Facile synthesis CQDs/SnO2-x/BiOI heterojunction photocatalyst to effectively degrade pollutants and antibacterial under LED light.

To remove multitudinous pollutants from wastewater, the design of a highly efficient and multifunctional photocatalyst is necessary. A novel CQDs/SnO2-x/BiOI photocatalyst (named CSnBI composite) was prepared by combining carbon quantum dots (CQDs), large specific surface area SnO2-x nanocrystals and BiOI nanocrystals to obtain a compact hybrid structure. TEM and Raman techniques confirmed the structure of CSnBI composite. The photocurrent and EIS showed that the photoexcited electron-hole pairs separation efficiency was improved. As anticipated, novel CSnBI photocatalyst can successfully remove tetracycline, methyl orange, E. coli (Escherichia coli) and S. aureus under a LED light due to the hybridization contaction among CQDs, SnO2-x and BiOI. The mechanism showed that the introduction of CQDs promoted visible light absorption and efficient separation of photogenerated carriers of SnO2-x/BiOI heterojunction. The capture experiment and related measurements showed that h+, •O2- and •OH are active species in the photocatalytic process. This study gave a novel case for facile construction of photocatalysts with tight hybrid structure.

Construction of oxygen vacancy assisted Z-scheme BiO2-x/BiOBr heterojunction for LED light pollutants degradation and bacteria inactivation.

It is well known that the most important task of photocatalytic technology is to synthesize photocatalysts with compact heterojunction structure and high redox ability. To achieve the goal, a novel Z-scheme BiO2-x/BiOBr heterojunction containing oxygen vacancy was synthesized by an in-situ generation process. Several techniques, X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) have verified the BiO2-x/BiOBr heterojunction. XPS and electron spin resonance (ESR) reveals the presence of oxygen vacancy in the BiO2-x/BiOBr composite. As expected, the BiO2-x/BiOBr composite showed good performance in removing Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), Rhodamine B (RhB) and tetracycline (TC). The effects of inorganic ions, pH value and water matrix were investigated with many details. The active species and proposed mechanism were revealed by trapping experiment and related characterizations. The synergistic effect of oxygen vacancy and Z-scheme heterojunction makes the BiO2-x/BiOBr composite possess excellent photocatalytic activity.