Effect of gamma irradiation on the physical properties of MoS2 monolayer.

Two-dimensional transition metal dichalcogenides (2D-TMDs) have been proposed as novel optoelectronic materials for space applications due to their relatively light weight. MoS2 has been shown to have excellent semiconducting and photonic properties. Although the strong interaction of ionizing gamma radiation with bulk materials has been demonstrated, understanding its effect on atomically thin materials has scarcely been investigated. Here, we report the effect of gamma irradiation on the structural and electronic properties of a monolayer of MoS2. We perform Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) studies of MoS2, before and after gamma ray irradiation with varying doses and density functional theory (DFT) calculations. The Raman spectra and XPS results demonstrate that point defects dominate after the gamma irradiation of MoS2. DFT calculations elucidate the electronic properties of MoS2 before and after irradiation. Our work makes several contributions to the field of 2D materials research. First, our study of the electronic density of states and the electronic properties of a MoS2 monolayer irradiated by gamma rays sheds light on the properties of a MoS2 monolayer under gamma irradiation. Second, our study confirms that point defects are formed as a result of gamma irradiation. And third, our DFT calculations qualitatively suggest that the conductivity of the MoS2 monolayer may increase after gamma irradiation due to the creation of additional defect states.

Switching between topological edge states in plasmonic systems using phase-change materials.

We introduce non-Hermitian plasmonic waveguide-cavity structures based on the Aubry-Andre-Harper model to realize switching between right and left topological edge states (TESs) using the phase-change material Ge2Sb2Te5 (GST). We show that switching between the crystalline and amorphous phases of GST leads to a shift of the dispersion relation of the optimized structure so that a right TES for the crystalline phase, and a left TES for the amorphous phase occur at the same frequency. Thus, we realize switching between right and left TESs at that frequency by switching between the crystalline and amorphous phases of GST. Our results could be potentially important for developing compact reconfigurable topological photonic devices.

Hyperspectral dark field optical microscopy for orientational imaging of a single plasmonic nanocube using a physics-based learning method.

Rotational dynamics at the molecular level could provide additional data regarding protein diffusion and cytoskeleton formation at the cellular level. Due to the isotropic emission pattern of fluorescence molecules, it is challenging to extract rotational information from them during imaging. Metal nanoparticles show a polarization-dependent response and could be used for sensing rotational motion. Nanoparticles as an orientation sensing probe offer bio-compatibility and robustness against photo-blinking and photo-bleaching compared to conventional fluorescent molecules. Previously, asymmetric geometrical structures such as nanorods have been used for orientational imaging. Here, we show orientational imaging of symmetric geometrical structures such as 100 nm isolated silver nanocubes by coupling a hyperspectral detector and a focused ion beam (FIB)-fabricated correlating substrate. More than 100 nanocubes are analyzed to confirm spectral shifts in the scattering spectra due to variations in the orientation of the nanocubes with respect to the incoming light. Results are further validated using finite-difference time-domain simulations. Our observations suggest a novel strategy for high-throughput orientation imaging of nanoparticles.

Tunable dual plasmon-induced transparency based on a monolayer graphene metamaterial and its terahertz sensing performance.

In this paper, tunable dual plasmon-induced transparency (PIT) is achieved by using a monolayer graphene metamaterial in the terahertz region, which consists of two graphene strips of different sizes and a graphene ring. As the dual PIT effect is induced by the destructive interference between the two quasi-dark modes and the bright mode, we propose a four-level plasmonic system based on the linearly coupled Lorentzian oscillators to explain the mechanism behind the dual PIT. It is proved that the theoretical results agree well with the simulation results. Most importantly, the sensing properties of the designed device have been investigated in detail and we found that it can exhibit high sensitivities and figure of merit (FOM). Furthermore, the dual PIT windows can be effectively modulated by changing the Fermi energy of the graphene layer and the angle of incidence. Thus, the proposed graphene-based metamaterial can hold wide applications for switches, modulators, and multi-band refractive index sensors in the terahertz region.

