Photocatalytic reduction of Cr(VI) using Mg-doped WO3 nanoparticles.

The hydrothermal synthesis method was employed for the fabrication of pristine tungsten trioxide (WO3) and that of varying dopant percentages (1, 3 and 5% m/m) of magnesium (Mg-WO3). The optical and structural properties of the synthesized materials were characterized using DRS, XRD, FTIR, TEM, BET, FESEM, XPS, PL, and Raman. Rectangular shaped nanostructures were observed through FESEM, wherein confirmed as monoclinic with the aid of XRD, FTIR and Raman analysis. Visualization of the doping was carried out using HRTEM imagery, which was also confirmed by a slight increase (0.0069 nm) of d spacing. As a consequence, band gaps were diminished and band edge positions were shifted. Band edge position shifts were confirmed via XPS analysis (0.08 eV). The point of zero charge was observed to shift towards positive upon doping at working pH 1 and 3.75 pH was the highest recorded. The rate of recombination was greatly reduced upon doping was observed through PL analysis. This was supported by DFT calculations, in which case the reduction of the rate of recombination was attributed to the introduction of Mg orbital. An improved efficiency was observed via the photo reduction of Cr(VI) metal ion in waste water, in which case, 97% reduction was attained.

Genotoxicity of metal based engineered nanoparticles in aquatic organisms: A review.

Engineered nanoparticles (ENPs) are an emerging class of environmental contaminants, but are generally found in very low concentrations and are therefore likely to exert sub-lethal effects on aquatic organisms. In this review, we: (i) highlight key mechanisms of metal-based ENP-induced genotoxicity, (ii) identify key nanoparticle and environmental factors which influence the observed genotoxic effects, and (iii) highlight the challenges involved in interpreting reported data and provide recommendations on how these challenges might be addressed. We review the application of eight different genotoxicity assays, where the Comet Assay is generally preferred due to its capacity to detect low levels of DNA damage. Most ENPs have been shown to cause genotoxic responses; e.g., DNA or/and chromosomal fragmentation, or DNA strand breakage, but at unrealistic high concentrations. The genotoxicity of the ENPs was dependent on the inherent physico-chemical properties (e.g. size, coating, surface chemistry, e.tc.), and the presence of co-pollutants. To enhance the value of published genotoxicity data, the role of environmental processes; e.g., dissolution, aggregation and agglomeration, and adsorption of ENPs when released in aquatic systems, should be included, and assay protocols must be standardized. Such data could be used to model ENP genotoxicity processes in open environmental systems.