1.
J Chromatogr
; 562(1-2): 681-96, 1991 Jan 02.
Article
in English
| MEDLINE
| ID: mdl-2026731
ABSTRACT
A number of compounds emitted during the thermal degradation of plastics are potentially toxic. This study was aimed at identifying the volatile compounds emitted during large-scale thermal degradation of poly(acrylonitrile-butadiene-styrene). About 5 g of the sample were degraded at between 25 and 470 degrees C in air and nitrogen in a device that can simulate temperature-programmed thermogravimetry. The volatiles were collected in dichloromethane using the solvent trap technique. Some of the 92 compounds identified by gas chromatography-mass spectrometry were found to have no hitherto documented toxicological profiles, even though they are potentially dangerous.