Non-PT-symmetric two-layer cylindrical waveguide for exceptional-point-enhanced optical devices.

We investigate the exceptional points in a two-layer cylindrical waveguide structure consisting of absorbing and non-absorbing dielectrics. We show that, by tuning the core to total radius ratio and the refractive index of the core layer in such a structure, the complex effective indices of two waveguide modes can coalesce so that an exceptional point is formed. We show that the sensitivity of the effective index of the waveguide mode to variations of the refractive index of the material filling the shell layer is enhanced at the exceptional point. In addition, we show that larger sensitivity enhancement is obtained for smaller perturbations. Our results could potentially contribute to the development of a new generation of chip-scale exceptional-point-enhanced optical waveguide devices for modulation, switching, and sensing.

Ultrasensitive Three-Dimensional Orientation Imaging of Single Molecules on Plasmonic Nanohole Arrays Using Second Harmonic Generation.

Recently, fluorescence-based super-resolution techniques such as stimulated emission depletion (STED) and stochastic optical reconstruction microscopy (STORM) have been developed to achieve near molecular-scale resolution. However, such a super-resolution technique for nonlinear label-free microscopy based on second harmonic generation (SHG) is lacking. Since SHG is label-free and does not involve real-energy level transitions, fluorescence-based super-resolution techniques such as STED cannot be applied to improve the resolution. In addition, due to the coherent and non-isotropic emission nature of SHG, single-molecule localization techniques based on isotropic emission of fluorescent molecule such as STORM will not be appropriate. Single molecule SHG microscopy is largely hindered due to the very weak nonlinear optical scattering cross sections of SHG scattering processes. Thus, enhancing SHG using plasmonic nanostructures and nanoantennas has recently gained much attention owing to the potential of various nanoscale geometries to tightly confine electromagnetic fields into small volumes. This confinement provides substantial enhancement of electromagnetic field in nanoscale regions of interest, which can significantly boost the nonlinear signal produced by molecules located in the plasmonic hotspots. However, to date, plasmon-enhanced SHG has been primarily applied for the measurement of bulk properties of the materials/molecules, and single molecule SHG imaging along with its orientation information has not been realized yet. Herein, we achieved simultaneous visualization and three-dimensional (3D) orientation imaging of individual rhodamine 6G (R6G) molecules in the presence of plasmonic silver nanohole arrays. SHG and two-photon fluorescence microscopy experiments together with finite-difference time-domain (FDTD) simulations revealed a ∼106-fold nonlinear enhancement factor at the hot spots on the plasmonic silver nanohole substrate, enabling detection of single molecules using SHG. The position and 3D orientation of R6G molecules were determined using the template matching algorithm by comparing the experimental data with the calculated dipole emission images. These findings could enable SHG-based single molecule detection and orientation imaging of molecules which could lead to a wide range of applications from nanophotonics to super-resolution SHG imaging of biological cells and tissues.

Optimization of photonic nanojets generated by multilayer microcylinders with a genetic algorithm.

We employ a genetic algorithm coupled with Mie theory to optimize the magnetic field intensity profile of photonic nanojets (PNJs) generated by multilayer microcylinders at visible wavelengths in free space. We first optimize five-layer microcylinders to elongate the PNJs. We show that a properly designed five-layer microcylinder structure can generate an ultra-long PNJ with a beam length ~ 107.5 times the illumination wavelength λ0. We then optimize five-layer microcylinders to narrow the waist of PNJs. We show that a PNJ with a full-width at half maximum waist of ~ 0.22λ0 can be obtained outside the surface of the optimized microcylinder. In addition, curved PNJs with subwavelength waist are also obtained. We finally optimize the five-layer structures for refractive index sensing based on the beam length of PNJs. The estimated minimum detectable refractive index variation when using this sensing method is ultra-small. Our results could potentially contribute to the development of a new generation of devices for optical nanoscopy and biophotonics, and greatly promote the practical applications of PNJs.

