Surface engineering of Al2O3 nanotubes by ureasolysis method for activating persulfate degradation of antibiotics.

Though ecofriendly, pure Al2O3 has never been used for activation of peroxodisulfate (PDS) to degrade pollutants. We report the fabrication of Al2O3 nanotubes by ureasolysis method for efficient activating PDS degradation of antibiotics. The fast ureasolysis in aqueous AlCl3 solution produces NH4Al(OH)2CO3 nanotubes, which are calcined to porous Al2O3 nanotubes, and the release of ammonia and carbon dioxide engineers the surface features of large surface area, numerous acidic-basic sites and suitable Zeta potentials. The synergy of these features facilitates the adsorption of the typical antibiotics ciprofloxacin and PDS activation, which is proved by experiment results and density functional theory simulation. The proposed Al2O3 nanotubes can catalyze 92-96% degradation of 10 ppm ciprofloxacin within 40 min, with chemical oxygen demand removal of 65-66% in aqueous, and 40-47% in whole including aqueous and catalysts. Ciprofloxacin at high concentration, other fluoroquinolones and tetracycline can also be effectively degraded. These data demonstrate the Al2O3 nanotubes prepared by the nature-inspired ureasolysis method has unique features and great potentials for antibiotics degradation.

Efficient Experimental Verification of Quantum Gates with Local Operations.

Verifying the correct functioning of quantum gates is a crucial step toward reliable quantum information processing, but it becomes an overwhelming challenge as the system size grows due to the dimensionality curse. Recent theoretical breakthroughs show that it is possible to verify various important quantum gates with the optimal sample complexity of O(1/ε) using local operations only, where ε is the estimation precision. In this Letter, we propose a variant of quantum gate verification (QGV) that is robust to practical gate imperfections and experimentally realize efficient QGV on a 2-qubit controlled-not gate and a 3-qubit Toffoli gate using only local state preparations and measurements. The experimental results show that, by using only 1600 and 2600 measurements on average, we can verify with 95% confidence level that the implemented controlled-not gate and Toffoli gate have fidelities of at least 99% and 97%, respectively. Demonstrating the superior low sample complexity and experimental feasibility of QGV, our work promises a solution to the dimensionality curse in verifying large quantum devices in the quantum era.

"Super-Heisenberg" and Heisenberg Scalings Achieved Simultaneously in the Estimation of a Rotating Field.

The Heisenberg scaling, which scales as N^{-1} in terms of the number of particles or T^{-1} in terms of the evolution time, serves as a fundamental limit in quantum metrology. Better scalings, dubbed as "super-Heisenberg scaling," however, can also arise when the generator of the parameter involves many-body interactions or when it is time dependent. All these different scalings can actually be seen as manifestations of the Heisenberg uncertainty relations. While there is only one best scaling in the single-parameter quantum metrology, different scalings can coexist for the estimation of multiple parameters, which can be characterized by multiple Heisenberg uncertainty relations. We demonstrate the coexistence of two different scalings via the simultaneous estimation of the magnitude and frequency of a field where the best precisions, characterized by two Heisenberg uncertainty relations, scale as T^{-1} and T^{-2}, respectively (in terms of the standard deviation). We show that the simultaneous saturation of two Heisenberg uncertainty relations can be achieved by the optimal protocol, which prepares the optimal probe state, implements the optimal control, and performs the optimal measurement. The optimal protocol is experimentally implemented on an optical platform that demonstrates the saturation of the two Heisenberg uncertainty relations simultaneously, with up to five controls. As the first demonstration of simultaneously achieving two different Heisenberg scalings, our study deepens the understanding on the connection between the precision limit and the uncertainty relations, which has wide implications in practical applications of multiparameter quantum estimation.

Zero-trade-off multiparameter quantum estimation via simultaneously saturating multiple Heisenberg uncertainty relations.

