binary aluminum-boron (Al-B) and aluminum-titanium (Al-Ti) systems, ternary aluminum-titanium-boron (Al-Ti-B) and aluminum-titanium-carbon (Al-Ti-C) systems, as well as taking into consideration the silicon-titanium-aluminide (Si-TiAl3) interaction in Al-based alloys containing Si. The analysis is supported by recent metallographic evidence obtained by the authors on A356.2 alloys. The sections on thermodynamic aspects cover the different models proposed concerning nucleation and growth on a newly formed Al grain. The value of the recalescence parameter reduces gradually with the increase in the Ti added. At a level of 0.20 wt%, this parameter becomes zero. If the concentration of grain refiner exceeds a certain amount, the grain size becomes minimal. Another parameter to be considered is the interaction between the grain refiner and traces of other metals in the base alloy. For example, Al-4%B can react with traces of Ti that may exist in the base alloy, leading to the reaction between boron and titanium to form titanium diboride (TiB2). Grain refinement is achieved primarily with TiB2 rather than aluminum diboride (AlB2), or both, depending on the Ti content in the given alloy.

A Comparative Study of Grain Refining of Al-(7-17%) Si Cast Alloys Using Al-10% Ti and Al-4% B Master Alloys.

The present article addresses solidification parameters, and includes analyses of the macrostructure and microstructure in the light of the results obtained from the thermal analysis, from which it is possible to conclude that undercooling (TS) and recalescence (TR) temperatures increase with the initial increase in titanium (Ti) concentration. If the concentration reaches approximately 0.25%, a rapid decrease in these temperatures is observed. Thereafter, the temperatures increase again with the further increase in Ti concentration, and eventually become constant. These temperatures also vary depending on the superheating and casting temperature. The ∆T parameter (i.e., TS - TR) decreases with the Ti concentration and, from a concentration of around 0.20% Ti, this parameter becomes zero. The grain size decreases with the Ti concentration. If the concentration exceeds about 0.20%, the grain size becomes the minimum. Another parameter to be considered is the interaction between the grain refiner and the traces of other metals in the base Al alloy. For example, Al-4%B can react with traces of Ti that may exist in the base alloy, leading to the reaction between boron (B) and Ti to form TiB2. Grain refinement is achieved primarily with TiB2 rather than AlB2, or both, depending on the Ti content in the given alloy.

A Review on Porosity Formation in Aluminum-Based Alloys.

The main objective of this review is to analyze the equations proposed for expressing the effect of various parameters on porosity formation in aluminum-based alloys. These parameters include alloying elements, solidification rate, grain refining, modification, hydrogen content, as well as the applied pressure on porosity formation in such alloys. They are used to establish as precisely as possible a statistical model to describe the resulting porosity characteristics such as the percentage porosity and pore characteristics, as controlled by the chemical composition of the alloy, modification, grain refining, and the casting conditions. The measured parameters of percentage porosity, maximum pore area, average pore area, maximum pore length, and average pore length, which were obtained from statistical analysis, are discussed, and they are supported using optical micrographs, electron microscopic images of fractured tensile bars, as well as radiography. In addition, an analysis of the statistical data is presented. It should be noted that all alloys described were well degassed and filtered prior to casting.

Effect of Cu Content on the Alloy Tensile Properties of Al-Cu Based Alloys Tested at 25 °C and 250 °C: Application of the Concept of Quality Index.

The present work was performed on three versions of a newly developed alloy coded T200 containing 6.5% Cu, 0.1% Fe, 0.45% Mg, and 0.18% Zr in addition to A319 and A356 alloys (grain refined and Sr-modified). Tensile bars were subjected to 13 different heat treatments prior to testing at either 25 °C or 250 °C. The tensile data were analyzed using the quality index method. The results obtained showed that, due to the high copper content in the T200 alloy coupled with proper grain refining, the alloy possesses the highest quality as well as improved resistance to softening when tested at 250 °C among the five alloys. The results also demonstrate the best heat treatment condition to maximize the use of the T200 alloy for automotive applications. Grain-refined alloy B, treated in the T6 temper and tested at 250 °C, exhibited the best combination of the four tensile parameters, i.e., UTS, YS, %El, and Q-values: 308 MPa, 304 MPa, 2.3%, and 352 MPa, respectively, which are comparable with those obtained from the 356 alloy: 309 MPa, 305 MPa, 2.8%, and 375 MPa in the same order.

Effect of Si, Mn, Be and Sr Addition on the Tensile Properties of 6061 Type Alloys: Role of Aging Treatment.