Graphene-based dual-band independently tunable infrared absorber.

In this paper, we theoretically demonstrate a dual-band independently tunable absorber consisting of a stacked graphene nanodisk and graphene layer with nanohole structure, and a metal reflector spaced by insulator layers. This structure exhibits a dipole resonance mode in graphene nanodisks and a quadrupole resonance mode in the graphene layer with nanoholes, which results in the enhancement of absorption over a wide range of incident angles for both TE and TM polarizations. The peak absorption wavelength is analyzed in detail for different geometrical parameters and the Fermi energy levels of graphene. The results show that both peaks of the absorber can be tuned dynamically and simultaneously by varying the Fermi energy level of graphene nanodisks and graphene layer with nanoholes structure. In addition, one can also independently tune each resonant frequency by only changing the Fermi energy level of one graphene layer. Such a device could be used as a chemical sensor, detector or multi-band absorber.

Switching of the direction of reflectionless light propagation at exceptional points in non-PT-symmetric structures using phase-change materials.

We introduce a non-parity-time-symmetric three-layer structure, consisting of a gain medium layer sandwiched between two phase-change medium layers for switching of the direction of reflectionless light propagation. We show that for this structure unidirectional reflectionlessness in the forward direction can be switched to unidirectional reflectionlessness in the backward direction at the optical communication wavelength by switching the phase-change material Ge2Sb2Te5 (GST) from its amorphous to its crystalline phase. We also show that it is the existence of exceptional points for this structure with GST in both its amorphous and crystalline phases which leads to unidirectional reflectionless propagation in the forward direction for GST in its amorphous phase, and in the backward direction for GST in its crystalline phase. Our results could be potentially important for developing a new generation of compact active free-space optical devices.

Plasmonic nanohole array for enhancing the SERS signal of a single layer of graphene in water.

We numerically design and experimentally test a SERS-active substrate for enhancing the SERS signal of a single layer of graphene (SLG) in water. The SLG is placed on top of an array of silver-covered nanoholes in a polymer and is covered with water. Here we report a large enhancement of up to 2 × 105 in the SERS signal of the SLG on the patterned plasmonic nanostructure for a 532 nm excitation laser wavelength. We provide a detailed study of the light-graphene interactions by investigating the optical absorption in the SLG, the density of optical states at the location of the SLG, and the extraction efficiency of the SERS signal of the SLG. Our numerical calculations of both the excitation field and the emission rate enhancements support the experimental results. We find that the enhancement is due to the increase in the confinement of electromagnetic fields on the location of the SLG that results in enhanced light absorption in the graphene at the excitation wavelength. We also find that water droplets increase the density of optical radiative states at the location of the SLG, leading to enhanced spontaneous emission rate of graphene at its Raman emission wavelengths.

Method for computationally efficient design of dielectric laser accelerator structures.

Dielectric microstructures have generated much interest in recent years as a means of accelerating charged particles when powered by solid state lasers. The acceleration gradient (or particle energy gain per unit length) is an important figure of merit. To design structures with high acceleration gradients, we explore the adjoint variable method, a highly efficient technique used to compute the sensitivity of an objective with respect to a large number of parameters. With this formalism, the sensitivity of the acceleration gradient of a dielectric structure with respect to its entire spatial permittivity distribution is calculated by the use of only two full-field electromagnetic simulations, the original and 'adjoint'. The adjoint simulation corresponds physically to the reciprocal situation of a point charge moving through the accelerator gap and radiating. Using this formalism, we perform numerical optimizations aimed at maximizing acceleration gradients, which generate fabricable structures of greatly improved performance in comparison to previously examined geometries.

Marangoni Convection Assisted Single Molecule Detection with Nanojet Surface Enhanced Raman Spectroscopy.

