Efficient Mechanical Stress Transfer in Multilayer Graphene with a Ladder-like Architecture.

We report that few graphene flakes embedded into polymer matrices can be mechanically stretched to relatively large deformation (>1%) in an efficient way by adopting a particular ladder-like morphology consisting of consecutive mono-, bi-, tri-, and four-layer graphene units. In this type of flake architecture, all of the layers adhere to the surrounding polymer inducing similar deformation on the individual graphene layers, preventing interlayer sliding and optimizing the strain transfer efficiency. We have exploited Raman spectroscopy to quantify this effect from a mechanical standpoint. The finite element method and molecular dynamics simulations have been used to interpret the above experimental findings. The results suggest that a step pyramid-like architecture of a flake can be ideal for efficient loading of layered materials embedded into a polymer and that there are two prevailing mechanisms that govern axial stress transfer, namely, interfacial shear transfer and axial transmission through the ends. This concept can be easily applied to other two-dimensional materials and related van der Waals heterostructures fabricated either by mechanical exfoliation or chemical vapor deposition by appropriate patterning. This work opens new perspectives in numerous applications, including high volume fraction composites, flexible electronics, and straintronic devices.

Conversionless efficient and broadband laser light diffusers for high brightness illumination applications.

Laser diodes are efficient light sources. However, state-of-the-art laser diode-based lighting systems rely on light-converting inorganic phosphor materials, which strongly limit the efficiency and lifetime, as well as achievable light output due to energy losses, saturation, thermal degradation, and low irradiance levels. Here, we demonstrate a macroscopically expanded, three-dimensional diffuser composed of interconnected hollow hexagonal boron nitride microtubes with nanoscopic wall-thickness, acting as an artificial solid fog, capable of withstanding ~10 times the irradiance level of remote phosphors. In contrast to phosphors, no light conversion is required as the diffuser relies solely on strong broadband (full visible range) lossless multiple light scattering events, enabled by a highly porous (>99.99%) non-absorbing nanoarchitecture, resulting in efficiencies of ~98%. This can unleash the potential of lasers for high-brightness lighting applications, such as automotive headlights, projection technology or lighting for large spaces.

Modeling and simulation of the impact behavior of soft polymeric-foam-based back protectors for winter sports.

OBJECTIVES: Winter sports are high-energy outdoor activities involving high velocities and acrobatic maneuvers, thus raising safety concerns. Specific studies on the impact mechanics of back protectors are very limited. In this study analytical and numerical models are developed to rationalize results of impact experiments and propose new design procedures for this kind of equipment. DESIGN: Different soft-shell solutions currently available on the market are compared. In particular, the role of dynamic material constitutive properties and of environmental temperature (which affects mainly material stiffness) on energy absorption capability are evaluated. METHODS: Starting from dynamic mechanical-thermal characterization of the closed-cell polymeric foams constituting the protectors, we exploited analytical modeling and Finite Element Method simulations to interpret experimental data from drop weight impact test and to characterize protectors at different temperatures and after multiple impacts. RESULTS: The temperature and frequency dependent properties of these materials characterize their impact behavior. Modeling results are in good agreement with impact tests. Results demonstrate how ergonomic soft-shell solution provides an advantage with respect to traditional hard-shell in terms of impact protection. Moreover, it can maintain nearly unaltered its protective properties after multiple impacts on the same point. CONCLUSIONS: The coupled analytical-simulation approach here presented could be extensively used to predict the impact behavior of such equipment, starting from material characterization, allowing to save costs and time for physical prototyping and tests for design and optimization.

Friction and Adhesion of Different Structural Defects of Graphene.

Graphene structural defects, namely edges, step-edges, and wrinkles, are susceptible to severe mechanical deformation and stresses under tribo-mechanical operations. Applied forces may cause deformation by folding, buckling, bending, and tearing of these defective sites of graphene, which lead to a remarkable decline in normal and friction load bearing capacity. In this work, we experimentally quantified the maximum sustainable normal and friction forces, corresponding to the damage thresholds of the different investigated defects as well as their pull-out (adhesion) forces. Horizontal wrinkles (with respect to the basal plane, i.e., folded) sustained the highest normal load, up to 317 nN, during sliding, whereas for vertical (i.e., standing) wrinkles, step-edges, and edges, the load bearing capacities are up to 113, 74, and 63 nN, respectively. The related deformation mechanisms were also experimentally investigated by varying the normal load up to the initiation of the damage from the defects and extended with the numerical results from molecular dynamics and finite element method simulations.