The present study was performed on a 6061-type alloy to examine the effects of minor additions (Si, Mn, Be, Sr) of the type of precipitated Fe-based intermetallics, in terms of Fe/Si ratios. All alloys were grain refined (0.15%Ti in the form of Al-5%Ti-1%B) to minimize hot tearing during casting. The effect of these intermetallics on the alloy tensile properties was also investigated. Tensile test bars were solutionized at 520 °C followed by quenching in warm water at 60 °C to avoid cracking. The quenched bars were aged at 175 °C for periods up to 100 h. Characterization of the formed intermetallics as well as phase precipitation were carried out using field emission scanning electron microscopy. In Be-treated alloys, α-Al8Fe2SiBe phase may precipitate along with α-Al15(Fe, Mn)3Si2 phase. In addition, Be results in fragmentation of the α-Fe phase when the alloy was Sr-modified, leading to better tensile properties, compared to those obtained from the base alloy under same conditions. It should be noted that this study does not promote the use of Be as it is a toxic element.

The Role of Mg Content and Aging Treatment on the Tensile and Fatigue Properties of Die-Cast 380 Alloy.

The main objective of this contribution was to determine the impact of magnesium (Mg) concentration and solidification rate (about 800 °C/s) on the mechanical properties of commercial A380.1 die-cast alloy. Respective amounts of 0.10%, 0.30%, and 0.50% Mg were used to establish their influence on the main tensile properties, namely, the ultimate limit, the elastic limit, and the percentage of elongation to fracture. The study also focused on the effect of magnesium on the fatigue behavior of A380.1 alloy where the role of surface defects and internal defects (porosity, oxide films, and inclusions) on the alloy fatigue life was also determined. The tensile properties were analyzed in order to optimize the heat treatments of T6 (under-aging) and T7 (over-aging). Consequently, the influence of several parameters was evaluated using tensile testing and optical and scanning electron micrography. Fatigue strength was investigated by performing rotational bending tests. The results show that the alloy tensile strength parameters improve with up to 0.3% Mg. Further addition of Mg, i.e., 0.5%, does not produce any significant improvement with respect to either traction or fatigue. It is observed that the tensile properties fluctuate according to the Guinier-Preston zones which occur during heat treatment, while the fatigue properties decrease as the Mg content increases. In contrast to a mechanical fatigue failure mechanism, in the present study, cracks were initiated at the sample's outer surface and then propagated toward the center.

Effect of Bi and Ca on the Solidification Parameters of Sr-Modified Al-S-Cu (Mg) Alloys.

The effect of tramp elements, mainly Bi and Ca, on the thermal characteristics of Sr-modified Al-Si-Cu and Al-Si-Cu-Mg alloys has been investigated using thermal analysis, X-ray radiography, and field emission scanning electron microscopy (FESEM) techniques. The high affinity of Bi to interact with Sr results in an increase in the Al-Si eutectic temperature, and hence an increase in the size of eutectic silicon particles. In contrast, the Ca-Sr interaction seems to have no significant effect on the alloy thermal behavior. The effect of these interactions on porosity formation has been discussed. Hot zones may be formed in thin cavities, in particular, near the bottom of the mold, leading to formation of unexpected coarse porosity, mostly shrinkage type. The study also highlights the significance of other parameters on porosity formation, such as no melt degassing, SrO, Al2O3 (strings or bifilms), as well as the presence of iron-based intermetallics.

Effect of Zr and Ti Addition and Aging Treatment on the Microstructure and Tensile Properties of Al-2%Cu-Based Alloys.

The present work investigated the effect of aging treatment on the microstructure and tensile properties of an Al-2%Cu base alloy containing various additions of Zr and other alloying elements. Aging was carried out at temperatures of 180-300 °C for different aging times at each temperature. The tensile properties indicated that Zr additions improved the strength of the base alloy, especially at high Zr levels at 180 °C. At the 220 °C aging temperature, however, while Zr addition did not have a beneficial effect on the alloy strength, the ductility was found to improve. Zr-Ti combined additions had a significant effect on the microstructure of the base alloy, as the morphology of the α-Al grains transformed into a non-dendritic morphology, and the grain size decreased sharply. These effects were at their maximum at 180 °C and 0.5 wt% Zr addition. Moreover, the Zr-containing alloys aged at higher temperatures, such as 220 °C and 240 °C, maintained a noticeably higher level of strength over the base alloy aged at the same temperatures. Quality index charts based on the tensile test data also reflected an improvement in alloy quality and strength with Zr-Ti combined additions.

