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Chem Commun (Camb)
; 59(46): 7080-7083, 2023 Jun 06.
Article
in English
| MEDLINE
| ID: mdl-37218432
ABSTRACT
A three-dimensional skeleton, π-fused [4.3.3]propellane, was constructed and derivatized by selective π-extension at the two naphthalene units. The obtained propellanes existed as stereoisomers different in spatial arrangement, one of which displayed a chiroptical response originating from through-space interactions between 5-azachrysenes in a skew position.