ABSTRACT
Biomass is a valuable renewable energy adapted as an alternative to traditional fossil fuels. Apart from fuels, biomass is synthesized into highly valuable products that are used in various forms including biofuels, biochemical, bioproducts, packing material, and find practice in pharmaceutical, cosmetics, and nutraceuticals industries. Particularly, microalgae a third-generation feedstock known for its rich carbon content possesses protein lipids and carbohydrates produces a variety of green products such as bioethanol, biohydrogen, biodiesel, and biomethane, and also fixes carbon emission to a certain amount in the atmosphere. However, microalgae conversion in the presence of a catalyst such as a metal-organic framework (MOF) yields high-quality valuable products. A MOF is a porous crystalline material where the structure and pore size can be controlled making it suitable for catalytic reactions and appropriate conversion paths. This review briefly explains the prevailing status of microalgae as a sustainable biomass and features its components for microalgae biorefinery into valuable products and its application in the food industry. MOF properties, characteristics and various MOF-based conversion technologies for biomass conversion with its application are elaborated. In addition, usage of value products produced from microalgae biorefinery in the food industry and its importance is elucidated. In addition, the challenges in integrating biorefinery processes with food industry operations and their solutions are also presented. © 2024 Society of Chemical Industry.
ABSTRACT
The permanent problem of formation of algal blooms in water polluted with nitrogen and phosphorus is one of the formidable environmental problems. Biochar has the potential to solve the issues related to eutrophication due to its special structure and ability to absorb the nutrients. Biochar's exceptional nutrient absorption capacity allows it to absorb excess nutrients, causing the algae to use fewer nutrients. This review deals with effective performance of biochar in reducing the effects caused by algal blooms and improving the environmental conditions. Besides, an analysis of the issues involved addresses the origins and consequences of nitrogen and phosphorus pollution, and the formation of algal blooms is also reviewed. It then delves deeply into biochar, explaining its properties, production methods, and their uses in environmental contexts. The review emphasizes that biochar can be effective in dealing with many challenges associated with environments affected by algal blooms, specifically focusing on the positive effects of biochar and algae to examine their roles in controlling algae growth. Finally, the review emphasizes new achievements and innovative ideas to foster sustainable aquatic ecosystems. The discussions emphasize the central role of biochar in managing nutrient-rich waters and algal blooms.
Subject(s)
Biodegradation, Environmental , Charcoal , Eutrophication , Phosphorus , Phosphorus/analysis , Nitrogen , EcosystemABSTRACT
This study introduces an innovative approach using highly efficient nanocomposite materials to effectively remove PFAS from water, demonstrating remarkable adsorption capabilities. The nanocomposite was synthesized by integrating a zirconium-based metal-organic framework (MOF) called UiO-66 with graphene oxide (GO) within a polyvinyl alcohol (PVA) matrix. The resulting PVA@UiO-66/GO material features flower-like UiO-66 MOF crystals embedded in the PVA and GO matrix. Various kinetic models were applied to determine the rate constants and adsorption capacities, with the Langmuir isotherm indicating an adsorption capacity of 9.904 mg/g. Thermodynamic analysis confirmed the process's spontaneity and exothermic nature. The UiO-66-NH2/GO/PVA composite also demonstrated high reusability, maintaining substantial PFOA removal efficiency across multiple cycles, with optimal reduction occurring at approximately pH 5. Overall, the PVA@UiO-66/GO composites offer an effective, sustainable, and environmentally friendly solution for PFAS removal in water purification.
ABSTRACT
Determining hazardous substances in the environment is vital to maintaining the safety and health of all components of society, including the ecosystem and humans. Recently, protein-based nanobiosensors have emerged as effective tools for monitoring potentially hazardous substances in situ. Nanobiosensor detection mode is a combination of particular plasmonic nanomaterials (e.g., nanoparticles, nanotubes, quantum dots, etc.), and specific bioreceptors (e.g., aptamers, antibodies, DNA, etc.), which has the benefits of high selectivity, sensitivity, and compatibility with biological systems. The role of these nanobiosensors in identifying dangerous substances (e.g., heavy metals, organic pollutants, pathogens, toxins, etc.) is discussed along with different detection mechanisms and various transduction methods (e.g., electrical, optical, mechanical, electrochemical, etc.). In addition, topics discussed include the design and construction of these sensors, the selection of proteins, the integration of nanoparticles, and their development processes. A discussion of the challenges and prospects of this technology is also included. As a result, protein nanobiosensors are introduced as a powerful tool for monitoring and improving environmental quality and community safety.
