Achiral Nanoparticle-Enhanced Chiral Twist and Thermal Stability of Blue Phase Liquid Crystals.

Blue phase liquid crystals (BPLCs) are chiral mesophases with 3D order, which makes them a promising template for doping nanoparticles (NPs), yielding tunable nanomaterials attractive for microlasers and numerous microsensor applications. However, doping NPs to BPLCs causes BP lattice extension, which translates to elongation of operating wavelengths of light reflection. Here, it is demonstrated that small (2.4 nm diameter) achiral gold (Au) NPs decorated with designed LC-like ligands can enhance the chiral twist of BPLCs (i.e., reduce cell size of the single BP unit up to ∼14% and ∼7% for BPI and BPII, respectively), translating to a blue-shift of Bragg reflection. Doping NPs also significantly increases the thermal stability of BPs from 5.5 °C (for undoped BPLC) up to 22.8 °C (for doped BPLC). In line with our expectations, both effects are saturated, and their magnitude depends on the concentration of investigated nanodopants as well the BP phase type. Our research highlights the critical role of functionalization of Au NPs on the phase sequence of BPLCs. We show that inappropriate selection of surface ligands can destabilize BPs. Our BPLC and Au NPs are photochemically stable and exhibit great miscibility, preventing NP aggregation in the BPLC matrix over the long term. We believe that our findings will improve the fabrication of advanced nanomaterials into 3D periodic soft photonic structures.

Silicon-organic hybrid thermo-optic switch based on a slot waveguide directional coupler.

We propose and demonstrate a passively biased 2 × 2 thermo-optic switch with high power efficiency and fast response time. The device benefits from the highly concentrated optical field of a slot waveguide mode and the strong thermo-optic effect of a nematic liquid crystal (NLC) cladding. The NLC fills the nano-slot region and is aligned by the subwavelength grating inside. The measured power consumption and thermal time constant are 0.58 mW and 11.8 µs, respectively, corresponding to a figure-of-merit of 6.8 mW µs. The proposed silicon-organic hybrid device provides a new solution to design thermo-optic actuators having low power consumption and fast operation speed.

Electrotunable 180° achromatic linear polarization rotator based on a dual-frequency liquid crystal.

Linear polarization rotators have been widely used in optical systems. Commonly used polarization rotators are still beset by strong dispersion and thus restricted spectral bandwidth of operation. This leads to the development of achromatic or broadband alternatives, but most of them incorporate multiple waveplates for retardation compensation, which comes at the cost of increased complexity and reduced flexibility in operation and system design. Here, we demonstrate a single-element achromatic polarization rotator based on a thin film of dual-frequency chiral liquid crystal. The angle of polarization rotation is electrically tunable from 0° to 180° with low dispersion (±3°) in the entire visible spectrum, and a high degree of linear polarization (>95%) at the output.

Polarization-controlled chirped guided-mode resonance filter incorporating a hybrid splay-twist liquid crystal.

This work develops a tunable chirped guided-mode resonant (GMR) filter that has a hybrid splay-twist (HST) liquid crystal as a cladding layer. The GMR filter is a color reflector that strongly reflects light at the resonance wavelength, and its chirped grating structure supports tuning of the resonance peak over a wavelength range of over 50 nm. The HST-LC configuration serves as an achromatic polarization rotator that can rotate the axis of polarization of linearly polarized light by providing effective twist angles in the LC layer under an applied voltage. The HST-LC is used to change the direction of the polarization axis of the light that is reflected by the GMR filter; continuous angles of rotation of ∼90∘ are achieved and the linear polarization is retained under applied voltages. The proposed filter enables an ultrabroadband polarization rotation and still maintains a high degree of linear polarization, which allows more degrees of freedom in spectral and polarization controls.

Functional Superhydrophobic Surfaces with Spatially Programmable Adhesion.

A superhydrophobic surface that has controllable adhesion and is characterized by the lotus and petal effects is a powerful tool for the manipulation of liquid droplets. Such a surface has considerable potential in many domains, such as biomedicine, enhanced Raman scattering, and smart surfaces. There have been many attempts to fabricate superhydrophobic films; however, most of the fabricated films had uniform adhesion over their area. A patterned superhydrophobic surface with spatially controllable adhesion allows for increased functions in the context of droplet manipulation. In this study, we proposed a method based on liquid-crystal/polymer phase separation and local photopolymerization to realize a superhydrophobic surface with spatially varying adhesion. Materials and topographic structures were analyzed to understand their adhesion mechanisms. Two patterned surfaces with varying adhesion were fabricated from a superhydrophobic material to function as droplet guides and droplet collectors. Due to their easy fabrication and high functionality, superhydrophobic surfaces have high potential for being used in the fabrication of smart liquid-droplet-controlling surfaces for practical applications.

Voltage-controlled liquid crystal Pancharatnam-Berry phase lens with broadband operation and high photo-stability.

