Wide-range resistivity characterization of semiconductors with terahertz time-domain spectroscopy.

Resistivity is one of the most important characteristics in the semiconductor industry. The most common way to measure resistivity is the four-point probe method, which requires physical contact with the material under test. Terahertz time domain spectroscopy, a fast and non-destructive measurement method, is already well established in the characterization of dielectrics. In this work, we demonstrate the potential of two Drude model-based approaches to extract resistivity values from terahertz time-domain spectroscopy measurements of silicon in a wide range from about 10-3 Ωcm to 102 Ωcm. One method is an analytical approach and the other is an optimization approach. Four-point probe measurements are used as a reference. In addition, the spatial resistivity distribution is imaged by X-Y scanning of the samples to detect inhomogeneities in the doping distribution.

ErAs:In(Al)GaAs photoconductor-based time domain system with 4.5 THz single shot bandwidth and emitted terahertz power of 164 µW.

Superlattice structures of In(Al)GaAs with localized ErAs trap centers feature excellent material properties for terahertz (THz) generation and detection. The carrier lifetime of these materials as emitter and receiver has been measured as 1.76 ps and 0.39 ps, respectively. Packaged photoconductors driven by a 1550 nm, 90 fs commercial Toptica "TeraFlash pro" system feature a 4.5 THz single shot bandwidth with more than 60 dB dynamic range. The emitted THz power of the ErAs:In(Al)GaAs emitter versus laser power has been recorded with a pyroelectric detector calibrated by the Physikalisch Technische Bundesanstalt (PTB). The maximum power was 164 µW at a laser power of 42 mW and a bias of 200 V.

Industrial Applications of Terahertz Sensing: State of Play.

This paper is a survey of existing and upcoming industrial applications of terahertz technologies, comprising sections on polymers, paint and coatings, pharmaceuticals, electronics, petrochemicals, gas sensing, and paper and wood industries. Finally, an estimate of the market size and growth rates is given, as obtained from a comparison of market reports.

All fiber-coupled THz-TDS system with kHz measurement rate based on electronically controlled optical sampling.

We demonstrate a completely fiber-coupled terahertz (THz) time-domain spectrometer (TDS) system based on electronically controlled optical sampling with two erbium-doped femtosecond fiber lasers at a central wavelength of 1560 nm. The system employs optimized InGaAs/InAlAs photoconductive antennas for THz generation and detection. With this system, we achieve measurement rates of up to 8 kHz and up to 180 ps scan range. We further achieve 2 THz spectral bandwidth and a dynamic range of 76 dB at only 500 ms measurement time.

Polarization sensitive terahertz imaging: detection of birefringence and optical axis.

We present a practicable way to take advantage of the spectral information contained in a broadband terahertz pulse for the determination of birefringence and orientation of the optical axis in a glass fiber reinforced polymer with a single measurement. Our setup employs circularly polarized terahertz waves and a polarization-sensitive detector to measure both components of the electromagnetic field simultaneously. The anisotropic optical parameters are obtained from an analysis of the phase and frequency resolved components of the terahertz field. This method shows a high tolerance against the skew of the detection axes and is also independent of a reference measurement.

Efficient terahertz en-face imaging.

In this work, we develop a pulsed terahertz imaging system in reflection geometry, where due to scanning of the terahertz beam neither the sample nor the emitter and detector have to be moved. We use a two mirror galvanoscanner for deflecting the beam, in combination with a single rotationally symmetric focusing lens. In order to efficiently image planar structures, we develop an advanced scanning routine that resolves all bending effects of the imaging plane already during measurement. Thus, the measurement time is reduced, and efficient imaging of surfaces and interfaces becomes possible. We demonstrate the potential of this method in particular for a plastic-metal composite sample, for which non-destructive evaluation of an interface is performed.

Paper terahertz wave plates.

We present a low-cost terahertz wave plate based on form birefringence fabricated using ordinary paper. Measurements of the transfer function of the wave plate between polarizers closely agree with predictions based on the measured complex indices of refraction of the effective medium. For the design frequency, the dependence on wave plate angle also agrees with theory.

Terahertz properties of liquid crystals with negative dielectric anisotropy.

We present what is believed to be the first terahertz time-domain study of a set of liquid crystals (LCs) with negative dielectric anisotropy. From the measured data, refractive indices, and absorption coefficients for ordinary and extraordinary polarization are extracted. We find that the investigated materials exhibit a much smaller absorption than LCs with positive dielectric anisotropy. Thus, these materials are more useful for switchable terahertz devices. Moreover, the LC 1808 shows what is to our knowledge the largest terahertz birefringence reported so far.

Terahertz imaging: applications and perspectives.

Terahertz (THz) spectroscopy, and especially THz imaging, holds large potential in the field of nondestructive, contact-free testing. The ongoing advances in the development of THz systems, as well as the appearance of the first related commercial products, indicate that large-scale market introduction of THz systems is rapidly approaching. We review selected industrial applications for THz systems, comprising inline monitoring of compounding processes, plastic weld joint inspection, birefringence analysis of fiber-reinforced components, water distribution monitoring in polymers and plants, as well as quality inspection of food products employing both continuous wave and pulsed THz systems.

Molecular properties of liquid crystals in the terahertz frequency range.

We report on a first experimental study of the molecular properties of nematic liquid crystals in the terahertz range. In the beginning, we extract the frequency and temperature dependent refractive index and absorption coefficient of the cyanobiphenyls 5CB, 6CB and 7CB from terahertz time domain spectroscopy measurements and investigate the impact of the alkyl chain length on the macroscopic liquid crystal characteristics, focusing especially on the pronounced odd and even effect. Next, we deduce the principle polarizabilities and the order parameter S by applying Vuks' approximation and Haller's approach. On this basis, we calculate the main polarizabilities along the longitudinal and transverse axis and link the observed terahertz properties to the molecular structure of the liquid crystals.

Liquid crystal based electrically switchable Bragg structure for THz waves.

We demonstrate the first electronically switchable Bragg structure for THz frequencies. The structure works as stop-band filter and as mirror. It exhibits the 60 GHz broad stop-band around 300 GHz which can be removed by reorienting liquid crystal molecules in an external electric field. Our first proof-of-principle experiments agree very well with transfer matrix calculations.