Subject(s)
Biosensing Techniques , Environmental Monitoring , Hazardous Substances , Hazardous Substances/analysis , Environmental Monitoring/methods , Proteins/analysis , Nanostructures , Nanotechnology , Nanoparticles/chemistryABSTRACT
This study reported the synthesis and assessment of zinc oxide/iron oxide (ZnO/Fe2O3) nanocomposite as photocatalysts for the degradation of a mixture of methylene red and methylene blue dyes. X-ray diffraction analysis confirms that the crystallite of zinc oxide (ZnO) has a hexagonal wurtzite phase and iron oxide (Fe2O3) has a rhombohedral phase. Fourier Transform Infra-Red spectrum confirms the presence of Zn-O vibration stretching at 428, 480 and 543 cm-1 stretching confirming Fe-O bond formation. Scanning Electron Microscope images exhibited a diverse size and shape of the nanocomposites. The ZnO-90%/Fe2O3-10% and ZnO-10%/Fe2O3-90% nanocomposites reveal good photocatalytic activity with reaction rate constants of 1.5 × 10-2 and 0.66 × 10-2; and 1.3 × 10-2 and 0.60 × 10-2 for methylene blue and methyl red dye respectively. The results revealed that the synthesized ZnO/Fe2O3 nanocomposite is the best catalyst for dye degradation and can be used for industrial applications in future.
Subject(s)
Coloring Agents , Ferric Compounds , Methylene Blue , Nanocomposites , Zinc Oxide , Zinc Oxide/chemistry , Nanocomposites/chemistry , Methylene Blue/chemistry , Ferric Compounds/chemistry , Catalysis , Coloring Agents/chemistry , X-Ray Diffraction , Microscopy, Electron, Scanning , Azo Compounds/chemistry , Water Pollutants, Chemical/chemistry , Photolysis , Spectroscopy, Fourier Transform InfraredABSTRACT
All pests can be eliminated with the help of pesticides, which can be either natural or synthetic. Because of the excessive use of pesticides, it is harmful to both ecology and people's health. Pesticides are categorised according to several criteria: their chemical composition, method of action, effects, timing of use, source of manufacture, and formulations. Many aquatic animals, birds, and critters live in danger owing to hazardous pesticides. Metaldehyde is available in various forms and causes significant impact even when small amounts are ingested. Metaldehyde can harm wildlife, including dogs, cats, and birds. This review discusses pesticides, their types and potential environmental issues, and metaldehyde's long-term effects. In addition, it examines ways to eliminate metaldehyde from the aquatic ecosystem before concluding by anticipating how pesticides may affect society. The metal-organic framework and other biosorbents have been appropriately synthesized and subsequently represent the amazing removal of pesticides from effluent as an enhanced adsorbent, such as magnetic nano adsorbents. A revision of the risk assessment for metaldehyde residuals in aqueous sources is also attempted.
Subject(s)
Acetaldehyde , Pesticides , Water Pollutants, Chemical , Acetaldehyde/analogs & derivatives , Animals , Risk Assessment , Humans , Adsorption , Metal-Organic Frameworks/chemistryABSTRACT
Amoxicillin, a member of the penicillin family, is primarily utilized for the treatment of various bacterial infections affecting ears, nose, throat, urinary tract, and skin. Given its widespread application in medicine, agriculture, environment, and food industry, the precise and sensitive detection of amoxicillin is important. This study introduces a novel approach to developing a sensitive and selective fluorescent aptasensor relying on fluorescence resonance energy transfer (FRET) for the specific detection of amoxicillin. The carboxyfluorescein-labeled aptamer serves as a energy donor, while MXene functions as an energy acceptor, and acting as a quencher. To achieve optimal detection efficiency, a dual optimization strategy utilizing RSM-CCD and ANN-GA was used to fine-tune experimental conditions. The fluorescence measurements revealed an expansive linear range extending from 100 to 2400 ng mL-1, accompanied by an exceptionally low detection limit of 1.53 ng mL-1. Additionally, it shows an excellent selectivity towards amoxicillin over other antibiotics commonly found in water matrices. The aptasensor demonstrates good stability and reproducibility; effectiveness of the aptasensor was validated by testing in real water samples. This remarkable sensitivity and broad dynamic range affirm the efficacy aptasensor in accurately detecting varying concentrations of amoxicillin in wastewater bodies.