Folding Large Graphene-on-Polymer Films Yields Laminated Composites with Enhanced Mechanical Performance.

A folding technique is reported to incorporate large-area monolayer graphene films in polymer composites for mechanical reinforcement. Compared with the classic stacking method, the folding strategy results in further stiffening, strengthening, and toughening of the composite. By using a water-air-interface-facilitated procedure, an A5-size 400 nm thin polycarbonate (PC) film is folded in half 10 times to a ≈0.4 mm thick material (1024 layers). A large PC/graphene film is also folded by the same process, resulting in a composite with graphene distributed uniformly. A three-point bending test is performed to study the mechanical performance of the composites. With a low volume fraction of graphene (0.085%), the Young's modulus, strength, and toughness modulus are enhanced in the folded composite by an average of 73.5%, 73.2%, and 59.1%, respectively, versus the pristine stacked polymer films, or 40.2%, 38.5%, and 37.3% versus the folded polymer film, proving a remarkable mechanical reinforcement from the combined folding and reinforcement of graphene. These results are rationalized with combined theoretical and computational analyses, which also allow the synergistic behavior between the reinforcement and folding to be quantified. The folding approach could be extended/applied to other 2D nanomaterials to design and make macroscale laminated composites with enhanced mechanical properties.

Multilayer stag beetle elytra perform better under external loading via non-symmetric bending properties.

Insect cuticle has drawn a lot of attention from engineers because of its multifunctional role in the life of insects. Some of these cuticles have an optimal combination of lightweight and good mechanical properties, and have inspired the design of composites with novel microstructures. Among these, beetle elytra have been explored extensively for their multilayered structure, multifunctional roles and mechanical properties. In this study, we investigated the bending properties of elytra by simulating their natural loading condition and comparing it with other loading configurations. Further, we examined the properties of their constitutive bulk layers to understand the contribution of each one to the overall mechanical behaviour. Our results showed that elytra are graded, multilayered composite structures that perform better in natural loading direction in terms of both flexural modulus and strength which is likely an adaptation to withstand loads encountered in the habitat. Experiments are supported by analytical calculations and finite element method modelling, which highlighted the additional role of the relatively stiff external exocuticle and of the flexible thin bottom layer in enhancing flexural mechanical properties. Such studies contribute to the knowledge of the mechanical behaviour of this natural composite material and to the development of novel bioinspired multifunctional composites and for optimized armours.

Publisher Correction: Hierarchical self-entangled carbon nanotube tube networks.

The original version of this Article was missing the ORCID ID of Professor Nicola Pugno.Also in the original version of this Article, the third to last sentence of the fourth paragraph of the Results incorrectly read 'However, the stepwise addition of CNTs increases the self-entanglement and thereby the compressive strength value as well as the Young's modulus (up to 2.5 MPa (normalized by density 6.4) and 24.5 MPa (normalized by density 62 MPa cm3 g-1).' The correct version adds the units 'MPa cm3 g-1' to '6.4'.Finally, in the original version of this Article, the y-axis label of Figure 3f incorrectly read 'Comp. strengthy'. The new version corrects that to 'Comp. Strength'.These errors have now been corrected in both the PDF and the HTML versions of the Article.

2D Material Armors Showing Superior Impact Strength of Few Layers.

We study the ballistic properties of two-dimensional (2D) materials upon the hypervelocity impacts of C60 fullerene molecules combining ab initio density functional tight binding and finite element simulations. The critical penetration energy of monolayer membranes is determined using graphene and the 2D allotrope of boron nitride as case studies. Furthermore, the energy absorption scaling laws with a variable number of layers and interlayer spacing are investigated, for homogeneous or hybrid configurations (alternated stacking of graphene and boron nitride). At the nanolevel, a synergistic interaction between the layers emerges, not observed at the micro- and macro-scale for graphene armors. This size-scale transition in the impact behavior toward higher dimensional scales is rationalized in terms of scaling of the damaged volume and material strength. An optimal number of layers, between 5 and 10, emerges demonstrating that few-layered 2D material armors possess impact strength even higher than their monolayer counterparts. These results provide fundamental understanding for the design of ultralightweight multilayer armors using enhanced 2D material-based nanocomposites.

