Reconfigurable broadband metasurfaces with nearly perfect absorption and high efficiency polarization conversion in THz range.

Reconfigurable metasurfaces (RMSs) that enable the switching function of absorption and polarization conversion have attracted increasing attention. However, the design of RMSs to achieve wideband and high efficiency for both absorption and polarization conversion functions simultaneously remains a great challenge. Here, we propose the design of a RMS structure with a high-efficiency cross-polarization conversion and nearly perfect absorption. The reconfiguration between different functions of polarization conversion and absorption is obtained based on the reversible insulator-to-metal phase transition of Vanadium dioxide (VO[Formula: see text]). When the VO[Formula: see text] is in insulator state, the RMS realizes the cross-polarization conversion function in the wideband of 1.04-3.75 THz with a relative bandwidth up to 113 [Formula: see text] due to the multi-resonant modes of electric and magnetic resonances. Meanwhile, the nearly-perfect absorption is achieved in the range of 1.36-3.38 THz with the corresponding relative bandwidth up to 85 [Formula: see text] for the VO[Formula: see text] in metallic state. Specially, the wideband and high-efficiency performance of these functionalities is maintained for a wide angle incidence. The capability of bi-functional switch and integration with polarization conversion and absorption in a single metasurface structure endowed with both wideband and high-efficiency characteristics for a wide incident angle is very promising for emerging RMS devices in the terahertz region.

Advances in magnetic field-assisted electrolyte's physicochemical properties and electrokinetic parameters: A case study on the response ability of chloramphenicol on Fe3O4@carbon spheres-based electrochemical nanosensor.

Despite the utilization of external magnetic field (MF) in promoting the intrinsic unique features of magnetic nanomaterials in many different applications has been reported, however the origin of MF-dependent electrochemical behaviors as well as the electrochemical response of analytes at the electrode in sensor applications is still not clear. In this report, the influence of MF on the electrolyte's physicochemical properties (polarization, mass transport, charge/electron transfer) and electrode's properties (conductivity, morphology, surface area, interaction, adsorption capability, electrocatalytic ability) was thoroughly investigated. Herein, the working electrode surface was modified with carbon spheres (CSs), magnetic nanoparticles (Fe3O4NPs), and their nanocomposites (Fe3O4@CSs), respectively. Then, they were directly used to enhance the electrochemical characteristics and response-ability of chloramphenicol (CAP). More interestingly, a series of various kinetic parameters related to the diffusion-controlled process of K3[Fe(CN)6]/K4[Fe(CN)6)] and the adsorption-controlled process of CAP were calculated at the bare electrode and the modified electrodes with and without the presence of MF. These parameters not only exhibit the crucial role of the modification of electrode surface with the proposed materials but also show positive impacts of the presence of external MF. Besides, the mechanism and hypothesis for the enhancements were proposed and discussed in detail, further demonstrating the development potential of using Fe3O4@CS nanocomposites with MF assistant for advanced energy, environmental, and sensor related-applications.

Insight into the Influence of Analyte Molecular Structure Targeted on MoS2-GO-Coated Electrochemical Nanosensors.

MoS2-GO composites were fabricated by an ultrasonication method at room temperature. Raman spectra, emission scanning electron microscopy (SEM), and transmission electron microscopy (TEM) images were used to study the structural characteristics, morphologies, and sizes of the synthesized materials. An MoS2-GO/SPE (screen-printed electrode) was prepared by a facile dropping method and acted as an effective electrochemical sensor toward clenbuterol (CLB) and 4-nitrophenol (4-NP) detection. Based on the obtained results, the influence of analyte molecular structure on the adsorption ability and electronic interoperability between the targeted analyte and electrode surface were investigated in detail and discussed as well, through some electrochemical kinetic parameters (electron/proton-transfer number, electron transfer rate constant (ks), charge transfer coefficient, and adsorption capacity (Γ)). In particular, it should be stressed that 4-NP molecules possess a simple molecular structure with many positive effects (electronic, conjugation, and small steric effects) and flexible functional groups, resulting in fast electron transport/charge diffusion and effective adsorption process as well as strong interactions with the electrode surface. Therefore, 4-NP molecules have been facilitated better in electrochemical reactions at the electrode surface and electrode-electrolyte interfaces, leading to improved current response and electrochemical sensing performance, compared with those of CLB.

