Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach.

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesoporous ZSM-5 were created via reverse order impregnation to facilitate HDO of non-edible oils. Techniques such as XRD, FT-IR, BET, HR-TEM, HR-SEM, TPD, and TGA were used to characterize the produced catalysts. The synthesized catalysts considerably influenced the hydrodeoxygenation activities for the synthesis of lengthy chain hydrocarbons in a stainless-steel reactor with a high-pressure fixed bed between 300 and 375 °C under 10-40 bar hydrogen pressure. High levels of Ni/Pt-ZSM-5 acidity, textural, and H2 consumption qualities were discovered. Distributions of the products were also reviewed, along with comparisons of the structure-activity connections.

Self-Super-Resolution of an MRI Image with Assistance of the DSTTD System.

Motivation. In the modern world of information technology, the need for ensuring the safety of wireless transmissions while transiting through a given network is growing rapidly. The process of transmitting images via a wireless network is fraught with difficulty. There is a possibility that data may be corrupted while being transmitted, which would result in an image with low resolution. Both of these issues were investigated head-on in this research methodology using the aiding double space-time block coding (DSTTD) system and the self-super-resolution (SSR) method. Description. In recent times, medical image transmission over a wireless network has received a significant amount of attention, as a result of the sharing of medical images between patients and doctors. They would want to make sure that the image was sent in a risk-free and protected manner. Arnold cat map, often known as ACM, is a well-known and widely implemented method of image transmission encryption that has been in use for quite some time. At the receiver end, SSR is now being employed in order to view the transmitted medical image in the finest possible resolution. It is anticipated that in the near future, image transmission through wireless DSTTD will be technically feasible. This is performed in order to maximize the benefits that the system has to offer in terms of both spatial diversity and multiplexing as much as is possible. Conclusion. The SSR approach is used in order to represent the image in a document pertaining to human resources. ACM is used so that the image may be sent in a risk-free and protected way. The adoption of a DSTTD-based architecture for wireless communication is suggested. A comparison of the results is provided, and PSNR and SSIM values are detailed towards the results and discussion of the article.

Twitter based sentimental analysis of Covid-19 observations.

The emergence of social media has provided people with the opportunity to express their feelings and thoughts about everything and everything in their lives. There is a massive amount of textual stuff available, and approaches are required to make meaningful use of the information provided by isolating and evaluating the different types of text. Sentimental Analysis is a method of obtaining a human being's point of view through mining his or her emotions. The entire world is sharing their thoughts on social media on the Corona Pandemic that is now underway. This research presents an analysis of attitudes in order to determine whether or not people are optimistic in the face of a difficult circumstance. The technique of polarity is employed by the paper in order to determine if an opinion is positive, negative, or nonpartisan [1]. In order to determine the polarity, the following three major keywords are used: "COVID", "Corona virus," and "COVID-19."

Microremediation of tannery wastewater by siderophore producing marine bacteria.

The present study evaluated the microremediation potential of nine siderophore producing marine bacteria for hazardous raw tannery wastewater from common effluent treatment plant (CETP). Most of the pollutants detected in the wastewater were diminished after the bioremediation process. Further, among the three potent isolates selected for aerobic and anaerobic bioremediation study, Marinobacter hydrocarbonoclasticus demonstrated the highest bioremediation aerobically with a reduction in chromium (88%), sulphate (71%), phosphate (68%) and nitrate (57%). Notably, Nitratireductor kimnyeongensis could attack the effluent under both aerobic and anaerobic conditions as substantiated by statistically significant (p < .05) reduction in the pollutants [chromium (85%), sulphate (63%), Chemical Oxygen Demand (COD) (69%), phosphate (76%)]. From the study it is evident that the pollutant load reduction was achieved under both aerobic and anaerobic conditions, however, aerobic environment was more effective in reducing chromium, Biochemical Oxygen Demand (BOD), sulphate, nitrate and phosphate. The bioremediation efficiency was further confirmed by the bioassay experiments with plant and animal models where higher seed germination, greater plant length and biomass, as well as improved survival rate of Artemia nauplii for bioremediated wastewater was observed as compared to the untreated effluent indicating a significant reduction in toxicity. The results for simultaneous removal of multiple-toxicants thus signify effectiveness and ease of using the robust properties of these marine bacterial strains suggesting their potential application for bioremediation. Hence this could pave a promising way for an environment-friendly and economically feasible clean-up strategy for safer disposal of tannery wastewater.

Effective bioremediation and toxicity assessment of tannery wastewaters treated with indigenous bacteria.

