Land use, land cover changes and expansion of artificial reservoirs in Eastern Thailand: implications for agriculture and vegetation drought reduction.

Eastern Thailand and Rayong province face perennial drought and water scarcity due to natural characteristics of climate and geology. Therefore, increasing water surface by man-made reservoirs is one of the priorities in the regional development plan to provide water adequately for industrial purposes, domestic consumption, and agriculture. The large reservoir constructions may induce land use, land cover changes (LULCC), yet it also is expected to alleviate the drought harshness in the region. By delineating Landsat satellite images and spatial analysis, this study revealed the LULCC in Rayong from 1990 to 2020. The most prominent LULCC was surface water expansion, about 10.9% per year, yet the increase was the most substantial in the first decade rather than the last two decades. Vegetation expansion was observed, contributing to an increase in forests/plantations and intensified agriculture by 39.19% and 25.54%, respectively. The LULCC corresponded to a 3.64% increase in ecosystem service values (ESV), implying positive benefits from the LULCC. Vegetation drought conditions monitored by the vegetation health index (VHI) exhibited an improvement trend, especially in the eastern basins. The development of artificial reservoirs was proven to stimulate the expansion of intensive agriculture and vegetation drought mitigation with spatial heterogeneity, spreading mainly across areas of the basins rather than remote areas. The research findings inform the efficiency of the reservoirs and irrigation systems regarding the beneficial effects on drought mitigation and water scarcity for agricultural cultivation. They also provide spatial information on areas still hindered by water problems that should be addressed in future strategies.

Effective adsorption of Pb(II) ion from aqueous solution onto ZSM-5 zeolite synthesized from Vietnamese bentonite clay.

ZSM-5 zeolite was successfully synthesized from bentonite clay sourced from Lam Dong Province, Vietnam, using the hydrothermal method at 170 °C for 18 h. The synthesized ZSM-5 (SiO2/Al2O3 ratio ~ 34) exhibited a single phase with high crystallinity (91.8%), and a clear and uniform shape. In a detailed examination of the synthesized material's Pb(II) adsorptive capacity, various factors were taken into account, including pH, interaction time, ionic strength, and the amount of adsorbent. Isotherms and kinetics were examined to elucidate the uptake behavior. Study results suggested that Pb(II) ion uptake by ZSM-5 was most appropriately described by the Sips isotherm and intraparticle diffusion kinetic models. The calculated maximum monolayer adsorption capacity according to the Langmuir isotherm model was 48.36 mg/g. Furthermore, the adsorption mechanisms of Pb(II) on ZSM-5 involving electrostatic interactions, ion exchange, and diffusion into pores were demonstrated using the analytical techniques before and after Pb(II) adsorption. These findings demonstrate that ZSM-5 synthesized from bentonite clay exhibits an excellent adsorption capacity for Pb(II), resulting in promising applications for treating drinking water or aqueous industrial waste containing Pb(II) ions.

Kinetic studies of the removal of methylene blue from aqueous solution by biochar derived from jackfruit peel.

Kinetic studies play an instrumental role in determining the most appropriate reaction rate model for industrial-scale applications. This study focuses on the kinetics of methylene blue (MB) adsorption from aqueous solutions by biochar derived from jackfruit peel. Various kinetic models, including pseudo-first-order (PFO), pseudo-second-order (PSO), intra-diffusion, and Elovich models, were applied to study MB adsorption kinetics of jackfruit peel biochar. The experiments were performed with two initial concentrations of MB (24.23 mg/L and 41.42 mg/L) over a span of 240 min. Our findings emphasized that the Elovich model provided the best fit of the experimental data for MB adsorption. When compared to other materials, biochar from jackfruit peel emerges as an eco-friendly adsorbent for dye decolorization, with potential applications in the treatment of environmental pollution.

Detailed Investigation of Factors Affecting the Synthesis of SiO2@Au for the Enhancement of Raman Spectroscopy.

The reaction time, temperature, ratio of precursors, and concentration of sodium citrate are known as the main factors that affect the direct synthesis process of SiO2@Au based on the chemical reaction of HAuCl4 and sodium citrate. Hence, we investigated, in detail, and observed that these factors played a crucial role in determining the shape and size of synthesized nanoparticles. The significant enhancement of the SERS signal corresponding to the fabrication conditions is an existing challenge. Our study results show that the optimal reaction conditions for the fabrication of SiO2@Au are a 1:21 ratio of HAuCl4 to sodium citrate, with an initial concentration of sodium citrate of 4.2 mM, and a reaction time lasting longer than 6 h at a temperature of 80 °C. Under optimal conditions, our synthesis process result is SiO2@Au nanoparticles with a diameter of approximately 350 nm. In particular, the considerable enhancement of Raman intensities of SiO2@Au compared to SiO2 particles was examined.