The Impacts and Analysis of Individual and Social Risks of the Stochastic Emission of Benzene from Floating-Roof Tanks Using Response Surface Analysis and MPACT Model.

In the present study, the researchers used an integrated approach composed of response surface analysis (RSM) and MPACT model to predict fatality rates caused by benzene emitted from floating-roof tanks. RSM scenarios were configured in Expert Design (version 7.0) software using the central composite design (CCD) method and five variables of wind speed, relative humidity, atmospheric temperature, failure diameter, and emission height were considered. Continuous Pasquill-Gifford Gaussian model was used to estimate the results of the RSM scenarios. The response values were considered for exposure concentrations above 50 ppm (slight damages), 150 ppm (moderate damage), and 1000 ppm (high damage). The analysis of individual and social risks for each scenario was done using the MPACT model in SAFETI program (version 8.22) by providing two variables of population characteristics and the frequency of tank wall failure. The results showed that atmospheric temperature, wind speed, failure diameter, and emission height have positive effects on the dispersion of the cloud of toxic benzene vapor with a concentration of 1000 ppm. Intolerable individual risk distances were estimated to be lower for indoor environments than for outdoor. Maximum distances of intolerable individual risks for the worst-case scenarios were estimated up to 2500 m from the emission point, which resulted from exposure to a concentration of 1000-ppm benzene. Results regarding the estimation of social risks showed that over 1600 fatalities should be expected under the worst-case scenarios. The three factors of high temperature, low wind speed, and low emission height play a major role in the occurrence of scenarios with the highest fatalities. High wind speed and high emission height were the most important factors in most scenarios with zero fatalities rate. Generally, the findings of this study show the necessity to provide an emergency response plan in the studied industry in both autumn and winter due to low wind speed. However, the coupling of the developed statistical models based on regional meteorological conditions with the MPACT model can help researchers to design an emergency response plan to deal with leakage incidents in petrochemical industries.

Modeling the environmental, health, and safety aspects of xylene isomer emission from storage tanks in petrochemical industries, Iran.

The release of xylene isomers from storage tanks poses a significant threat to petrochemical industries, and their safe transportation and storage is a widely researched topic. This paper focused on modeling the environmental, health, and safety effects of P-xylene and O-xylene leakage from storage tanks via Areal Locations of Hazardous Atmospheres (ALOHA) and Wireless Information System for Emergency Responders (WISER). The meteorological data of the area, characteristics of the tanks, and the roughness of the land surrounding the tanks were used to run the ALOHA model. The dispersion distances of P-xylene and O-xylene toxic and flammable vapor clouds were estimated according to the Immediately Dangerous to Life or Health (IDLH) and lower explosive limit (LEL) criteria. Also, the levels of thermal radiation due to the burning of P-xylene and O-xylene were estimated. The results showed that in the cold seasons, the IDLH was a maximum distance of 62 m and 45 m for P-xylene and O-xylene, respectively. The LEL criteria were 10% with a magnitude of 1100 ppm for a maximum distance of 54 m and 35 m for P-xylene and O-xylene, respectively. The maximum distance of 20 m for O-xylene based on the results of the LEL criteria of 60% (6600 ppm) was attained in the warm seasons. They are potentially lethal within 60 s at 21 m (10.0 kW/m2) when burned. The WISER software predicted the protective distance for xylene isomers to be about 300 m. The results show that creating a protective zone around the P-xylene and O-xylene tanks with a radius of 54 m is necessary to reduce hazards.