Efficient removal of Rhodamine B dye using biochar as an adsorbent: Study the performance, kinetics, thermodynamics, adsorption isotherms and its reusability.

Removal of toxic dyes such as Rhodamine B is essential as it pollutes aqueous and soil streams as well. This comprehensive study explores the potential of Calophyllum inophyllum seed char as an efficient bio-adsorbent based on their characteristic properties and a comparative study between various carbon-based adsorbents on the adsorption capacity of Rhodamine B dye. In this study, the char was prepared from Calophyllum inophyllum seed using a slow pyrolysis process (298 K/min) at an optimum temperature of 823 K and used as an adsorbent for the removal of Rhodamine B from water. The resulting char was mesoporous and had 155.389 m2/g surface areas (BET) and 0.628 cc/g pore volume. The formation of pores was observed from the SEM analysis. The adsorption studies were tested and optimized through various parameters such as solution pH, adsorbent dosage, initial dye concentration, stirring speed, contact time, and solution temperature. Maximum 95.5 % removal of Rhodamine B was possible at the pH: 2, stirring speed: 100 rpm, time: 25 min, temperature 308 K, and dose: 1.2 g/L. The highest adsorption capacity at equilibrium was determined to be 169.5 (mg/g) through Langmuir adsorption isotherm studies and followed pseudo 2nd order kinetics. The thermodynamics study confirmed the adsorption processes were spontaneous (ΔG°=-0.735 kJ/mol) and endothermic (ΔH° = 4.1 kJ/mol) processes. The reusability study confirmed that the mesoporous char can be reused as an efficient adsorbent for up to 3 cycles for environmental remediation.

Biotechnological innovations in nanocellulose production from waste biomass with a focus on pineapple waste.

New materials' synthesis and utilization have shown many critical challenges in healthcare and other industrial sectors as most of these materials are directly or indirectly developed from fossil fuel resources. Environmental regulations and sustainability concepts have promoted the use of natural compounds with unique structures and properties that can be biodegradable, biocompatible, and eco-friendly. In this context, nanocellulose (NC) utility in different sectors and industries is reported due to their unique properties including biocompatibility and antimicrobial characteristics. The bacterial nanocellulose (BNC)-based materials have been synthesized by bacterial cells and extracted from plant waste materials including pineapple plant waste biomass. These materials have been utilized in the form of nanofibers and nanocrystals. These materials are found to have excellent surface properties, low density, and good transparency, and are rich in hydroxyl groups for their modifications to other useful products. These materials are well utilized in different sectors including biomedical or health care centres, nanocomposite materials, supercapacitors, and polymer matrix production. This review explores different approaches for NC production from pineapple waste residues using biotechnological interventions, approaches for their modification, and wider applications in different sectors. Recent technological developments in NC production by enzymatic treatment are critically discussed. The utilization of pineapple waste-derived NC from a bioeconomic perspective is summarized in the paper. The chemical composition and properties of nanocellulose extracted from pineapple waste may have unique characteristics compared to other sources. Pineapple waste for nanocellulose production aligns with the principles of sustainability, waste reduction, and innovation, making it a promising and novel approach in the field of nanocellulose materials.

A novel investigation using thermal modeling and optimization of waste pyrolysis reactor using finite element analysis and response surface methodology.

The influence of humans on the environment is growing drastically and is pervasive. If this trend continues for a longer time, it can cost humankind, social and economic challenges. Keeping this situation in mind, renewable energy has paved the way as our saviour. This shift will not only help in reducing pollution but will also provide immense opportunities for the youth to work. This work discusses about various waste management strategies and discusses the pyrolysis process in details. Simulations were done keeping pyrolysis as the base process and by varying parameters like feeds and reactor materials. Different feeds were chosen like Low-Density Polyethylene (LDPE), wheat straw, pinewood, and a mixture of Polystyrene (PS), Polyethylene (PE), and Polypropylene (PP). Different reactor materials were considered namely, stainless steel AISI 202, AISI 302, AISI 304, and AISI 405. AISI stands for American Iron and Steel Institute. AISI is used to signify some standard grades of alloy steel bars. Thermal stress and thermal strain values and temperature contours were obtained using simulation software called Fusion 360. These values were plotted against temperature using graphing software called Origin. It was observed that these values increased with increasing temperature. LDPE got the lowest values for stress and stainless steel AISI 304 came out to be the most feasible material for pyrolysis reactor having the ability to withstand high thermal stresses. RSM was effectively used to generate a robust prognostic model with high efficiency, R2 (0.9924-0.9931), and low RMSE (0.236 to 0.347). Optimization based on desirability identified the operating parameters as 354 °C temperature and LDPE feedstock. The best thermal stress and strain responses at these ideal parameters were 1719.67 MPa and 0.0095, respectively.