Subject(s)
Amoxicillin , Biosensing Techniques , Amoxicillin/analysis , Amoxicillin/chemistry , Fluorescence Resonance Energy Transfer/methods , Aptamers, Nucleotide/chemistry , Fluorescence , Water Pollutants, Chemical/analysis , Water/chemistryABSTRACT
Indole-3-acetic acid (IAA) derived from Actinobacteria fermentations on agro-wastes constitutes a safer and low-cost alternative to synthetic IAA. This study aims to select a high IAA-producing Streptomyces-like strain isolated from Lake Oubeira sediments (El Kala, Algeria) for further investigations (i.e., 16S rRNA gene barcoding and process optimization). Subsequently, artificial intelligence-based approaches were employed to maximize IAA bioproduction on spent coffee grounds as high-value-added feedstock. The specificity was the novel application of the Limited-Memory Broyden-Fletcher-Goldfarb-Shanno Box (L-BFGS-B) optimization algorithm. The new strain AW08 was a significant producer of IAA (26.116 ± 0.61 µg/mL) and was identified as Streptomyces rutgersensis by 16S rRNA gene barcoding and phylogenetic inquiry. The empirical data involved the inoculation of AW08 in various cultural conditions according to a four-factor Box Behnken Design matrix (BBD) of Response surface methodology (RSM). The input parameters and regression equation extracted from the RSM-BBD were the basis for implementing and training the L-BFGS-B algorithm. Upon training the model, the optimal conditions suggested by the BBD and L-BFGS-B algorithm were, respectively, L-Trp (X1) = 0.58 %; 0.57 %; T° (X2) = 26.37 °C; 28.19 °C; pH (X3) = 7.75; 8.59; and carbon source (X4) = 30 %; 33.29 %, with the predicted response IAA (Y) = 152.8; 169.18 µg/mL). Our findings emphasize the potential of the multifunctional S. rutgersensis AW08, isolated and reported for the first time in Algeria, as a robust producer of IAA. Validation investigations using the bioprocess parameters provided by the L-BFGS-B and the BBD-RSM models demonstrate the effectiveness of AI-driven optimization in maximizing IAA output by 5.43-fold and 4.2-fold, respectively. This study constitutes the first paper reporting a novel interdisciplinary approach and providing insights into biotechnological advancements. These results support for the first time a reasonable approach for valorizing spent coffee grounds as feedstock for sustainable and economic IAA production from S. rutgersensis AW08.
Subject(s)
Artificial Intelligence , Indoleacetic Acids , RNA, Ribosomal, 16S , Streptomyces , Streptomyces/genetics , Streptomyces/metabolism , Indoleacetic Acids/metabolism , RNA, Ribosomal, 16S/genetics , Algeria , PhylogenyABSTRACT
This study aims to improve the quality of fuel with high calorific value namely Sfuel - a commercial high-quality refuse-derived fuel (RDF) from hazardous waste via modifying the process design and operating parameters of thermal conversion process. The study analyses key parameters of RDF quality, such as calorific value and heavy metal content, before and after process modifications based on the combination of experimental and simulation using Aspen Plus. In this study, the temperature and pressure of the simulation system are varied from 100 to 700 °C and from 1 to 5 bar, respectively. Findings indicate that there are a total of eleven heavy metals and 179 volatile compounds in the "Sfuels". The quality of the targeted product is greatly improved by the metal evaporation at high temperatures and pressures. However, the calorific value of RDF significantly decreases at 700 °C due to a large amount of the carbon content being evaporated. Although the carbon content at high temperatures is significantly lost, the heat from the vapour stream reactor outlet, which is reused to preheat the nitrogen gas stream supplied to the system, reduces energy consumption while improving the thermal conversion efficiency of the system. Besides, low pressure along with high temperature are not the optimal conditions for quality Sfuels improvement by thermal conversion. Results also indicate that electric heating is more economically efficient than natural gas heating.