Simple design of efficient broadband multifunctional polarization converter for X-band applications.

A simple design of a broadband multifunctional polarization converter using an anisotropic metasurface for X-band application is proposed. The proposed polarization converter consists of a periodic array of the two-corner-cut square patch resonators based on the FR-4 substrate that achieves both cross-polarization and linear-to-circular polarization conversions. The simulated results show that the polarization converter displays the linear cross-polarization conversion in the frequency range from 8 to 12 GHz with the polarization conversion efficiency above 90%. The efficiency is kept higher than 80% with wide incident angle up to 45°. Moreover, the proposed design achieves the linear-to-circular polarization conversion at two frequency bands of 7.42-7.6 GHz and 13-13.56 GHz. A prototype of the proposed polarization converter is fabricated and measured, showing a good agreement between the measured and simulated results. The proposed polarization converter exhibits excellent performances such as simple structure, multifunctional property, and large cost-efficient bandwidth and wide incident angle insensitivity in the linear cross polarization conversion, which can be useful for X-band applications. Furthermore, this structure can be extended to design broadband polarization converters in other frequency bands.

Correlation of magnetic and magnetoresistive properties of nanoporous Co/Pd thin multilayers fabricated on anodized TiO2 templates.

In this study, we consider a technological approach to obtain a high perpendicular magnetic anisotropy of the Co/Pd multilayers deposited on nanoporous TiO2 templates of different types of surface morphology. It is found that the use of templates with homogeneous and smoothed surface relief, formed on silicon wafers, ensures conservation of perpendicular anisotropy of the deposited films inherent in the continuous multilayers. Also, their magnetic hardening with doubling of the coercive field is observed. However, inhomogeneous magnetic ordering is revealed in the porous films due to the occurrence of magnetically soft regions near the pore edges and/or inside the pores. Modeling of the field dependences of magnetization and electrical resistance indicates that coherent rotation is the dominant mechanism of magnetization reversal in the porous system instead of the domain-wall motion typical of the continuous multilayers, while their magnetoresistance is determined by electron-magnon scattering, similarly to the continuous counterpart. The preservation of spin waves in the porous films indicates a high uniformity of the magnetic ordering in the fabricated porous systems due to a sufficiently regular pores array introduced into the films, despite the existence of soft-magnetic regions. The results are promising for the design and fabrication of future spintronic devices.

Complex magnetic ordering in nanoporous [Co/Pd]5-IrMn multilayers with perpendicular magnetic anisotropy and its impact on magnetization reversal and magnetoresistance.

We have systematically investigated the magnetization reversal characteristics and magnetoresistance of continuous and nanoporous [Co/Pd]5-IrMn multilayered thin films with perpendicular magnetic anisotropy at different temperatures (4-300 K). For their nanostructuring, porosity was induced by means of deposition onto templates of anodized titania with small (∼30 nm in diameter) homogeneously distributed pores. The magnetization reversal and magnetoresistance of the porous films were found to be closely related to the splitting of the ferromagnetic material into regions with different magnetic properties, in correlation with the complex morphology of the porous system. Independent magnetization reversal is detected for these regions, and is accompanied by its strong impact on the magnetic order in the capping IrMn layer. Electron-magnon scattering is found to be a dominant mechanism of magnetoresistance, determining its almost linear field dependence in a high magnetic field and contributing to its magnetoresistance behavior, similar to magnetization reversal, in a low magnetic field. Partial rotation of IrMn magnetic moments, consistent with the magnetization reversal of the ferromagnet, is proposed as an explanation for the two-state resistance behavior observed in switching between high-resistive and low-resistive values at the magnetization reversal of the porous system studied.