Many single-molecule (SM) label-free techniques such as scanning probe microscopies (SPM) and magnetic force spectroscopies (MFS) provide high resolution surface topography information, but lack chemical information. Typical surface enhanced Raman spectroscopy (SERS) systems provide chemical information on the analytes, but lack spatial resolution. In addition, a challenge in SERS sensors is to bring analytes into the so-called "hot spots" (locations where the enhancement of electromagnetic field amplitude is larger than 103). Previously described methods of fluid transport around hot spots like thermophoresis, thermodiffusion/Soret effect, and electrothermoplasmonic flow are either too weak or detrimental in bringing new molecules to hot spots. Herein, we combined the resonant plasmonic enhancement and photonic nanojet enhancemnet of local electric field on nonplanar SERS structures, to construct a stable, high-resolution, and below diffraction limit platform for single molecule label-free detection. In addition, we utilize Marangoni convection (mass transfer due to surface tension gradient) to bring new analytes into the hotspot. An enhancement factor of ∼3.6 × 1010 was obtained in the proposed system. Rhodamine-6G (R6G) detection of up to a concentration of 10-12 M, an improvement of two orders of magnitude, was achieved using the nanojet effect. The proposed system could provide a simple, high throughput SERS system for single molecule analysis at high spatial resolution.

Combination of scanning probe technology with photonic nanojets.

Light focusing through a microbead leads to the formation of a photonic nanojet functional for enhancing the spatial resolution of traditional optical systems. Despite numerous works that prove this phenomenon, a method to appropriately translate the nanojet on top of a region of interest is still missing. Here, by using advanced 3D fabrication techniques we integrated a microbead on an AFM cantilever thus realizing a system to efficiently position nanojets. This fabrication approach is robust and can be exploited in a myriad of applications, ranging from microscopy to Raman spectroscopy. We demonstrate the potential of portable nanojets by imaging different sub-wavelength structures. Thanks to the achieved portability, we were able to perform a detailed optical characterization of the resolution enhancement induced by the microbead, which sheds light into the many contradictory resolution claims present in literature. Our conclusions are strongly supported by rigorous data analysis and by numerical simulations, all in perfect agreement with experimental results.

Tunable spatial mode converters and optical diodes for graphene parallel plate waveguides.

We introduce compact tunable spatial mode converters between the even and odd modes of graphene parallel plate (GPP) waveguides. The converters are reciprocal and are based on spatial modulation of graphene's conductivity. We show that the wavelength of operation of the mode converters can be tuned in the mid-infrared wavelength range by adjusting the chemical potential of a strip on one of the graphene layers of the GPP waveguides. We also introduce optical diodes for GPP waveguides based on a spatial mode converter and a coupler, which consists of a single layer of graphene placed in the middle between the two plates of two GPP waveguides. We find that for both the spatial mode converter and the optical diode the device functionality is preserved in the presence of loss.

Broadband near total light absorption in non-PT-symmetric waveguide-cavity systems.

We introduce broadband waveguide absorbers with near unity absorption. More specifically, we propose a compact non-parity-time-symmetric perfect absorber unit cell, consisting of two metal-dielectric-metal (MDM) stub resonators with unbalanced gain and loss side-coupled to a MDM waveguide, based on unidirectional reflectionlessness at exceptional points. With proper design, light can transport through the perfect absorber unit cell with reflection close to zero in a broad wavelength range. By cascading multiple unit cell structures, the overall absorption spectra are essentially the superposition of the absorption spectra of the individual perfect absorber unit cells, and absorption of ~ 100% is supported in a wide range of frequencies.

Highly compact magneto-optical switches for metal-dielectric-metal plasmonic waveguides.

We introduce highly compact resonant-cavity-enhanced magneto-optical switches for metal-dielectric-metal (MDM) plasmonic waveguides. The field profile of the fundamental mode of a MDM waveguide in which the metal is subject to an externally applied static magnetic field is asymmetric. The static magnetic field induced asymmetry, which enhances or reduces the coupling between the waveguide and a side-coupled resonator, and the relatively large induced wave vector modulation are used to design a Fabry-Perot cavity magneto-optical switch, consisting of a MDM waveguide side-coupled to two MDM stub resonators. The on and off states correspond to either the presence or the absence of the externally applied static magnetic field.