Subject(s)
Metals, Heavy , Metals, Heavy/analysis , Refuse Disposal/methods , Computer Simulation , Hazardous Waste/analysis , Hot TemperatureABSTRACT
Arsenic is the hazardous species and still is the global challenge in water treatment. Apatite soil is highly rich in arsenic species, and its mining presents various environmental issues. In this study, novel magnetic microbeads as adsorbent were developed for the elimination of hazardous arsenic ions from apatite soil's aqueous leachate before discharging into environment. The microbeads were fabricated with metformin polyether sulfone after being doped with zero-valent iron (Met-PES/ZVI). The microbeads were characterized using various techniques, including FTIR, XRD, SEM-EDX, VSM, and zeta potential analysis. The developed adsorbent demonstrated a significant elimination in arsenic in aqueous leachate, achieving 82.39% removal after 30 min of contact time, which further increased to 90% after 180 min of shaking. The kinetic analysis revealed that the pseudo-second-order model best represented the adsorption process. The intra-particle diffusion model indicated that the adsorption occurred in two steps. The Langmuir model (R2 = 0.991), with a maximum adsorption capacity of 188.679 mg g-1, was discovered to be the best fit for the experimental data as compared Freundlich model (R2 = 0.981). According to the thermodynamic outcome (ΔG < -20 kJ/mol), the adsorption process was spontaneous and involved physisorption. These findings demonstrate the potential of magnetic Met-PES/ZVI microbeads as an efficient adsorbent for the removal of arsenic from apatite soil aqueous leachate.
Subject(s)
Arsenic , Water Pollutants, Chemical , Water Purification , Arsenic/analysis , Soil , Kinetics , Microspheres , Thermodynamics , Adsorption , Magnetic Phenomena , Water Pollutants, Chemical/analysis , Hydrogen-Ion Concentration , Water Purification/methodsABSTRACT
The emergence of algal toxins in water ecosystems poses a significant ecological and human health concern. These toxins, produced by various algal species, can lead to harmful algal blooms, and have far-reaching consequences on biodiversity, food chains, and water quality. This review explores the types and sources of algal toxins, their ecological impacts, and the associated human health risks. Additionally, the review delves into the potential of bioremediation strategies to mitigate the effects of algal toxins. It discusses the role of microorganisms, enzymes, and algal-bacterial interactions in toxin removal, along with engineering approaches such as advanced oxidation processes and adsorbent utilization. Microbes and enzymes have been studied for their environmentally friendly and biocompatible properties, which make them useful for controlling or removing harmful algae and their toxins. The challenges and limitations of bioremediation are examined, along with case studies highlighting successful toxin control efforts. Finally, the review outlines future prospects, emerging technologies, and the need for continued research to effectively address the complex issue of algal toxins and their ecological significance.
Subject(s)
Ecosystem , Harmful Algal Bloom , Humans , Biodegradation, Environmental , Water QualityABSTRACT
Composites of magnetic biochar derived from spent coffee grounds were prepared using MoS2 decorated by plasmonic silver nanoparticles (MoS2-Ag), which were used for the bioremediation Cr6+ ions. The composites were characterized by electron microscopy, X-ray diffraction, Raman, and UV-VIS spectroscopy. The bioremediation of Cr6+ ions was enhanced almost two times compared to microalgae, Spirulina maxima. Such an increased activity is attributed to heterojunction formation of Biochar@MoS2-Ag composite due to the synergetic effects of surface plasmon resonance of AgNPs inducing amplified local electric field, thus simultaneously increasing the absorption of MoS2 under visible or near-infrared light. The combination of Biochar@MoS2-Ag and Spirulina maxima powder was effective for the separation (microalga-based absorption and accumulation of Cr6+ ions) of photo-induced carriers (composite-assisted to breakdown Cr6+ ions). This study offers efficient eco-friendly treatment of Cr6+ ions by reporting the first enhanced bioremediation of Cr(VI) ions by microalgae using MoS2-Ag-modified biochar obtained from consumed coffee grounds.