Characterization of Si and SiO2 in Dust Emitted during Granite Polishing as a Function of Cutting Conditions.

Particles emitted during manufacturing processes such as polishing can represent a serious danger for the environment and for occupational safety. The formation mechanisms responsible for these dust emissions include chip formation, friction at the tool/workpiece and chip/tool interfaces, shearing and cutting. These mechanisms thus depend on workpiece and tool properties, as well as the polishing conditions. In the case of granite polishing, particle emissions during polishing can contain chemical compounds such as silica, which represent harmful health risks for the worker. It is therefore important to characterize the particles emitted and to search for possible interactions between the particles (size and composition) and the machining conditions in order to find ways of reducing emissions at the source. In this study, an investigation was undertaken to characterize the particles emitted during granite polishing as a function of polishing conditions, type of granite, and abrasive grit sizes used. Scanning electron microscopy (SEM) was employed for particle morphology characterization and particle grain size and chemical composition were evaluated using X-ray diffraction (XRD) and energy dispersive X-ray (EDX) techniques, respectively. Results show that the influence of polishing speed and feed rate on particle emission depends mainly on the granite type used, providing useful information for controlling the polishing procedure, and thereby dust emission.

Assessment of the Influence of Additives on the Mechanical Properties and Machinability of Al-11%Si Cast Alloys: Application of DOE and ANOVA Methods.

In the present study, the statistical design of experiments (DOE) method was applied to study and control the properties of near-eutectic Al-11%Si alloys. In this study, we developed regression equations between response variables, including hardness, yield stress, ultimate tensile stress, elongation, total cutting force, cutting power, and tool life, and varying factors which included the percentage of the alloying element in the composition and the modification level. These equations may be analyzed quantitatively to acquire an understating of the effects of the main variables and their interactions on the mechanical behavior and the machinability of the alloy under investigation. Analysis of variance (ANOVA) was performed to verify the fit and adequacy of the developed mathematical models. The results show that increasing the levels of Cu and Fe results in an increase in hardness, yield stress and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the elongation adversely, whereas the Sr level shows a positive effect on the elongation percentage. We found that the Sr level had the most significant effect on the cutting forces and cutting power, followed by Fe and Cu contents.

Mechanical Performance and Precipitation Behavior in Al-Si-Cu-Mg Cast Alloys: Effect of Prolonged Thermal Exposure.

Al-Si-Cu-Mg cast (354) alloys are used in the automotive sector owing to their remarkable properties which are achievable after applying appropriate thermal treatments. Zirconium, Nickel, and Manganese were added to this category of Al-alloys to preserve good mechanical properties while being exposed to elevated temperatures for long times. The ultimate and yield strength values obtained at room temperature for the stabilized (thermally-exposed) T5-treated condition were comparable to those of the stabilized T6-treated condition, whereas the same properties for T5-treated alloys were higher than those of T6-treated ones for elevated-temperature tensile testing. Interestingly, the results showed that the addition of 0.75 wt.% Mn was competitive with the addition of 2 and 4 wt.% Ni with respect to the elevated-temperature and ambient temperature strength values, respectively. In addition, the Mn-containing alloy M3S exhibited improved ductility values at ambient temperature and at 250 °C, compared to the Ni-containing alloys. Examination of the fracture surface of tested samples revealed the advantageous role of sludge particles in enhancing the performance of Mn-containing alloys through their resistance to the propagation of cracks that developed in many intermetallic phases. This finding is considered to be economically significant in view of the lower price of manganese compared to that of nickel.

Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys.

The present study was undertaken to examine the effect of iron, manganese, copper and magnesium on the microstructural characteristics of Al-11%Si-2%Cu-Mg-based alloy referred to as 396 under different working conditions. The results show that strontium (Sr) has high affinity to react with magnesium (Mg), resulting in reduced effectiveness as eutectic silicon modifier or age hardening agent. In addition, Sr alters the sequence of the precipitation of the α-AlFeMnSi phase from post-eutectic to pro-eutectic which would harden the soft α-Aluminum matrix. The mechanism is still under investigation. The interactions between iron (Fe) and Mg and Sr-Mg result in the formation of serval dissolvable intermetallics during the solutionizing treatment such as ß-AlFeSi, π-AlFeMgSi and Q-AlMgSiCu phases. The study also emphasizes the role of modification and grain refining as well as intermetallics in porosity formation and hardness of samples aged in the temperature range 155-240 °C.

Effect of Intermetallics and Drill Materials on the Machinability of Al-Si Cast Alloys.

