Preparation of graphene/carbon nanotube-cellulose composites assisted by ionic liquids: A review.

As is well known, cellulose, as a natural polymer material with abundant reserves, plays an irreplaceable role as the major raw material in energy and chemical-related fields. With the continuous advancement of technology, native single-component cellulose is often unsatisfactory for practical applications, constructing composites is an effective means of expanding the applications. When compounded with other ingredients to prepare composites, cellulose usually needs to be dissolved and regenerated to obtain good dispersion. Current studies have revealed that cellulose is insoluble in conventional solvents, and the limited types of solvent systems that can dissolve cellulose tend to degrade the cellulose during the dissolution process, altering the cellulose properties. Ionic liquids (ILs) are a class of solvents that are capable of dissolving cellulose without adversely affecting the cellulose during the dissolution process, such as degradation. Graphene and carbon nanotubes (CNTs) are poorly dispersed and easily agglomerated by π-π stacking in general solvents, whereas ILs can effectively shield them from π-π stacking, resulting in a favorable and steady dispersion. Thus, the cellulose composites of graphene/CNTs can be prepared with the assistance of ILs. In this paper, the solubilization of cellulose by ILs and the solubilization mechanism to the preparation of cellulose composites with graphene/CNTs are reviewed, the interactions between graphene, CNTs and cellulose in the composites are elucidated, and the preparation of cellulose composites with graphene/CNTs is introduced in terms of their structure, properties and application potential.

A Rhodamine-Spiropyran Conjugate Empowering Tunable Mechanochromism in Polymers under Multiple Stimuli.

Mechanochromic functionality realized via the force-responsive mechanophores in polymers has great potential for damage sensing and information storage. Mechanophores with the ability to recognize multiple stimuli for tunable chromic characteristics are highly sought after for versatile sensing ability and color programmability. Nevertheless, the majority of mechanophores are based on single-component chromophores with limited sensitivity, or require additional fabrication technology for multi-modal chromism. Here, we report a novel multifunctional mechanophore capable of vividly detectable and tunable mechanochromism in polymers. This synergistic optical coupling relies on strategically fusing rhodamine and spiropyran (Rh-SP), and tethering polymer chains on both subunits. The mechanochromic behaviors of the Rh-SP-linked polymers under sonication and compression are thoroughly evaluated in response to changes in force and the light-controlled relaxation process. Non-sequential ring-opening of the two subunits under force is identified, endowing high-contrast mechanochromism. Light-induced differential ring-closing reactions of the two subunits, together with the acidichromism of the SP moiety, are employed to engineer elastomers with programmable and wide-spectrum colors. Our work presents an effective strategy for highly appreciable and regulable mechanochromic functionality, and also provides new insights into the rupture mechanisms of π-fused mechanophores, as well as how the stimuli history controls stress accumulation in polymers.

Electrokinetic remediation for the removal of heavy metals in soil: Limitations, solutions and prospection.

Electrokinetic remediation (EKR) technology is a promising method to remove heavy metals from low permeability soil, because it is environmentally friendly, efficient and economical, and can realize in-situ remediation. In this paper, the basic principles and related physical and chemical phenomena of EKR are systematically summarized, and three limiting problems of EKR technology are put forward: the weak ability of dissolving metals, focusing effect, and energy consumption. There are many methods to solve these technical problems, but there is a lack of systematic summary of the causes of problems and solutions. Based on various enhanced EKR technologies, this paper summarizes the main ideas to solve the limiting problems. The advantages and disadvantages of each technology are compared, which has guiding significance for the development of new technology in the future. This paper also discusses the dissolution of residual heavy metals, which is rare in other articles. The energy consumption of EKR and the remediation effect are equally important, and both can be used as indicators for evaluating the feasibility of new technologies. This paper reviews the influence of various electric field conditions on power consumption, such as renewable energy supply, new electrode materials and electrode configurations, suitable voltage values and functional electrolytes. In addition, a variety of energy consumption calculation methods are also introduced, which are suitable for ohmic heat loss, energy distribution when there is non-target ion competition, and power consumption of specific ions in various metal ions. Researchers can make selective reference according to their actual situations. This paper also systematically introduces the engineering design and cost calculation of EKR, lists the research progress of some engineering cases and pilot-scale tests, analyzes the reasons why it is difficult to apply EKR technology in large-scale engineering at present, and puts forward the future research direction.

Hydrogen-Bonding Controlled Nickel-Catalyzed Regioselective Cyclotrimerization of Terminal Alkynes.

Herein we report a hydrogen-bonding controlled nickel-catalyzed regioselective cyclotrimerization of terminal alkynes in moderate to excellent yields with high regioselectivities toward 1,3,5-trisubstituted benzenes. This method features a cheap catalyst, mild reaction conditions, and excellent functional group compatibility. The Ni-B(OH)2 complex in situ generated from NiCl2·DME and tetrahydroxydiboron might act as an active catalyst. After three consecutive cis-additions of terminal alkynes, internal migratory insertion cyclization, and ß-boron elimination induced aromatization, 1,3,5-trisubstituted benzenes were selectively established.

Metal-Free Difunctionalization of Pyridines: Selective Construction of N-CF2H and N-CHO Dihydropyridines.

The reactivity of N-difluoromethylpyridinium salts is seldom explored because of their instability and low availability. Here we present a novel nucleophilic addition of N-difluoromethylpyridinium salts with nitroalkanes to synthesize N-CF2H-dihydropyridines and N-CHO-dihydropyridines in a highly efficient and regioselective pathway. This protocol exhibits good functional group tolerance and good to excellent yields.

Tetrahydroxydiboron-Promoted Radical Addition of Alkynols.

Tetrahydroxydiboron has previously been used as a borylation or reducing reagent in organic synthesis. Herein, we present a novel tetrahydroxydiboron-promoted radical addition of internal alkynes followed by intramolecular oxidation of alcohol through 1,5-hydrogen atom transfer. Preliminary mechanistic studies showed that the process might be initiated through N,N-dimethylformamide-assisted homolytic cleavage of tetrahydroxydiboron. This process provides a convenient synthesis of fluoroalkyl-substituted alkenes with a pendant aldehyde or ketone moiety.