Pancharatnam-Berry phase optical elements (PBOEs) have received much attention due to their ability to generate complex structured light or to manipulate the shape of a light beam. This work demonstrates a tunable liquid crystal (LC) Pancharatnam-Berry (LCPB) lens using a simple and cost-effective PB phase hologram optical setup and thermal polymerization to form an irreversible photo-patterning alignment layer. The LCPB lens with high photo-stability supports ultra-broadband operation and provides a diffraction efficiency of ∼90% throughout the visible spectral range, achieved by applying the appropriate voltages. The LCPB lens functions as a convex or a concave lens, depending on the handedness of the circularly polarized incident light, so its image reduction and magnification functions are demonstrated, and its photo-stability is characterized. The fabrication of the proposed LC PBOEs is simpler and more cost-effective than previous methods, and the irreversible photo-patterning alignment layer that is formed by thermal polymerization allows larger operational bandwidths, supporting new applications.

Highly sensitive silicon photonic temperature sensor based on liquid crystal filled slot waveguide directional coupler.

A highly sensitive silicon photonic temperature sensor based on silicon-on-insulator (SOI) platform has been proposed and demonstrated. A two-mode nano-slot waveguide device structure cladded with a nematic liquid crystal (LC), E7, was adopted to facilitate strong light-matter interaction and achieve high sensitivity. The fabricated sensor was characterized by measuring the optical transmission spectra at different ambient temperatures. The extracted temperature sensitivities of the E7-filled device are 0.810 nm/°C around room temperature and 1.619 nm/°C near 50°C, which match well with simulation results based on a theoretical analysis. The results obtained represent the highest experimentally demonstrated temperature sensitivity for a silicon-waveguide temperature sensor on SOI platform. The slot waveguide directional coupler device configuration provides submicron one-dimensional spatial resolution and flexible selection in LC materials for designing temperature sensitivity and operational temperature range required by specific applications.

Smart Window with Active-Passive Hybrid Control.

Dimming and scattering control are two of the major features of smart windows, which provide adjustable sunlight intensity and protect the privacy of people in a building. A hybrid photo- and electrical-controllable smart window that exploits salt and photochromic dichroic dye-doped cholesteric liquid crystal was developed. The photochromic dichroic dye causes a change in transmittance from high to low upon exposure to sunlight. When the light source is removed, the smart window returns from colored to colorless. The salt-doped cholesteric liquid crystal can be bi-stably switched from transparent into the scattering state by a low-frequency voltage pulse and switched back to its transparent state by a high-frequency voltage pulse. In its operating mode, an LC smart window can be passively dimmed by sunlight and the haze can be actively controlled by applying an electrical field to it; it therefore exhibits four optical states-transparent, scattering, dark clear, and dark opaque. Each state is stable in the absence of an applied voltage. This smart window can automatically dim when the sunlight gets stronger, and according to user needs, actively adjust the haze to achieve privacy protection.

Spatially Broadband Coupled-Surface Plasmon Wave Assisted Transmission Effect in Azo-Dye-Doped Liquid Crystal Cell.

Active tuning on a plasmonic structure is discussed in this report. We examined the transient transmission effects of an azo-dye-doped liquid crystal cell on a metallic surface grating. The transition between isotropic and nematic phases in liquid crystal generated micro-domains was shown to induce the dynamic scattering of light from a He-Ne laser, thereby allowing transmission through a non-transparent aluminum film overlaying a dielectric grating. Various grating pitches were tested in terms of transmission effects. The patterned gratings include stripe ones and circular forms. Our results indicate that surface plasmon polariton waves are involved in the transmission process. We also demonstrated how momentum diagrams of gratings and Surface Plasmon Polariton (SPP) modes combined with Mie scattering effects could explain the broadband coupling phenomenon. This noteworthy transition process could be applied to the development of spatially broadband surface plasmon polariton coupling devices.

Optical Properties of Electrically Active Gold Nanoisland Films Enabled with Interfaced Liquid Crystals.

A system comprising a gold nanoisland film (Au NIF) covered with a liquid crystal (LC) material is introduced. By applying a voltage across the LC bulk, we demonstrate that changes in the refractive-index and orientation significantly modified the hybrid plasmonic-photonic resonances of the Au NIF. The hybrid structure enabled active control of the spectrum of the resonance wavelength of the metallic nanoisland by means of an externally applied electric field. Our modeling supports the observed results in LC/Au NIF. In a combination of the nanostructured surface with birefringent LCs, nonpolarized wavelength tunability of ~15 nm and absorbance tunability of ~0.024 were achieved in the visible wavelength, opening the door to optical devices and nanoscale sensors.

Reconfiguration of three-dimensional liquid-crystalline photonic crystals by electrostriction.