Subject(s)
Metal Nanoparticles , Microalgae , Molybdenum , Coffee , Biodegradation, Environmental , Silver/chemistry , Magnetic Phenomena , IonsABSTRACT
Phthalate esters (PAEs) are known as esters of phthalic acid, which are commonly used as plasticizers in the plastic industry. Due to the lack of chemical bonding with the polymer matrix, these compounds are easily separated from plastic products and enter the environment. To investigate the growth of concentration of PAEs like DBP (Dibutyl phthalate), DEP (Diethyl phthalate), DMP (Dimethyl phthalate), DIBP (Diisobutyl phthalate), and TPMBP (tris(2-methylbutyl) phosphate) in different water sources, a study from January 01, 1976, to April 30, 2021, was implemented via a global systematic review plus meta-analysis in which, 109 articles comprising 4061 samples, 4 water types, and 27 countries were included. Between various types of water sources, river water and lake water were the most contaminated resources with PAEs. Among all studies of PAEs, DBP and DEP with the values >15,573 mg L-1 have the highest average concentration and TPMBP with the value 0.002885 mg L-1 has the lowest average concentration in water sources. The most contaminated water sources with PAEs were in Nigeria and the least contaminated was in China. Besides, Monte-Carlo simulation indicated that for DMP and DEP minimum values that are lower than the acceptable limit are generated. However, most of the population (>75 %) is at risk for both adults and child cases. For DIBP and DBP the situation is much worse, the simulations not providing at least one case where the R index is lower than the acceptable limit of 1E-06.
ABSTRACT
Global warming is the result of traditional fuel use and manufacturing, which release significant volumes of CO2 and other greenhouse gases from factories. Moreover, rising energy consumption, anticipated limitations of fossil fuels in the near future, and increased interest in renewable energies among scientists, currently increase research in biofuels. In contrast to biomass from urban waste materials or the land, algae have the potential to be a commercially successful aquatic energy crop, offering a greater energy potential. Here we discuss the importance of Anaerobic Digestion (AD) for enhanced biogas yield, characterization, and comparisons between algae pretreatment methods namely, mechanical, thermal, microwave irradiation, and enzymatic and catalytic methods. The importance of anaerobic digestion enhances biogas yield, characterization, and comparisons between mechanical, thermal, microwave irradiation, and enzymatic and catalytic treatment. Additionally, operational aspects such as algal species, temperature, C/N ratio, retention period, and particle size impact biofuel yield. The highest algal biogas yield reported was 740 mL/gVS, subtracted from Taihu de-oiled algae applying thermos-chemical pretreatment under conditions of temperature, time, and catalyst concentration of 70 °C, 3 h, and 6%, respectively. Another high yield of algal-based biogas was obtained from Laminaria sp. with mechanical pretreatment under temperature, time, and VS concentration of 38 ± 1 °C, 15 min, and 2.5% respectively, with a maximum yield of 615 ± 7 mL/g VS. Although biofuels derived from algae species are only partially commercialized, the feedstock for biogas might soon be commercially grown. Algae and other plant species that could be cultivated on marginal lands as affordable energy crops with the potential to contribute to the production of biogas are promising and are already being worked on.
ABSTRACT
Heterogeneous advanced oxidation process has been widely studied as an effective method for removing organic pollutants in wastewater, but the development of efficient catalysts is still challenging. This review summaries the present status of researches on biochar/layered double hydroxides composites (BLDHCs) as catalysts for treatment of organic wastewater. The synthesis methods of layered double hydroxides, the characterizations of BLDHCs, the impacts of process factors influencing catalytic performance, and research advances in various advanced oxidation processes are discussed in this work. The integration of layered double hydroxides and biochar provides synthetic effects for improving pollutant removal. The enhanced pollutant degradation in heterogeneous Fenton, sulfate radical-based, sono-assisted, and photo-assisted processes using BLDHCs have been verified. Pollutant degradation in heterogeneous advanced oxidation processes using BLDHCs is influenced by process factors such as catalyst dosage, oxidant addition, solution pH, reaction time, temperature, and co-existing substances. BLDHCs are promising catalysts due to the unique features including easy preparation, distinct structure, adjustable metal ions, and high stability. Currently, catalytic degradation of organic pollutants using BLDHCs is still in its infancy. More researches should be conducted on the controllable synthesis of BLDHCs, the in-depth understanding of catalytic mechanism, the improvement of catalytic performance, and large-scale application of treating real wastewater.