This study evaluated the bioremediation capacity of indigenous bacteria isolated from tannery sludge for two different tannery wastewaters collected from Kanpur and Chennai. To identify bacteria which can efficiently degrade a mixture of different pollutants, the isolates were grown in hazardous 100% tannery wastewaters. The reductions in toxicants such as chromium, sulphate, biochemical oxygen demand (BOD) and chemical oxygen demand (COD) of the wastewater were analysed post-bioremediation. Amongst the isolates, Citrobacter freundii was able to reduce the concentration of multiple toxicants such as chromium by 73% and sulphate was reduced by 68% bringing down the level much below the permissible limit stipulated by Bureau of Indian Standards (BIS). Notably, the organic load characterized by BOD and COD was also lowered by 86 and 80%, respectively. The indigenous isolates, not only bioremediated the Kanpur effluent but, also significantly detoxified the Chennai effluent having higher toxicant load. An interesting observation made during the study was better survival and growth along with the development of appendages of Artemia nauplii in the treated wastewaters which thus further confirmed reduction in toxicity of the effluents. The results thus demonstrate that the tested indigenous strains are promising for bioremediation of tannery wastewater and effectively improve the water quality for safe discharge.

Detoxification and color removal of Congo red by a novel Dietzia sp. (DTS26) - a microcosm approach.

The present study deals with the decolorization and detoxification of Congo red (CR) by a novel marine bacterium Dietzia sp. (DTS26) isolated from Divar Island, Goa, India. The maximum decolorization of 94.5% (100 mg L(-1)) was observed under static condition within 30 h at pH 8 and temperature 32±2°C. Bacterially treated samples could enhance the light intensity by 38% and the primary production levels 5 times higher than the untreated. The strain was also able to reduce COD by 86.4% within 30 h at 100 mg L(-1) of CR dye. The degraded metabolites of CR dye were analyzed by FTIR, HPLC, GC-MS and the end product closely matches with 4-amino-3-naphthol-1-sulfonate which is comparatively less toxic than CR. Bioassay experiments conducted in treated samples for Artemia franciscana showed better survival rates (after 72 h) at higher concentration of CR (500 mg L(-1)). This work suggests the potential application of DTS26 in bioremediation of dye wastes and its safe disposal into coastal environment.

Biosynthesis of Silver Nanoparticles from Marine Seaweed Sargassum cinereum and their Antibacterial Activity.

Seaweed extracts of Sargassum cinereum was used as a reducing agent in the eco-friendly extracellular synthesis of silver nanoparticles from an aqueous solution of silver nitrate (AgNO3). High conversion of silver ions to silver nanoparticles was achieved with a reaction temperature of 100(°) and a seaweed extract concentration of 10% with a residential time of 3 h. Formation of silver nanoparticles was characterised by spectrophotometry and the scanning electron microscope. The average particles size was ranging from 45 to 76 nm. Antimicrobial activities indicate the minimum inhibitory concentration of biologically synthesised nanoparticles tested against the pathogen Staphylococcus aureus with 2.5 µl (25 µg/disc). High inhibitions over the growth of Enterobacter aerogenes, Salmonella typhi and Proteus vulgaris were witnessed against the concentrations of 100 µg/disc. Promising potential and the future prospects of S. cinereum nanoparticles in pharmaceutical research are the highlights in this paper.

Electrochemical, catalytic and antimicrobial activity of N-functionalized tetraazamacrocyclic binuclear nickel(II) complexes.

The five binuclear nickel(II) complexes have been synthesized by the Schiff base condensation of 1,8-[bis(3-formyl-2-hydroxy-5-methyl)benzyl]-l,4,8,11-tetraazacyclo-tetradecane (PC) with appropriate aliphatic diamines and nickel(II) perchlorate. All the five complexes were characterized by elemental and spectral analysis. The electronic spectra of the complexes show three d-d transition in the range of 550-1055 nm due to 3A2g→3T2g(F), 3A2g→3T1g(F) and 3A2g→3T1g(P). These spin allowed electronic transitions are characteristic of an octahedral Ni2+ center. Electrochemical studies of the complexes show two irreversible one electron reduction waves at cathodic region. The reduction potential of the complexes shifts towards anodically upon increasing the chain length of the macrocyclic ring. All the nickel(II) complexes show two irreversible one electron oxidation waves at anodic region. The oxidation potential of the complexes shift towards anodically upon increasing the chain length of the macrocyclic ring. The catalytic activities of the complexes were observed to be increase with increase the macrocyclic ring size. The observed rate constant values for the catalytic hydrolysis of 4-nitrophenyl phosphate are in the range of 5.85×10(-3) to 9.14×10(-3) min(-1). All the complexes were screened for antimicrobial activity.