Rapid carbothermal shocking fabrication of iron-incorporated molybdenum oxide with heterogeneous spin states for enhanced overall water/seawater splitting.

Molybdenum dioxide (MoO2) has been considered as a promising hydrogen evolution reaction (HER) electrocatalyst. However, the active sites are mainly located at the edges, resulting in few active sites and poor activity in the HER. Herein, we first reported on an efficient strategy to incorporate Fe into MoO2 nanosheets on Ni foam (Fe-MoO2/NF) using a rapid carbothermal shocking method (820 °C for 127 s). Notably, the different spin states between Fe and Mo atoms could lead to rich lattice dislocations in Fe-MoO2/NF, exposing abundant oxygen vacancies and the low-oxidation-state of Mo sites during the rapid Joule heating process. As tested, the catalyst exhibited superior activity with ultralow overpotentials (HER: 17 mV@10 mA cm-2; oxygen evolution reaction (OER): 310 mV@50 mA cm-2) and high OER selectivity in alkaline seawater splitting. Meanwhile, this catalyst was equipped in a home-made anion exchange membrane (AEM) seawater electrolyzer, which achieved a low energy consumption (5.5 kW h m-3). More importantly, Fe-MoO2/NF also coupled very well with a solar-driven electrolytic system and turned out a solar-to-hydrogen (STH) efficiency of 13.5%. Theoretical results also demonstrated that Fe incorporated and abundant oxygen vacancies in MoO2 can distort the distance of the Mo-O bonds and regulate the electronic structure, thus optimizing the binding energy of H*/OOH* adsorption. This method can be extended to other heterogeneous spin states in MoO2-based catalysts (e.g. Ni-MoO2/NF, Co-MoO2/NF) for seawater splitting, and provide a simple, efficient and universal strategy to prepare highly-efficient MoO2-based electrocatalysts.

Mechanical properties of cracked teeth with different dental materials and crown parameters: An in vitro proof-of-concept.

OBJECTIVE: This work analyzed and compared the mechanical properties of identical cracked tooth models treated with different materials and crown parameters. Thus, to provide dentists with a more structured way to select materials and geometric parameters and determine the strongest restoration model for cracked teeth. METHODS: This work used finite element analysis (FEA). We applied 25 restorative models, including five restorative materials, and three preparation parameters. Seven mechanical properties of the cracked tooth preparation were analyzed using correlation analysis. RESULTS: The highest lifetime of the cracked preparation was obtained for crowns with a 5° of polymerization, width = 0.8 mm, and a length offset of 0.2 mm. The highest lifetime was obtained with ZC crown material, but the least deformation of the cracked tip was obtained with LU material. SIGNIFICANCE: The results showed that the larger MOE material for the crown and a reasonable increase in the thickness and length of the crown is a favorable method to prevent further cracks to extend. This FEA study, thereby forming a novel basis for clinical guidance as to preparation of dental crowns applicable to cracked teeth.

Astellolides R-W, Drimane-Type Sesquiterpenoids from an Aspergillus parasiticus Strain Associated with an Isopod.

Sesquiterpenoids with a cage-like multiring frame are rarely found in nature. Mining of the isopod-derived fungus Aspergillus parasiticus SDU001 by the one strain-many compounds (OSMAC) strategy unexpectedly led to the discovery of fungal drimane-type sesquiterpenoids astellolide R (1), featuring an unusual cage-like 6/6/5/6/5 pentacyclic ring system, astellolide S (2), possessing a rare nicotinic acid building block, and astellolides T-W (3-6). Their structures were comprehensively assigned by spectroscopic data analysis, single-crystal X-ray diffraction, and electronic circular dichroism calculations. Furthermore, compounds 3 and 5 exhibited anti-inflammatory activity by inhibiting the lipopolyssacharide-induced NO production in RAW264.7 macrophages with IC50 values of 6.1 ± 0.8 and 6.8 ± 0.8 µM, respectively. A putative biosynthetic pathway for 1 is proposed. Our results enlarge the chemical space of the drimane-type sesquiterpenoids generated from endophytic fungi.

In silico fatigue performance of molars restored with full crowns under alternating cyclic loadings.