Effective hydrolysis for waste plant biomass impacts sustainable fuel and reduced air pollution generation: A comprehensive review.

Among various natural biowastes availability in the environment, agricultural residues showed great impacts. It is due to huge availability and cheap carbon source, creating big challenges for their utility and systematic reduction. Objective of this review is to address the waste biomass availability and huge quantities issues and also put effort to minimize this nutrient load via biotransforming into value-added products. Different wastes (organic/inorganic) generation with their negative issues are due to numbers of developmental and social activities, reported. Currently, various efforts are found for these wastes minimization via generation of different types of value-added products (biogas, bioH2, alcoholic fuel, organic acids and others products) and these wastes in municipal cities are also reported with production of advanced biofuels as promising outcomes. For hydrolysis of complex organic resources including lignocellulosic biomasses, physicochemical, structural or compositional changes are needed that aid in conversion into sugar and organic compounds such as biofuels. So, efficient and effective pretreatment processes selection (physical, biological, chemical or combined one) is critical to achieve these hydrolysis goals and resultant cellulose or hemicellulose components can be accessible by biological catalysis. These can achieve final hydrolysis and fermentative or monomer sugars. And later, synthesis of fuels or value-added products during microbial fermentation or biotransformation processes can be achieved. This review discusses pretreatment techniques for improved hydrolysis for fermentative sugar with emphasis on reduced quantities of toxic compounds (furfural compound) in hydrolyzed biomasses. Minimum deterioration fuel economy also reported with production of different bioproducts including biofuels. Additionally, impacts of toxic products and gasses emission are also discussed with their minimization.

Ionic liquid [bmim] [TFSI] templated Na-X zeolite for the adsorption of (Cd2+, Zn2+), and dyes (AR, R6).

1-butyl-3-methylimidazolium bis(triflouromethylsufonyl)imide functionalization to Na-X zeolite (IFZ) is the primary goal of this study in order to evaluate its ability to remove heavy metals (Cd2+), (Zn2+), dyes Rhodamine 6G (R6), and Alizarin Red S (AR) from aqueous streams. IFZ was thoroughly examined using analytical techniques XRD, BET, FE-SEM, and FTIR, to better understand its physical and chemical properties. The surface area and the volume of pores (IFZ; 19.93 m2/g, 0.0544 cm3/g) were reduced in comparison to the parent zeolite (Na-X; 63.92 m2/g, 0.0884 cm3/g). According to SEM, the crystal structure of the zeolite (Na-X) has not been significantly altered by XRD analysis. The mechanism, kinetics, isotherms, and thermodynamic properties of adsorption were all studied using batch adsorption experiments under various operating conditions. IFZ adsorbs dyes (AR; 76.33 mg/g, R6; 65.85 mg/g) better than metal ions (Cd2+; 30.68 mg/g, Zn2+; 41.53 mg/g) in acidic conditions. The Langmuir isotherm and pseudo-second order models were found to be the most accurate models for equilibrium data. Adsorption is endothermic and spontaneous, as revealed by the thermodynamics of the process. The IFZ can be used in three (Cd2+), two (Zn2+), four (AR), and five (R6) cycles of desorption and regeneration. For these reasons, IL-modified zeolite can be used to remove multiple types of pollutants from water in one simple step.

Synthesis of dye-sensitized TiO2/Ag doped nano-composites using UV photoreduction process for phenol degradation: A comparative study.

This study investigates a comparison between the photocatalytic action of two nanocomposites (TiO2 and TiO2(Ag) doped) on the degradation of phenol from water. The nanocomposites were synthesized by the UV photo-reduction process to get a silver metal loading of 0.25, 0.5, 0.75, and 1% (w/w). In addition to this, Eriochrome Cyanine Red (ECR) and Eosin Yellow (EY) both anionic dyes were used for sensitization of Ag-doped TiO2 photo-catalyst such as TiO2(Ag)ECR and TiO2(Ag)EY. The TiO2(Ag-1.0)EY photo-catalyst indicated higher absorbance compared to the TiO2(Ag-1.0)ECR in the 400-700 nm range (visible range). The degradation of phenol was tested by varying the pH, silver loading and catalyst dosage. The maximum degradation of phenol was 98% in 180 min at pH 7 in presence of 1% (w/w) silver loading with 0.5 gL-1 dosage of photo-catalyst TiO2(Ag-1.0)EY. At this condition, the reduction in the phenol concentration was noticed from 20 mg/L to 0.4 mg/L.

