Building a small fire database for Sub-Saharan Africa from Sentinel-2 high-resolution images.

Coarse resolution sensors are not very sensitive at detecting small fire patches, making current estimations of global burned areas (BA) very conservative. Using medium or high-resolution sensors to generate BA products becomes then a priority, particularly in areas where fires tend to be small and frequent. Building on previous work that developed a small fire dataset (SFD) for Sub-Saharan Africa for 2016, this paper presents a new version of the dataset for 2019 using the two Sentinel-2 satellites (A and B) and VIIRS active fires. Total estimated BA was 4.8 Mkm2. This value was much higher than estimations from two global, coarser-spatial resolution BA products based on MODIS data for the same area and period: 80 % greater than estimates from FireCCI51 (based on MODIS 250 m bands) and 120 % larger than MCD64A1 (based on MODIS 500 m bands). The main differences were observed in those months with higher fire occurrence (November to January for the Northern Hemisphere regions and June to September for the Southern Hemisphere ones). Accuracy assessment of the SFD product was based on a novel sampling strategy designed to obtain independent fire reference perimeters. Validation results showed remarkable high accuracy values comparing to existing global BA products. Overall omission errors (OE) were estimated as 8.5 %, commission errors (CE) as 15.0 %, with a Dice Coefficient of 87.7 %. All of these estimations implied significant improvements over the global, coarser spatial resolution BA products (OE > 50 % and CE > 20 % for the same area and period), as well as over the previous SFD product for 2016 of the same area, generated from a single Sentinel-2 satellite and MODIS active fires (OE = 26.5 % and CE = 19.3 %). Temporal accuracies greatly increased as well with the new product, with 92.5 % of fires detected within the first 10 days of occurrence.

Two stage biological treatment of a diazo reactive textile dye and the fate of the dye metabolites.

A two stage anaerobic/aerobic bacterial process was used to decolorize and partially mineralize a reactive vinyl sulfone diazo dye C.I. Reactive Black 5 (RB5) in a synthetic wastewater. Since the anchor group of reactive dyes reacts during the dyeing process, the effect the degree of hydrolysis of the vinyl sulfone dye had on decolorization, mineralization and toxicity in each stage was investigated. An overall color removal of approximately 65% was found for both the fully and partially hydrolyzed dye. Partial mineralization of the fully hydrolyzed RB5 was achieved in the two stage rotating disc reactors. While the anchor group metabolite p-aminobenzene-2-hydroxyethylsulfonic acid (p-ABHES) was mineralized, an oxidized form of the center metabolite (1,2-ketimino-7-amino-8-hydroxynaphthalene-3,6-disulfonic acid) remained in the aerobic stage effluent, causing the effluent to be colored although no RB5 was present. Partially hydrolyzed dye in the influent with vinyl forms of the anchor group caused cessation of biogas production and a reduction in decolorization efficiency in the anaerobic stage. No evidence for mineralization of the partially hydrolyzed dye or its metabolites was found. A method for evaluating dye mineralization using lumped parameters is presented.