Hierarchical self-entangled carbon nanotube tube networks.

Three-dimensional (3D) assemblies based on carbon nanomaterials still lag behind their individual one-dimensional building blocks in terms of mechanical and electrical properties. Here we demonstrate a simple strategy for the fabrication of an open porous 3D self-organized double-hierarchical carbon nanotube tube structure with properties advantageous to those existing so far. Even though no additional crosslinking exists between the individual nanotubes, a high reinforcement effect in compression and tensile characteristics is achieved by the formation of self-entangled carbon nanotube (CNT) networks in all three dimensions, employing the CNTs in their high tensile properties. Additionally, the tubular structure causes a self-enhancing effect in conductivity when employed in a 3D stretchable conductor, together with a high conductivity at low CNT concentrations. This strategy allows for an easy combination of different kinds of low-dimensional nanomaterials in a tube-shaped 3D structure, enabling the fabrication of multifunctional inorganic-carbon-polymer hybrid 3D materials.

Nanomechanics of individual aerographite tetrapods.

Carbon-based three-dimensional aerographite networks, built from interconnected hollow tubular tetrapods of multilayer graphene, are ultra-lightweight materials recently discovered and ideal for advanced multifunctional applications. In order to predict the bulk mechanical behaviour of networks it is very important to understand the mechanics of their individual building blocks. Here we characterize the mechanical response of single aerographite tetrapods via in situ scanning electron and atomic force microscopy measurements. To understand the acquired results, which show that the overall behaviour of the tetrapod is governed by the buckling of the central joint, a mechanical nonlinear model was developed, introducing the concept of the buckling hinge. Finite element method simulations elucidate the governing buckling phenomena. The results are then generalized for tetrapods of different size-scales and shapes. These basic findings will permit better understanding of the mechanical response of the related networks and the design of similar aerogels based on graphene and other two-dimensional materials.

Fermentation based carbon nanotube multifunctional bionic composites.

The exploitation of the processes used by microorganisms to digest nutrients for their growth can be a viable method for the formation of a wide range of so called biogenic materials that have unique properties that are not produced by abiotic processes. Here we produced living hybrid materials by giving to unicellular organisms the nutrient to grow. Based on bread fermentation, a bionic composite made of carbon nanotubes (CNTs) and a single-cell fungi, the Saccharomyces cerevisiae yeast extract, was prepared by fermentation of such microorganisms at room temperature. Scanning electron microscopy analysis suggests that the CNTs were internalized by the cell after fermentation bridging the cells. Tensile tests on dried composite films have been rationalized in terms of a CNT cell bridging mechanism where the strongly enhanced strength of the composite is governed by the adhesion energy between the bridging carbon nanotubes and the matrix. The addition of CNTs also significantly improved the electrical conductivity along with a higher photoconductive activity. The proposed process could lead to the development of more complex and interactive structures programmed to self-assemble into specific patterns, such as those on strain or light sensors that could sense damage or convert light stimulus in an electrical signal.

Tribological characteristics of few-layer graphene over Ni grain and interface boundaries.

The tribological properties of metal-supported few-layered graphene depend strongly on the grain topology of the metal substrate. Inhomogeneous distribution of graphene layers at such regions led to variable landscapes with distinguishable roughness. This discrepancy in morphology significantly affects the frictional and wetting characteristics of the FLG system. We discretely measured friction characteristics of FLG covering grains and interfacial grain boundaries of polycrystalline Ni metal substrate via an atomic force microscopy (AFM) probe. The friction coefficient of FLG covered at interfacial grain boundaries is found to be lower than that on grains in vacuum (at 10(-5) Torr pressure) and similar results were obtained in air condition. Sliding history with AFM cantilever, static and dynamic pull-in and pull-off adhesion forces were addressed in the course of friction measurements to explain the role of the out-of-plane deformation of graphene layer(s). Finite element simulations showed good agreement with experiments and led to a rationalization of the observations. Thus, with interfacial grain boundaries the FLG tribology can be effectively tuned.