ABSTRACT
The solar-to-electric conversion efficiency of mesoscopic solar cells is highly dependent on electron extraction under solar irradiation and determines the charge recombination processes within devices. Boosting charge transfer via building energy level alignment has been proved to be a promising method to enhance the output power of solar cells. In the current work, we present the successful fabrication of functional biomass-converted carbon quantum dots with graded energy levels by doping nitrogen or sulphur atoms from lotus root powder. When employed as light absorbers for mesoscopic solar cells, light harvesting and electron extraction can be markedly increased arising from the band alignment of graded carbon quantum dots, yielding maximal power conversion efficiencies of 0.158% and 0.208% for bi- and tri-cascaded photovoltaics, respectively. The primary results demonstrate that the employment of an energy-graded architecture is a promising strategy to optimize the device output. Following this line of thought, we further fabricate a co-sensitized device by integrating graded carbon quantum dots with N719 dyes to enhance the electron extraction capability. The final device yields an efficiency as high as 9.04%, showing the potential application of carbon quantum dots in high-performance solar cells.
Subject(s)
Carbon/chemistry , Quantum Dots/chemistry , Solar Energy , Biomass , Electric Power Supplies , Quantum TheoryABSTRACT
@# Chimeric antigen receptor (CAR) T lymphocyte has shown attractive prospects in the treatment of lymphohematopoietic malignancies including B-cell lymphoblastic leukemia, B-cell lymphoma and multiple myeloma. Many applicants have submitted investigational new drug (IND) applications to Center for Drug Evaluation of National Medical Products Ggency, however, many of the INDs have problems in patient selection, prognostic indicators and risk management, etc, which might hinder the evaluation of the safety and efficacy of CAR-T cells. Thus, we made some suggestions on the above-mentioned problems through summarizing clinical experience and communicating with domestic clinical experts, which the sponsors and researchers can refer to when conducting CAR-T cell clinical trials for registration.
ABSTRACT
Bismuth (Bi) nanoparticles are prepared by using NaBi(MoO4)2 nanosheets in the beam of electrons emitted by transmission electron microscope. The formation and growth of Bi nanoparticles are investigated in situ. The sizes of Bi nanoparticles are confined within the range of 6-10nm by controlling irradiation time. It is also observed that once the diameter of nanoparticles is larger than 10nm, the Bi particles are stable as a result of the immobility of large nanoparticles. In addition, some nanoparticles on the edges form nanorods, which are explained as the result of a coalescence process, if the irradiation period is longer than 10min. The in situ research on Bi nanoparticles facilitates in-depth investigations of the physicochemical behavior and provides more potential applications in various fields such as sensors, catalysts and optical devices.
ABSTRACT
Abstract Highly efficient bilayer-structure yellow-green organic light-emitting device (OLED) has been demonstrated based on MADN as hole-transport layer (HTL) and host-guest coped system of [Alq3: 0.7 Wt% rubrene] as emitting and electron-trans- port layer. The device gives yellow-green emission through incomplete energy transfer from the host of Alq3 to the guest of ru- brene. An electroluminescent peak of 560 nm, 1931 CIE color coordinates of (0.46, 0.52) and a maximum current efficiency of 7.63 cd · A⻹ (which has been enhanced by 30% in comparison with the counterpart having conventional NPB HTL) are ob- served. The hole-transporting characteristics of MADN and NPB have been systematically investigated by constructing hole-only devices and employing impedance spectroscopy analysis. Our results indicate that MADN can be served as an effective hole-trans- port material and its hole-transporting ability is slightly inferior to NPB. This overcomes the shortcoming of hole transporting more quickly than electron in OLED and improves carrier balance in the emitting layer. Consequently, the device current efficien- cy is promoted. In addition, the current efficiency of bilayer-structure OLED with MADN as HTL is comparable to that of conv- entinol trilayer-structure device with MADN as HTL and Alq3 as electron-transport layer. This indicates that the simplified bi- layer-structure device can be achieved without sacrificing current efficiency. The emitting layer of [Alq: 0.7 Wt% rubrene possesses superior elecron-transporting ability.