Subject(s)
Environmental Pollutants , Water Pollutants, Chemical , Wastewater , Water Pollutants, Chemical/analysis , Hydroxides , Oxidation-ReductionABSTRACT
Pharmaceutical compounds are among the environmental contaminants that cause pollution of water resources and thereby threaten ecosystem services and the environmental health of the past decades. Antibiotics are categorized as emerging pollutants due to their persistence in the environment that are difficult to remove by conventional wastewater treatment. Ceftriaxone is one of the multiple antibiotics whose removal from wastewater has not been fully investigated. In this study, TiO2/MgO (5% MgO) the efficiency of photocatalyst nanoparticles in removing ceftriaxone was analyzed by XRD, FTIR, UV-Vis, BET, EDS, and FESEM. The results were compared with UVC, TiO2/UVC, and H2O2/UVC photolysis processes to evaluate the effectiveness of the selected methods. Based on these results, the highest removal efficiency of ceftriaxone from synthetic wastewater was 93.7% at the concentration of 400 mg/L using TiO2/MgO nano photocatalyst with an HRT of 120 min. This study confirmed that TiO2/MgO photocatalyst nanoparticles efficiently removed ceftriaxone from wastewater. Future studies should focus on the optimization of reactor conditions and improvements of the reactor design to obtain higher removal of ceftriaxone from wastewater.
Subject(s)
Wastewater , Water Pollutants, Chemical , Ultraviolet Rays , Magnesium Oxide , Ceftriaxone , Hydrogen Peroxide , Ecosystem , Titanium , Anti-Bacterial Agents , CatalysisABSTRACT
This review provides an overview of recent progress in the development of layered covalent organic frameworks (LCOFs) for the adsorption and degradation of pollutants in water and wastewater treatment. LCOFs have unique properties such as high surface area, porosity, and tunability, which make them attractive adsorbents and catalysts for water and wastewater treatment. The review covers the different synthesis methods for LCOFs, including self-assembly, co-crystallization, template-directed synthesis, covalent organic polymerization (COP), and solvothermal synthesis. It also covers the structural and chemical characteristics of LCOFs, their adsorption and degradation capacity for different pollutants, and their comparison with other adsorbents and catalysts. Additionally, it discussed the mechanism of adsorption and degradation by LCOFs, the potential applications of LCOFs in water and wastewater treatment, case studies and pilot-scale experiments, challenges, and limitations of using LCOFs, and future research directions. The current state of research on LCOFs for water and wastewater treatment is promising, however, more research is needed to improve their performance and practicality. The review highlights that LCOFs have the potential to significantly improve the efficiency and effectiveness of current water and wastewater treatment methods and can also have implications for policy and practice.
Subject(s)
Environmental Pollutants , Metal-Organic Frameworks , Water Pollutants, Chemical , Water Purification , Water , Wastewater , Water Pollutants, Chemical/analysis , Water Purification/methods , AdsorptionABSTRACT
An investigation was conducted into the dynamic behavior of two polyaromatic hydrocarbon (PAH) semi-volatile organic compound (SVOC) naphthalene (NAP) and benzo [ghi]perylene (BghiP) in air and on various surfaces including glass, dust, and polyurethane foam (PUF) to understand their interaction with different media. A confocal fluorescence microscope and an infrared microscope were employed to detect and monitor the concentration-, time-, and temperature-dependent changes of the aromatic NAP and BghiP species on the surfaces. Infrared two-dimensional mapping of the vibrational characteristic peaks was used to track the two PAHs on the surfaces. Gas chromatography-mass spectrometry (GC-MS) was employed to measure the gaseous concentrations. The sorption of NAP and BghiP on the surfaces was estimated using Arizona desert sand fine (ISO 12103-1 A2) dust and organic contaminant household (SRM 2585) dust. The surface-to-air partition coefficients of NAP and BghiP were estimated on the different surfaces of glass, dust, and PUF. Molecular dynamic simulations were performed on dust surfaces based on the Hatcher model to understand the behavior of NAP and BghiP on dust surfaces. The Weschler-Nazaroff model was introduced to predictPAH film accumulation on the surfaces, providing a better understanding of PAH interaction with different environmental media. These findings could contribute to developing effective strategies to mitigate the adverse impact of PAHs on the environment and human health.