Broadband microwave coding metamaterial absorbers.

In this paper, a broadband metamaterial microwave absorber is designed, simulated and measured. Differently from the traditional method which is only based on unit cell boundary conditions, we carried out full-wave finite integration simulations using full-sized configurations. Starting from an elementary unit cell structure, four kinds of coding metamaterial blocks, 2 × 2, 3 × 3, 4 × 4 and 6 × 6 blocks were optimized and then used as building blocks (meta-block) for the construction of numerous 12 × 12 topologies with a realistic size scale. We found the broadband absorption response in the frequency range 16 GHz to 33 GHz, in good agreement with the equivalent medium theory prediction and experimental observation. Considering various applications of metamaterials or metamaterial absorbers in the electromagnetic wave processing, including the radars or satellite communications, requires the frequency in the range up to 40 GHz. Our study could be useful to guide experimental work. Furthermore, compared to the straightforward approach that represents the metamaterials configurations as 12 × 12 matrices of random binary bits (0 and 1), our new approach achieves significant gains in the broadband absorption. Our method also may be applied to the full-sized structures with arbitrary dimensions, and thus provide a useful tool in the design of metamaterials with specific desired frequency ranges.

Tunable broadband-negative-permeability metamaterials by hybridization at THz frequencies.

We present a numerical study of thermo-tunable broadband-negative-permeability metamaterial based on second-order hybridization operating at the THz regime. The conventional metal is replaced by InSb, in which the temperature-dependent conductivity plays a key role in tuning the separation of second-order-hybridization magnetic-resonance modes. It is demonstrated that the hybridization in a simple disk-pair dimer can be tuned by temperature, leading to a significant broadening of the negative-permeability at THz frequencies. By increasing the temperature of the InSb patterns in the structure from 300 to 450 K, the fractional bandwidth (FBW) of the negative permeability curve varies from 4.4% to 12.9%. The thermally-increased carrier-density of InSb reduces the kinetic inductance, the main mechanism of the enhanced magnetic-resonance and the stronger activated-hybridization. Moreover, optimization for the bandwidth of negative permeability is also carried out by changing the geometrical parameters to have a FBW of 20.9%. The equivalent LC-circuit model and standard retrieval method are performed to elaborate our proposed idea. Our results would pave the way for the implementations of diversified semiconductors in tunable broadband-negative-permeability and broadband-negative-refractive-index metamaterials at THz frequencies.

Controlling Fano resonances in multilayer dielectric gratings towards optical bistable devices.

The spectral properties of Fano resonance generated in multilayer dielectric gratings (MDGs) are reported and numerically investigated in this paper. We examine the MDG consisting of numerous identically alternative chalcogenide glass (As2S3) and silica (SiO2) multilayers with several grating widths inscribed through the structure, emphasizing quality (Q) and asymmetric (q) factors. Manipulation of Fano lineshape and its linear characteristics can be achieved by tailoring the layers' amount and grating widths so that the proposed structure can be applicable for several optical applications. Moreover, we demonstrate the switching/bistability behaviors of the MDG at Fano resonance which provide a significant switching intensity reduction compared to the established Lorentzian resonant structures.

Controlled Defect Based Ultra Broadband Full-sized Metamaterial Absorber.

Metamaterial full-sized absorber structures are numerically and experimentally investigated in GHz region and then examined in THz frequency. By manipulating monitoring the number and the position of the defect elements in conventional unit cells, the optimal integrative absorber structures are generated. The proposed structures provide an ultra-broadband absorbance in the operating frequency. The good agreement between simulation, measurement and theoretical analysis is observed with a 5 GHz-bandwidth corresponding to the absorption of 95%. In particular, we extrapolate the concept to THz region and demonstrate that, the method can be applied to increase the bandwidth of the metamaterial absorber to 5 THz, while maintaining the other characteristics. This structure can be applied to improve the performance of telecommunication systems such as micro-antenna, micro-electromagnetic transmitters and apply to imaging and sensing fields.