Facile Fabrication of SERS Substrates by the Electrodeposition Method to Detect Pesticides with High Enhancement Effect and Long-Term Stability.

In this study, surface-enhanced Raman scattering substrates were investigated by the electrodeposition method to detect low concentrations of pesticides via the electrodeposition method with different agents from silver and gold precursors on APTES-modified ITO glass. A dual-potential method supplied three electrodes and was performed with a nucleation potential of 0.7 V for 2 s and a growth potential of -0.2 V for 500 s. The Ag film produced by the electrodeposition approach has great surface uniformity and good SERS signal amplification for the thiram insecticide at low concentrations. Interestingly, the ITO/APTES/Ag substrate extensively increased the sensitivity than the other investigated ones, thanks to the adequate assistance of amino groups of APTES in the denser and hierarchical deposition of Ag NPs. These observations were additionally elucidated via finite-difference time-domain (FDTD) calculation. For thiram, the detection was set at 10-8 M with an enhancement factor of up to 3.6 × 107 times. Comparing the SERS spectra of thiram at concentrations of 10-3, 10-4, and 10-5 M with a relative standard deviation (RSD) of less than 7.0% demonstrates excellent reproducibility of the ITO/APTES/Ag substrate. In addition, the special selectivity of the ITO/APTES/Ag substrate for thiram demonstrates that these nanostructures can identify pesticides with extreme sensitivity.

Rapid and sensitive detection of Rhodamine B in food using the plasmonic silver nanocube-based sensor as SERS active substrate.

The use of dye in food is harmful to human health and is prohibited nowadays. However, it is still used because of the benefits, such as cheap prices and abundant resources. Rhodamine B is usually used as the colorant in food such as chili powder, chili oil, etc. It is colorless at very low concentration 10-7 M. The sensitive detection of RhB at ultra-low concentration help to prevent some risk for human. Surface-enhanced Raman scattering (SERS) is a great technique to detect the analytes at ultra-low concentration and provide the molecule's information as a fingerprint. In this study, silver nano-cube was facilely synthesized by reducing Ag+ in ethylene glycol and upgraded to thin-film as a SERS active substrate. RhB was detected at 10-10 M by a silver nano-cube sensor. The dynamic linear regression between the Raman intensity and RhB concentration over seven orders of magnitude (from 10-4 to 10-10 M) was excellent with high reliability (R2 = 0.99). Moreover, the substrate can be used after storing in a dark area for 60 days. This proposed nano-cube silver could serve as a potential substrate for detecting RhB in food at very low concentration.