Subject(s)
Dust , Polycyclic Aromatic Hydrocarbons , Humans , Dust/analysis , Polyurethanes/analysis , Polycyclic Aromatic Hydrocarbons/analysis , Environmental MonitoringABSTRACT
A unique nanomaterial platform was developed for trace detection and efficient degradation of triclosan (TCS). A facile spectroscopic technique for surface-enhanced Raman scattering (SERS)-supported identification and ultraviolet (UV) degradation of TCS using a SERS template based on silver spherical nanoparticle (AgNP)-modified ZnO multipods (ZnO@Ag) is reported. Core-shell composite materials of ZnO multipods with a dimension of around 3 µm and AgNPs with an average diameter of â¼27 nm was designed not only as a substrate for TCS degradation up to â¼92% upon UV irradiation (λ = 365 mm, 300 µW/cm2) but also as a monitoring platform sensitive to TCS at a detection limit as low as 10-9 M (≈0.3 ppb). Herein, the first investigation into ZnO@Ag bimetallic composites is established for both the SERS-based detection and UV-assisted degradation of environmental TCS pollutants. The calibration curve was estimated to be linear at R2 > 0.97. The validated technology was successfully used to determine the antibacterial agent and TCS in distilled or river water. The advantages of the ZnO@Ag template are highlighted over conventional detection and excellent degradation.
Subject(s)
Environmental Pollutants , Metal Nanoparticles , Nanocomposites , Triclosan , Zinc Oxide , Metal Nanoparticles/chemistry , Zinc Oxide/chemistry , Silver/chemistry , Nanocomposites/chemistryABSTRACT
Ultrasound as a clean, efficient, and cheap technique gains special attention in wastewater treatment. Ultrasound alone or coupled with hybrid processes have been widely studied for the treatment of pollutants in wastewater. Thus, it is essential to conduct a review about the research development and trends on this emerging technique. This work presents a bibliometric analysis of the topic associated with multiple tools such as Bibliometrix package, CiteSpace, and VOSviewer. The literature sources from 2000 to 2021 were collected from Web of Science database, and the data of 1781 documents were selected for bibliometric analysis in respect to publication trends, subject categories, journals, authors, institutions, as well as countries. Detailed analysis of keywords in respect to co-occurrence network, keyword clusters, and citation bursts was conducted to reveal the research hotspot and future directions. The development of the topic can be divided into three stages, and the rapid development begins from 2014. The leading subject category is Chemistry Multidisciplinary, followed by Environmental Sciences, Engineering Chemical, Engineering Environmental, Chemistry Physical, and Acoustics, and there exists difference in the publications of different categories. Ultrasonics Sonochemistry is the most productive journal (14.75 %). China is the leading country (30.26 %), followed by Iran (15.67 %) and India (12.35 %). The top 3 authors are Parag Gogate, Oualid Hamdaoui, and Masoud Salavati-Niasari. There exists close cooperation between countries and researchers. Analysis of highly cited papers and keywords gives a better understanding of the topic. Ultrasound can be employed to assist various processes such as Fenton-like process, electrochemical process, and photocatalysis for degradation of emerging organic pollutants for wastewater treatment. Research topics in this field evolve from typical studies on ultrasonic assisted degradation to latest studies on hybrid processes including photocatalysis for pollutants degradation. Additionally, ultrasound-assisted synthesis of nanocomposite photocatalysts receives increasing attention. The potential research directions include sonochemistry in pollutant removal, hydrodynamic cavitation, ultrasound-assisted Fenton or persulfate processes, electrochemical oxidation, and photocatalytic process.