A mini review on microwave and contemporary based biohydrogen production technologies: a comparison.

Hydrogen gas, along with conventional fossil fuels, has been used as a green fuel with enormous potential. Due to the rapid depletion of fossil fuels, a new dimension of hydrogen production technology has arrived to reduce reliance on nonrenewable energy sources. Microwave-based hydrogen production is a more promising and cost-effective technology than other existing green hydrogen production methods such as fermentation and gasification. Microwave heating may be superior to traditional heating due to several advantages such as less power consumption compared to other methods, higher yield, and a higher rate of conversion. Compared to another process for hydrogen production, the microwave-driven process worked efficiently at lower temperatures by providing more than 70% yield. The process of production can be optimized by using properly sized biomass, types of biomass, water flow, temperature, pressure, and reactor size. This method is the most suitable, attractive, and efficient technique for hydrogen production in the presence of a suitable catalyst. Hot spots formed by microwave irradiation would have a substantial impact on the yield and properties of microwave-processed goods. The current techno-economic situation of various technologies for hydrogen production is discussed here, with cost, efficiency, and durability being the most important factors to consider. The present review shows that a cost-competitive hydrogen economy will necessitate continual efforts to increase performance, scale-up, technical prospects, and political backing.

Pyrolytic oil blended gasoline as future fuel: pyrolysis mechanism, fuel properties, and composition analysis.

In this investigation, waste motor oil (WMO) was pyrolyzed at 550 °C which yielded about 76.73 wt.% of pyrolytic oil (PO). To study the effect of blending with gasoline on the fuel properties and composition, the PO was blended at 5-30% with an augmentation of 5% by volume. The respective fuel properties of all the blends were determined and compared with gasoline. The prime blending percentage of WMO pyrolytic oil (WMOPO) was established based on the gross calorific value obtained. Among all the blends, 5% blending PO (B5) ensued the highest calorific value about 45.63 MJ kg-1 which was adjacent to gasoline. The B5 oil was also having an analogous density as gasoline. The composition analysis visualized that B5 comprised of alkenes (1.25%), cycloalkanes (3.88%), cycloalkenes (2.43%), aromatics (25.38%), and alkanes (53.75%). The results also confirmed the occurrence of 50.52% of C4-C12 compounds. Since the fuel properties and composition of the B5 oil were comparable to the untainted gasoline, it can be a suitable proportion to consider as future fuel if the engine performance and emission analysis show any positive effects.

Conversion of carbon dioxide to methanol: A comprehensive review.

This review explains the various methods of conversion of Carbon dioxide (CO2) to methanol by using homogenous, heterogeneous catalysts through hydrogenation, photochemical, electrochemical, and photo-electrochemical techniques. Since, CO2 is the major contributor to global warming, its utilization for the production of fuels and chemicals is one of the best ways to save our environment in a sustainable manner. However, as the CO2 is very stable and less reactive, a proper method and catalyst development is most important to break the CO2 bond to produce valuable chemicals like methanol. Litertaure says the catalyt types, ratio and it surface structure along with the temperature and pressure are the most controlling parameters to optimize the process for the production of methanol from CO2. This article explains about the various controlling parameters of synthesis of Methanol from CO2 along with the advantages and drawbacks of each process. The mechanism of each synthesis process in presence of metal supported catalyst is described. Basically the activity of Cu supported catalyst and its stability based on the activity for the methanol synthesis from CO2 through various methods is critically described.

Study the fuel characteristics of ethanol and waste engine oil pyrolytic oil blends.

This study shows the application of pyrolytic oil derived from waste engine oil (WEOPO) as an alternative fuel by blending with ethanol. For this, the effect of blending of ethanol at 5 %, 10 %, 15 %, 20 %, 25 %, and 30 % on the compositions and fuel properties were analyzed. The utmost blending was established based on the higher heating value. The pyrolytic oil used for this study was produced at 550 °C which was the optimum pyrolytic temperature. A comparison study of the blended oil was performed with commercially available gasoline to observe the similarities in their fuel properties and composition. The study confirmed that ethanol can be blended with WEOPO at 20 % by volume to obtain a fuel of a higher heating value of about 44.24 MJ/kg that can be used as fuel. Since WEOPO contains 65.80 % of C4-C12 (gasoline range), hydrocarbon compounds and the rest 31.48 % C11-C15, 11.84 % C15-C19, and 6.94 % > C19 compounds, it can be used as a future fuel.