The present study was conducted on the machinability of 396 alloy (containing approximately 11% Si) and B319.2 alloy mainly to emphasize the effects of Fe-intermetallics, i.e., α-Fe, ß-Fe, and sludge. The results demonstrate that the presence of sludge in the form of hard spots has a significant effect on cutting forces and tool life, in that it decreases drill life by 50% compared to the base alloy. The formation of the α-Fe phase in the M1 base alloy has a beneficial effect on tool life in that this alloy produces the highest number of holes drilled compared to alloys containing sludge or ß-Fe; this result may be explained by the fact that the formation of the α-Fe intermetallic, with its rounded Chinese script morphology and its presence within α-Al dendrites, is expected to improve matrix homogeneity via hardening of the soft α-Al dendrites. Increasing the Fe-content from 0.5% to 1% in the 396-T6 alloy containing 0.5% Mn produces a distinct improvement in alloy machinability in terms of cutting force and tool life. The addition of Fe and/or Mn appears to have no discernible effect on the build-up edge area (BUE) and chip shape.

Effects of Trace Elements on the Microstructural and Machinability Characteristics of Al-Si-Cu-Mg Castings.

This study was undertaken to emphasize the influence of Sn and Bi addition on the machinability of Sr-modified, grain-refined, and heat-treated Al-Si B319 and 396 alloys. Drilling and tapping tests were conducted to examine the cutting forces, tool life, tool wear, built-up edge evolution, and chip shape. Microstructures were examined using optical and electron microscopy. Drilling test results show that the B319.2 alloy with 0.15%Sn yields the longest drill life, i.e., twice that of the B319.2 alloy containing 0.5%Bi, and one-and-a-half times that of the B319.2 alloy containing 0.15%Sn + 0.5%Bi. The presence of 0.5%Bi in the B319.2 alloy causes a deterioration of drill life (cf., 1101 holes with 2100 holes drilled in the B319.2 alloy containing 0.15%Sn). The α-Fe phase in the 396 alloy produces the highest number of holes drilled compared with alloys containing sludge or ß-Fe. The presence of sludge decreases the drill life by 50%. Built-up edge (BUE) measurements and optical photographs show little change in the BUE width for different numbers of holes except for the B319.2 alloy containing 0.5%Bi, which shows a slightly lower width (0.166 mm) compared with that containing 0.15% Sn (0.184 mm) or 0.15%Sn + 0.5%Bi (0.170 mm).

The Effect of Bi-Sr and Ca-Sr Interactions on the Microstructure and Tensile Properties of Al-Si-Based Alloys.

The effect of bismuth and calcium additions on the microstructural characteristics and the tensile properties of the modified and grain-refined Al-Si based B319 alloys were studied in this paper. Based on the results obtained, it has been concluded that Bi reacts with both Sr and Mg, leading to severe demodification of the eutectic Si at Bi levels of 0.15%-0.6% Bi. Bismuth causes a decrease of the yield and tensile strengths for the as-cast and artificially aged conditions and an increase of yield strength in the solution heat-treated condition. The elongation increases with the Bi in the solution heat-treated condition. Based on this, Bi is found to be an efficient solid-solution strengthening element for these alloys. Thus, solution heat treatment, rather than the artificial aging, may be recommended for alloys containing about 1.0% Bi. Calcium has no significant demodification effect on the Sr-modified Si particles at 100-400 ppm Ca, and has a modifying effect at ~600 ppm Ca. The elongation increases with the Ca level at all conditions (as-cast, solution heat-treated, and artificially aged). A slight increase of the tensile strength in the heat-treated conditions was also observed. The lowest tensile properties either in the as-cast or the heat-treated conditions correspond to the most demodified-Si condition obtained at 408 ppm Ca. Calcium is, therefore, not as detrimental to the tensile properties as Bi.

Effect of Rare Earth Metals on the Microstructure of Al-Si Based Alloys.

The present study was performed on A356 alloy [Al-7 wt %Si 0.0.35 wt %Mg]. To that La and Ce were added individually or combined up to 1.5 wt % each. The results show that these rare earth elements affect only the alloy melting temperature with no marked change in the temperature of Al-Si eutectic precipitation. Additionally, rare earth metals have no modification effect up to 1.5 wt %. In addition, La and Ce tend to react with Sr leading to modification degradation. In order to achieve noticeable modification of eutectic Si particles, the concentration of rare earth metals should exceed 1.5 wt %, which simultaneously results in the precipitation of a fairly large volume fraction of insoluble intermetallics. The precipitation of these complex intermetallics is expected to have a negative effect on the alloy performance.