The role of Rabi splitting tuning in the dynamics of strongly coupled J-aggregates and surface plasmon polaritons in nanohole arrays.

We have investigated the influence of Rabi splitting tuning on the dynamics of strongly coupled J-aggregate/surface plasmon polariton systems. In particular, the Rabi splitting was tuned by modifying the J-aggregate molecule concentration while a polaritonic system was provided by a nanostructure formed by holes array in a golden layer. From the periodic and concentration changes we have identified, through numerical and experimental steady-state analyses, the best geometrical configuration for maximizing Rabi splitting, which was then used for transient absorption measurements. It was found that in transient absorption spectra, under upper band excitation, two bleaching peaks appear when a nanostructured polaritonic pattern is used. Importantly, their reciprocal distance increases upon increase of J-aggregate concentration, a result confirmed by steady-state analysis. In a similar manner it was also found that the lifetime of the upper band is intimately related to the coupling strength. In particular, we argue that with strong coupling strength, i.e. high J-aggregate concentration, a short lifetime of the upper band has to be expected due to the suppression of the bottleneck effect. This result supports the idea that the dynamics of hybrid systems is profoundly dependent on Rabi splitting.

Unidirectional reflectionless propagation in plasmonic waveguide-cavity systems at exceptional points.

We design a non-parity-time-symmetric plasmonic waveguide-cavity system, consisting of two metal-dielectric-metal stub resonators side coupled to a metal-dielectric-metal waveguide, to form an exceptional point, and realize unidirectional reflectionless propagation at the optical communication wavelength. The contrast ratio between the forward and backward reflection almost reaches unity. We show that the presence of material loss in the metal is critical for the realization of the unidirectional reflectionlessness in this plasmonic system. We investigate the realized exceptional point, as well as the associated physical effects of level repulsion, crossing and phase transition. We also show that, by periodically cascading the unidirectional reflectionless plasmonic waveguide-cavity system, we can design a wavelength-scale unidirectional plasmonic waveguide perfect absorber. Our results could be potentially important for developing a new generation of highly compact unidirectional integrated nanoplasmonic devices.

Plasmonic coaxial waveguide-cavity devices.

We theoretically investigate three-dimensional plasmonic waveguide-cavity structures, built by side-coupling stub resonators that consist of plasmonic coaxial waveguides of finite length, to a plasmonic coaxial waveguide. The resonators are terminated either in a short or an open circuit. We show that the properties of these waveguide-cavity systems can be accurately described using a single-mode scattering matrix theory. We also show that, with proper choice of their design parameters, three-dimensional plasmonic coaxial waveguide-cavity devices and two-dimensional metal-dielectric-metal devices can have nearly identical transmission spectra. Thus, three-dimensional plasmonic coaxial waveguides offer a platform for practical implementation of two-dimensional metal-dielectric-metal device designs.

Slow-light enhanced subwavelength plasmonic waveguide refractive index sensors.

We introduce slow-light enhanced subwavelength scale refractive index sensors which consist of a plasmonic metal-dielectric-metal (MDM) waveguide based slow-light system sandwiched between two conventional MDM waveguides. We first consider a MDM waveguide with small width structrue for comparison, and then consider two MDM waveguide based slow light systems: a MDM waveguide side-coupled to arrays of stub resonators system and a MDM waveguide side-coupled to arrays of double-stub resonators system. We find that, as the group velocity decreases, the sensitivity of the effective index of the waveguide mode to variations of the refractive index of the fluid filling the sensors as well as the sensitivities of the reflection and transmission coefficients of the waveguide mode increase. The sensing characteristics of the slow-light waveguide based sensor structures are systematically analyzed. We show that the slow-light enhanced sensors lead to not only 3.9 and 3.5 times enhancements in the refractive index sensitivity, and therefore in the minimum detectable refractive index change, but also to 2 and 3 times reductions in the required sensing length, respectively, compared to a sensor using a MDM waveguide with small width structure.