OBJECTIVE: In this study, a preclinical approach was used to analyze and directly compare the fatigue performance (fatigue life and damage percentage) and maximum principal stresses (Max. Ps) of prepared models treated with different materials and geometric parameters. METHODS: Four groups of preparative parameters (crown width, crown length, degree of polymerization and material) were selected, each with five variables. An alternating cyclic occlusal load with an amplitude of 300 N was applied to the ball part along the longitudinal axis. The fatigue properties of the preparations and Max.Ps were analyzed. RESULTS: A shoulder width of 0.8 mm, a shoulder height offset of 0.2 mm, a degree of polymerization of 5°, and a crown material of ZC resulted in the smallest percentage of damage. In contrast, the effect of different modulus of elasticity (MOE) on Max.Ps was not significant (p = 0.609). CONCLUSION: The results suggest that the selection of larger modulus of elasticity MOE and larger Poisson's ratio material's, preparation of larger shoulder widths within safety, reasonable increase in crown length, and selection of larger degree of polymerization are favorable methods to protect the preparation.

Stress intensity factor of a cracked molar restored with different materials and designs: A 3D-FEA.

OBJECTIVE: This work used 3D finite element analysis (FEA) to analyze and directly compare the stress intensity factor (SIF) and stress distribution at the crack tip of identical cracked tooth models restored with different materials and crown parameters. METHODS: A 3D model of the cracked tooth was generated. Then, we applied 25 restorative models, including three parameters (shoulder height, width, and degree of polymerization), five restorative materials (GC, IPS, LU, ZC, VE), and two combinations of types of cement (RMGIC and GIC). An occlusal load of 800N was applied to the spherical part along the longitudinal axis. The stress distribution of the preparation and the SIF of the crack tip was analyzed. RESULTS: The crack tip SIF was minimal for a shoulder height offset of 0.8 mm (P = 0.032), a shoulder width of 0.6 mm (P = 0.045), a crown material of ZC (P < 2e-16), and a cement material of RMGIC (P < 0.05), respectively. In contrast, the effect of different polymerization degrees on SIF was insignificant (P = 0.95). CONCLUSION: Our results suggest that the selection of a larger modulus of elasticity (MOE) material for the crown, the preparation of a smaller shoulder width within a safe range, a reasonable increase in the crown length, and the selection of adhesive materials with high fracture toughness are favorable methods to prevent further crack extension.

User's image perception improved strategy and application of augmented reality systems in smart medical care: A review.

BACKGROUND: Augmented reality (AR) is a new human-computer interaction technology that combines virtual reality, computer vision, and computer networks. With the rapid advancement of the medical field towards intelligence and data visualisation, AR systems are becoming increasingly popular in the medical field because they can provide doctors with clear enough medical images and accurate image navigation in practical applications. However, it has been discovered that different display types of AR systems have different effects on doctors' perception of the image after virtual-real fusion during the actual medical application. If doctors cannot correctly perceive the image, they may be unable to correctly match the virtual information with the real world, which will have a significant impact on their ability to recognise complex structures. METHODS: This paper uses Citespace, a literature analysis tool, to visualise and analyse the research hotspots when AR systems are used in the medical field. RESULTS: A visual analysis of the 1163 articles retrieved from the Web of Science Core Collection database reveals that display technology and visualisation technology are the key research directions of AR systems at the moment. CONCLUSION: This paper categorises AR systems based on their display principles, reviews current image perception optimisation schemes for various types of systems, and analyses and compares different display types of AR systems based on their practical applications in the field of smart medical care so that doctors can select the appropriate display types based on different application scenarios. Finally, the future development direction of AR display technology is anticipated in order for AR technology to be more effectively applied in the field of smart medical care. The advancement of display technology for AR systems is critical for their use in the medical field, and the advantages and disadvantages of various display types should be considered in different application scenarios to select the best AR system.

Ultrathin coordination polymer nanosheets modified with carbon quantum dots for ultrasensitive ammonia sensors.

Exposure to ammonia (NH3) is known harmful to health, environment and industrial facilities, hence it is important for the trace detection of NH3. Herein, for the first time, ultrasensitive room temperature NH3 sensors are realized by assembling carbon quantum dots (CQDs) on free-standing ultrathin coordination polymers (CPs) nanosheets (Co[Ni(CN)4]) with an average thickness of ∼2.5 nm, which demonstrate excellent sensitivity (Ra/Rg = 87.7 to 30 ppm), fast gas response speed (∼10 s to 30 ppm), remarkable repeatability, high selectivity, good long-term stability and low limit of theoretical detection (∼8 ppb) toward NH3 gas. The NH3 gas sensor enhancement through incorporation of CQDs provides a simple and environment-friendly strategy for further improving sensor property of CPs nanosheets. This work provides an effective way to construct new electrode materials for high-performance gas sensor devices via the rational design.

