Comparison of active and passive methods for atmospheric particulate matter collection: From case study to a useful biomonitoring tool.

In this study we conducted air pollution monitoring using three different methods: active monitoring with the use of high volume aerosol sampler and biomonitoring with the use of lichens and spider webs. All of these monitoring tools were exposed to air pollution in Legnica city, a region of Cu-smelting in the SW Poland, which is well known for exceeding the environmental guidelines. Quantitative analysis was carried out for the particles collected by the three selected methods and concentrations of seven selected elements (Zn, Pb, Cu, Cd, Ni, As, Fe) were obtained. Concentrations found in lichens and in spider webs were directly compared and indicated significant differences between them, with higher amounts noted for spider webs. Then, in order to recognize the main pollution sources the principal component analysis was conducted and obtained results were compared. It resulted that spider webs and aerosol sampler, despite different mechanisms of accumulation, show similar sources of pollution - in this case - copper smelter. Additionally, the HYSPLIT trajectories and the correlations between metals in the aerosol samples also confirmed that this is the most probable source of pollution. This study can be considered innovative as these three air pollution monitoring methods were compared, which has never been conducted before, and their comparison gave satisfying results.

The Comprehensive Health Risk Assessment of Polish Smelters with Ecotoxicological Studies.

Air pollution connected to smelter activity can significantly deteriorate the quality of soil due to the precipitation of rain or simple deposition of the air particulates into the ground. Hence, in this study, we focused on the analysis of the soil which can inform us about the general state of the environment in the area and the possible health hazard for humans. If the top layer of the soil is in bad condition, it can indicate that air pollution in the area is also not in good condition, and the lives of the inhabitants of these areas can be at serious risk. To comprehensively identify the level of contamination in the soils from the areas of Polish smelters, studies of the concentration of potentially toxic elements (PTEs) in the soil were conducted. On the basis of the obtained results, health risk assessment was performed to verify the possible influence on human health. The results showed that the non-carcinogenic risk existed only for Olawa, while the possibility of the carcinogenic risk occurred in all of the studied places. The outcome is very disturbing and certain steps must be undertaken in order to protect the lives of the inhabitants. Additionally, in order to assess the suitability of soils for the cultivation of edible plants, phytotoxicity tests were conducted. The obtained results revealed that in all the studied areas, a visible inhibition of roots and shoots can be observed. The conducted study indicated the most polluted regions and the possible health hazard, and it can provide the general information about the impact of smelters on the environment.

The multi-isotope biogeochemistry (S, C, N and Pb) of Hypogymnia physodes lichens: air quality approach in the Swietokrzyski National Park, Poland.

The isotope biogeochemistry of bioindicators has widely demonstrated its added value in environmental issues by allowing to precisely identify sources of contamination. Most of the studies are based on studying one or two isotope systematics. Here, we are presenting an innovative multi-proxy approach that combines chemistry with both stable (C, S, N) and radiogenic (Pb) isotope systematics. Using Hypogymnia physodes bioindicators, we evaluated air quality in the complex environment of the Swietokrzyski National Park (SNP, Poland) with the ultimate objective of isotopically identifying the sources responsible for the observed contamination. Combining the isotope systematics showed that home heating is a major source of contamination in winter, whereas the contribution of road traffic increases during the summer. Pb isotope ratios identified industrial activities as the major source of this metal in the atmosphere.