High-Temperature Ash Melting and Fluidity Behavior upon the Cocombustion of Sewage Sludge and Coal.

Wastewater treatment produces a large amount of sludge, where the minimizing of the disposed sludge is essential for environmental protection. The co-combustion of sludge with coal is a preferable method for sewage sludge disposal from the economic and environmental perspective. The co-combustion of sludge has been widely used in the industry with the advantages of large processing capacity. The melting characteristics of ash are an important criterion for the selection of the co-combustion methods and furnace types. In this study, two types of sludge and four types of coal with different ash melting points were selected, where the ash melting behavior upon co-combustion is investigated by experimental and thermodynamical approaches. Especially, the slag fluidity upon co-combustion is explored via a modified inclined plane method. It has been found that the presence of SiO2 and CaO in sludge substantially enhances its fusion temperature owing to the high content of CaO, while SiO2 acts as a solvent, facilitating the co-melting of other oxides and raising the sludge fusion temperature. Fe2O3 exhibits a specific mass fraction within the range of 10-20%. Furthermore, the presence of CaO and SiO2 prohibits the flow ability of the slag at high temperatures, and Fe2O3 promotes the flow ability for sludge at high temperatures. With increasing base/acid ratio, the sludge flow velocity increases remarkably and peaks at 1.6. The interaction between Fe-Ca and Si-AI significantly affects the fluidity significantly. The findings are expected to optimize the condition of co-combustion and desirable furnace design for the incineration of sludge.

Influence of coke heterogeneity and the interaction between different coke species on the emission of toxic HCN and NOx from FCC spent catalyst regeneration.

Concerning the emissions of hydrogen cyanide (HCN) and other N-bearing air pollutants from the fluid catalytic cracking (FCC) regeneration units, this paper has conducted a comprehensive testing and surface characterisation of four industrial spent catalysts, aged catalysts and hard coke sample in three different schemes, Ar-TPD, O2 -TPO and rapid heating to elaborate the transformation of N upon the influence of the heterogeneity of coke and N speciation. In the Ar-TPD scheme, the surface N is responsive for the emission of gaseous NH3 from pyrrolic N-5 and HCN from both pyridinic N-6 and quaternary N-Q. The removal of soft coke is beneficial in promoting the surface exposure of hard coke, thereby increasing the HCN emission dramatically. In the O2-TPO scheme, the oxygen accessibility is the principal factor governing the emission of HCN. The external soft coke is able to access the bulk O2 firstly, the combustion of which in turn provides heat back to promote the cracking of internal hard coke from the same and neighbouring particles to release more HCN. The induction effect of bulk O2 is also superior over the spent catalyst properties in formulating a nearly identical trend of HCN emission for all the four spent catalysts tested. Finally, for the use of rapid heating scheme that is typical in a commercial FCC regenerator, it is effective in accelerating the volatilisation of soft coke quickly, thereby promoting the oxygen accessibility to hard coke and the internal N-bearing precursors so as to mitigate the emission of HCN effectively. The use of a large superficial velocity of gas is further effective in sweeping the volatiles including HCN away from the catalyst, promoting their oxidation extent accordingly.