The state of the art and future trends of root canal files from the perspective of patent analysis: a study design.

The goal of this review is to present a detailed and comprehensive description of the published work from the past decade regarding methods of improved material, geometric design, and additional functions in root canal files. The main improved methods of files and the most common technologies were further addressed, underlining their advantages and main limitations. Online databases (the Derwent Innovations Index) were consulted on this topic. Published work from 2010 to 2022 was collected and analyzed the relevant papers were chosen for inclusion in this review. The patent map classified the latest phase of the root canal files based on the analysis of the number of patents. The performance of the root canal files, such as materials. Directly affects the quality of the root canal therapy. We provided a thorough review of advances in the field of root canal files. In particular, three categories of improved methods were examined and compared, including material-based methods, geometry-based methods, and those based on additional functions. To understand this state of the art of different improved methods of root canal files, we conducted a literature analysis and a series of comparisons between different methods. The features and limitations of each method of root canal files were further discussed. Finally, we identified promising research directions in advancing the methods for the improved performance of root canal files. There is no perfect technology for all material/geometric design/additional functions, capable alone of fulfilling all the specificity and necessities of every patient. Although it is very promising, the material of the files remains understudied, and further work is required to make material science a pervasive technology in root canal therapy, and contribute to endodontic and periapical diseases by assisting in the subsequent development of root canal files.

An improved typhoon simulation method based on Latin hypercube sampling method.

In order to further improve the prediction accuracy of typhoon simulation method for extreme wind speed in typhoon prone areas, an improved typhoon simulation method is proposed by introducing the Latin hypercube sampling method into the traditional typhoon simulation method. In this paper, the improved typhoon simulation method is first given a detailed introduction. Then, this method is applied to the prediction of extreme wind speeds under various return periods in Hong Kong. To validate this method, two aspects of analysis is carried out, including correlation analysis among typhoon key parameters and prediction of extreme wind speeds under various return periods. The results show that the correlation coefficients among typhoon key parameters can be maintained satisfactorily with this improved typhoon simulation method. The results show that the improved typhoon simulation method can generate the correlations among all typhoon key parameters satisfactorily. Compared with the traditional typhoon simulation method, the improved typhoon simulation method has higher accuracy in predicting the typhoon extreme wind speed in Hong Kong, increasing by about 8% and 11% respectively at 200 m height and gradient height.

2D coordination polymer-derived CoSe2-NiSe2/CN nanosheets: the dual-phase synergistic effect and ultrathin structure to enhance the hydrogen evolution reaction.

The evolution of cost-effective hydrogen evolution reaction (HER) electrocatalysts is of great significance for the development of clean energy. Exploring effective synthesis strategies to optimize the performance of non-noble metal electrocatalysts has always attracted our attention. Herein, ultrathin coordination polymers were used as precursors to controllably synthesize two-dimensional (2D) ultrathin dual-phase transition metal selenide (TMSs)/carbon-nitrogen (CN) composites (CoSe2-NiSe2/CN) by a two-step method (first a low temperature hydrothermal method for selenization, and then high temperature calcination selenization). Benefiting from its large specific surface area (49 m2 g-1), abundant catalytically active sites and synergistic effects, CoSe2-NiSe2/CN can significantly enhance the HER catalytic activity and exhibits good electrocatalytic activity with an overpotential of 150 mV at -10 mA cm-2, and a small Tafel slope of 42 mV dec-1 in an acidic electrolyte for the HER. This work provides a new strategy for optimizing the HER catalytic activity of TMSs by preparing 2D ultrathin dual-phase TMS composite materials.

A sulfonated cobalt phthalocyanine/carbon nanotube hybrid as a bifunctional oxygen electrocatalyst.

