ABSTRACT
Mixed-metal inorganic fluoride, Co0.60Fe0.40F3, solid solutions are obtained through topochemical reactions of Co2FeCl(OH)6·2H2O LDH with molecular fluorine, F2, at temperatures as low as 100 °C. This solid solution possesses interesting F(â¢)-releasing ability, and its efficiency as a solid-state fluorinating agent is demonstrated on a commercial polyethylene film. (19)F solid state NMR and contact angle measurements underline the efficient fluorination of this polymer.
Subject(s)
Cobalt/chemistry , Fluorine/chemistry , Halogenation , Hydroxides/chemistry , Iron/chemistry , Models, Molecular , Molecular ConformationABSTRACT
In order to enhance the durability of chemical filters for ozone molecules, devoted to microsystem for the selective detection of NO2 in the environment, the adsorption of indigo molecules onto the surface of carbonaceous nanomaterials (multi-walled carbon nanotubes, a mixture of nanodisks/nanocones, nanofibres) was investigated. The surface of the multi-walled carbon nanotubes was coated by π-stacking with adsorbed indigo molecules. An excess of indigo has resulted in a biphasic sample where nanotubes covered with indigo coexist with free indigo particles. Although similar filtering yields toward O3 (close to 100%) and NO2 (around 0%) were obtained as compared to individual materials, the indigo/MWCNTs samples exhibit enhanced durability as chemical filter at high ozone concentration (1 ppm).