Quantum estimation of a single parameter has been studied extensively. Practical applications, however, typically involve multiple parameters, for which the ultimate precision is much less understood. Here, by relating the precision limit directly to the Heisenberg uncertainty relation, we show that to achieve the highest precisions for multiple parameters at the same time requires the saturation of multiple Heisenberg uncertainty relations simultaneously. Guided by this insight, we experimentally demonstrate an optimally controlled multipass scheme, which saturates three Heisenberg uncertainty relations simultaneously and achieves the highest precisions for the estimation of all three parameters in SU(2) operators. With eight controls, we achieve a 13.27-dB improvement in terms of the variance (6.63 dB for the SD) over the classical scheme with the same loss. As an experiment demonstrating the simultaneous achievement of the ultimate precisions for multiple parameters, our work marks an important step in multiparameter quantum metrology with wide implications.

Minimizing Backaction through Entangled Measurements.

When an observable is measured on an evolving coherent quantum system twice, the first measurement generally alters the statistics of the second one, which is known as measurement backaction. We introduce, and push to its theoretical and experimental limits, a novel method of backaction evasion, whereby entangled collective measurements are performed on several copies of the system. This method is inspired by a similar idea designed for the problem of measuring quantum work [Perarnau-Llobet et al., Phys. Rev. Lett. 118, 070601 (2017)PRLTAO0031-900710.1103/PhysRevLett.118.070601]. By using entanglement as a resource, we show that the backaction can be extremely suppressed compared to all previous schemes. Importantly, the backaction can be eliminated in highly coherent processes.

Experimental Optimal Orienteering via Parallel and Antiparallel Spins.

Antiparallel spins are superior in orienteering to parallel spins. This intriguing phenomenon is tied to entanglement associated with quantum measurements rather than quantum states. Using photonic systems, we experimentally realize the optimal orienteering protocols based on parallel spins and antiparallel spins, respectively. The optimal entangling measurements for decoding the direction information from parallel spins and antiparallel spins are realized using photonic quantum walks, which is a useful idea that is of wide interest in quantum information processing and foundational studies. Our experiments clearly demonstrate the advantage of antiparallel spins over parallel spins in orienteering. In addition, entangling measurements can extract more information than local measurements even if no entanglement is present in the quantum states.

Control-Enhanced Sequential Scheme for General Quantum Parameter Estimation at the Heisenberg Limit.

The advantage of quantum metrology has been experimentally demonstrated for phase estimations where the dynamics are commuting. General noncommuting dynamics, however, can have distinct features. For example, the direct sequential scheme, which can achieve the Heisenberg scaling for the phase estimation under commuting dynamics, can have even worse performances than the classical scheme when the dynamics are noncommuting. Here we realize a scalable optimally controlled sequential scheme, which can achieve the Heisenberg precision under general noncommuting dynamics. We also present an intuitive geometrical framework for the controlled scheme and identify sweet spots in time at which the optimal controls used in the scheme can be prefixed without adaptation, which simplifies the experimental protocols significantly. We successfully implement the scheme up to eight controls in an optical platform and demonstrate a precision near the Heisenberg limit. Our work opens the avenue for harvesting the power of quantum control in quantum metrology, and provides a control-enhanced recipe to achieve the Heisenberg precision under general noncommuting dynamics.

Deterministic realization of collective measurements via photonic quantum walks.

Collective measurements on identically prepared quantum systems can extract more information than local measurements, thereby enhancing information-processing efficiency. Although this nonclassical phenomenon has been known for two decades, it has remained a challenging task to demonstrate the advantage of collective measurements in experiments. Here, we introduce a general recipe for performing deterministic collective measurements on two identically prepared qubits based on quantum walks. Using photonic quantum walks, we realize experimentally an optimized collective measurement with fidelity 0.9946 without post selection. As an application, we achieve the highest tomographic efficiency in qubit state tomography to date. Our work offers an effective recipe for beating the precision limit of local measurements in quantum state tomography and metrology. In addition, our study opens an avenue for harvesting the power of collective measurements in quantum information-processing and for exploring the intriguing physics behind this power.