The development of effective bifunctional catalysts for both oxygen reduction reactions (ORRs) and oxygen evolution reactions (OERs) is crucial for improving the performance of charge and discharge processes in rechargeable metal-air batteries. Here, we report a sulfonated cobalt phthalocyanine/carbon nanotube hybrid (CoPc-SO3H/CNT) prepared by a facile anchoring method along with sonication and magnetic stirring. The resulting CoPc-SO3H/CNT hybrid exhibits better catalytic activity for ORRs and OERs than the cobalt phthalocyanine/carbon nanotube hybrid (CoPc/CNT), sulfonated cobalt phthalocyanine (CoPc-SO3H), cobalt phthalocyanine (CoPc) and the carbon nanotube (CNT). The onset potential of CoPc-SO3H/CNT for the ORR in 0.1 M KOH is 0.88 V (vs. RHE), which is higher than that of CoPc/CNT (0.85 V), the CNT (0.80 V), CoPc-SO3H (0.77 V) and CoPc (0.66 V). Meanwhile, the CoPc-SO3H/CNT hybrid shows a much lower OER potential (1.62 V) at a current density of 10 mA cm-2 compared to CoPc-SO3H (1.64 V), CoPc/CNT (1.74 V), the CNT (1.96 V) and CoPc (>2.00 V) in 1 M KOH. Similar patterns are also found in 0.1 M KOH solution. Both the conductive CNT and the electron-withdrawing sulfonic groups are confirmed to benefit the electrochemical oxygen reactions (ORRs/OERs).

Preparation and characterization of cellulose-based adsorbent and its application in heavy metal ions removal.

In this work, we develop a facile route to prepare a cellulose-based adsorbent, namely carboxymethylated cellulose fiber (CMF), for the water purification. The as-prepared CMF bio-adsorbent was synthesized via a controllable carboxymethylation modification in the case of maintaining inherent fibrous framework. The CMF bio-adsorbent was applied to adsorb the heavy metal ions, such as Cu(II) and Ni(II), from aqueous solution. Results showed that the CMF adsorbent exhibited excellent adsorption capacity toward these ions and a higher selectivity for the Cu(II) removal based on surface complexation and electrostatic interaction mechanisms. Besides, the adsorption isotherm of Cu(II) fitted better with the Langmuir isotherm model. Moreover, the relationship between the charges and adsorption capacity of CMF to Cu(II) revealed that the enhanced adsorption capacity of CMF adsorbent can mainly attributed to its increased inner charges rather than surface charges, which can provide a new strategy for the further modification of cellulose-based adsorbent.

Monodisperse selenium-substituted hydroxyapatite: Controllable synthesis and biocompatibility.

Hydroxyapatite (HA) is the major inorganic component of natural bone tissue. As an essential trace element, selenium involves in antioxidation and anticancer of human body. So far, ion-doped hydroxyapatites (HAs) are widely investigated owing to their great applications in field of biomaterial, biological labeling. In this paper, series of monodisperse HA doped with SeO32- (SeHA) was successfully synthesized based on the liquid-solid-solution (LSS) strategy. The obtained samples were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and energy-dispersive spectrometer (EDS). The results indicated that the SeO32- doping level of the Se/(P+Se) molar ratio of 0-0.4 can be requisitely controlled, and the morphology of SeHA nanoparticles varied from nanorods to nanoneedles with increasing Se/(P+Se) molar ratio. Significantly, the as-synthesized SeHA nanocrystals exhibit a low cytotoxicity for osteoblastic cells, showing exciting potentials for application in artificial scaffold materials inhibiting of tumor growth in bone.

Determination of cyantraniliprole and its major metabolite residues in pakchoi and soil using ultra-performance liquid chromatography-tandem mass spectrometry.

A rapid, simple and reliable analytical method was developed for the determination of cyantraniliprole and its major metabolite J9Z38 in pakchoi and soil by using ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The sample preparation approach is known as QuEChERS, which stands for quick, easy, cheap, effective, rugged and safe. Samples were extracted with acetonitrile, and cleaned up with dispersive primary and secondary amine sorbent before analysis by UPLC-MS/MS. The limit of quantitation for cyantraniliprole and J9Z38 was 0.01 mg/kg in both pakchoi and soil. Average recoveries of cyantraniliprole and J9Z38 at three fortified levels (0.01, 0.05, 0.1 mg/kg) ranged from 77.8% to 102.5% with relative standard deviation of 1.6%-8.9%. This method has been applied to the analysis of cyantraniliprole and J9Z38 residues in real pakchoi and soil samples selected from field. The results of the residue dynamic experiment showed that the half-life of cyantraniliprole ranged from 2.9 to 6.4 days in pakchoi and 8.7 to 18.2 days in soil, respectively. The final residual levels of cyantraniliprole in pakchoi and soil from Guangdong and Shanghai were below 0.20 and 0.10 mg/kg, respectively; similarly, the final residual levels of J9Z38 in pakchoi and soil from Guangdong and Shanghai were <0.07 and 0.01 mg/kg. These results will be helpful in setting maximum residue limit guidance for cyantraniliprole in pakchoi in China.