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1.
Nanotechnology ; 26(7): 074001, 2015 Feb 20.
Article in English | MEDLINE | ID: mdl-25629930

ABSTRACT

Graphene nanopores are receiving great attention due to their atomically thin membranes and intrinsic electrical properties that appear greatly beneficial for biosensing and DNA sequencing. Here, we present an extensive study of the low-frequency 1/f noise in the ionic current through graphene nanopores and compare it to noise levels in silicon nitride pore currents. We find that the 1/f noise magnitude is very high for graphene nanopores: typically two orders of magnitude higher than for silicon nitride pores. This is a drawback as it significantly lowers the signal-to-noise ratio in DNA translocation experiments. We evaluate possible explanations for these exceptionally high noise levels in graphene pores. From examining the noise for pores of different diameters and at various salt concentrations, we find that in contrast to silicon nitride pores, the 1/f noise in graphene pores does not follow Hooge's relation. In addition, from studying the dependence on the buffer pH, we show that the increased noise cannot be explained by charge fluctuations of chemical groups on the pore rim. Finally, we compare single and bilayer graphene to few-layer and multi-layer graphene and boron nitride (h-BN), and we find that the noise reduces with layer thickness for both materials, which suggests that mechanical fluctuations may be the underlying cause of the high 1/f noise levels in monolayer graphene nanopore devices.


Subject(s)
Biosensing Techniques/methods , Graphite/chemistry , Metal Nanoparticles/chemistry , Nanopores , Nanotechnology/methods , Benzophenones , Buffers , DNA/chemistry , Ethanol/chemistry , Fourier Analysis , Hydrogen-Ion Concentration , Ketones/chemistry , Microscopy, Electron, Transmission , Polyethylene Glycols/chemistry , Polymers , Reproducibility of Results , Sequence Analysis, DNA , Signal-To-Noise Ratio
2.
Nat Mater ; 11(10): 865-71, 2012 Oct.
Article in English | MEDLINE | ID: mdl-22961203

ABSTRACT

The unique optoelectronic properties of graphene make it an ideal platform for a variety of photonic applications, including fast photodetectors, transparent electrodes in displays and photovoltaic modules, optical modulators, plasmonic devices, microcavities, and ultra-fast lasers. Owing to its high carrier mobility, gapless spectrum and frequency-independent absorption, graphene is a very promising material for the development of detectors and modulators operating in the terahertz region of the electromagnetic spectrum (wavelengths in the hundreds of micrometres), still severely lacking in terms of solid-state devices. Here we demonstrate terahertz detectors based on antenna-coupled graphene field-effect transistors. These exploit the nonlinear response to the oscillating radiation field at the gate electrode, with contributions of thermoelectric and photoconductive origin. We demonstrate room temperature operation at 0.3 THz, showing that our devices can already be used in realistic settings, enabling large-area, fast imaging of macroscopic samples.


Subject(s)
Graphite/chemistry , Temperature , Electrodes , Electromagnetic Fields , Photons , Transistors, Electronic
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