Natural self-assembled three-dimensional photonic crystals such as blue-phase liquid crystals typically assume cubic lattice structures. Nonetheless, blue-phase liquid crystals with distinct crystal symmetries and thus band structures will be advantageous for optical applications. Here we use repetitive electrical pulses to reconfigure blue-phase liquid crystals into stable orthorhombic and tetragonal lattices. This approach, termed repetitively applied field, allows the system to relax between each pulse, gradually transforming the initial cubic lattice into various intermediate metastable states until a stable non-cubic crystal is achieved. We show that this technique is suitable for engineering non-cubic lattices with tailored photonic bandgaps, associated dispersion and band structure across the entire visible spectrum in blue-phase liquid crystals with distinct composition and initial crystal orientation. These field-free blue-phase liquid crystals exhibit large electro-optic responses and can be polymer-stabilized to have a wide operating temperature range and submillisecond response speed, which are promising properties for information display, electro-optics, nonlinear optics, microlasers and biosensing applications.

Bistable switching of polarization-grating diffractions enabled by a front bistable twisted nematic film.

Bistable electrical switching of high-efficiency grating diffractions is realized by adding a front π-bistable twisted nematic (π-BTN) cell to a passive liquid crystal polarization grating (LCPG). The π-BTN cell can be switched between stable non- and 180°-twisted states, acting as a polarization converter that switches the polarization of a laser beam and thus changes the diffraction behavior of the LCPG. Both states of the π-BTN cell are stable and can be reversibly switched to each other by applying a voltage pulse of different frequencies. We experimentally demonstrate two bistable-switching operations: (i) the BTN-LCPG can either split or deflect the laser beam; and (ii) the BTN-LCPG can selectively diffract the laser beam to the +1st and -1st orders, while maintaining a high diffraction efficiency of ∼90%. With electrical switchability, a simple optical design, and low power consumption, the proposed BTN-LCPG concept is favorable in various applications.

Selective variable optical attenuator for visible and mid-Infrared wavelengths.

This work demonstrates a variable optical attenuator (VOA) using dynamic scattering mode (DSM) in ion-doped liquid crystals with negative dielectric anisotropy. The mechanism of attenuation comes from optical scattering, which is generated by the electrically induced instability of undulation of LC textures. Electric fields are applied to switch the initial transparent state of the designed VOA to scattering states, varying the transmittance. The electric field also changes the size of the scattering domain from the LC texture and causes the designed device to exhibit an ultra-broadband selective operation in a visible to mid-IR spectral range. Furthermore, the VOA can selectively block one visible or mid-IR wavelength of light while letting other light pass. Such a VOA has many superior optical switching properties, such as high on/off contrast, insensitivity to polarization, and spectral selectivity; therefore, it has the potential to be used in practical optical systems.

Full-color reflector using vertically stacked liquid crystal guided-mode resonators.

In this work, we proposed a full-color reflector using three stacked red (R), green (G), and blue (B) reflection gratings which are combined with the tunable 90° twisted nematic liquid crystals (TNLCs). The color reflector based on guided-mode resonance (GMR) gratings reflects strongly at the resonance wavelength. The optical reflectivity of GMR gratings can then be controlled by using 90° TNLCs to change the polarization of incident light. The optical characteristics and the chromaticity of the designed reflectors were evaluated by simulation. An individual RGB chip with/without LC was demonstrated experimentally. The fabricated GMR reflector for red exhibits a high TE/TM polarization ratio of >10:1 and 80% optical reflectivity at resonant wavelength, while the GMR reflector for blue only allows 60% optical reflectivity and a degraded polarization ratio of 3:1 mainly due to high optical absorption of silicon. Nevertheless, the silicon-based GMR reflector enables a wide reflection bandwidth, so a full-color reflector can be realized by vertically stacking RGB tunable reflectors. The proposed full-color reflector therefore exhibits a wide-gamut color space with low driving voltage of <3 V, showing its promise for use in energy-saving reflective information systems.

Large three-dimensional photonic crystals based on monocrystalline liquid crystal blue phases.

Although there have been intense efforts to fabricate large three-dimensional photonic crystals in order to realize their full potential, the technologies developed so far are still beset with various material processing and cost issues. Conventional top-down fabrications are costly and time-consuming, whereas natural self-assembly and bottom-up fabrications often result in high defect density and limited dimensions. Here we report the fabrication of extraordinarily large monocrystalline photonic crystals by controlling the self-assembly processes which occur in unique phases of liquid crystals that exhibit three-dimensional photonic-crystalline properties called liquid-crystal blue phases. In particular, we have developed a gradient-temperature technique that enables three-dimensional photonic crystals to grow to lateral dimensions of ~1 cm (~30,000 of unit cells) and thickness of ~100 µm (~ 300 unit cells). These giant single crystals exhibit extraordinarily sharp photonic bandgaps with high reflectivity, long-range periodicity in all dimensions and well-defined lattice orientation.Conventional fabrication approaches for large-size three-dimensional photonic crystals are problematic. By properly controlling the self-assembly processes, the authors report the fabrication of monocrystalline blue phase liquid crystals that exhibit three-dimensional photonic-crystalline properties.

Broadband mid-infrared polarization rotator based on optically addressable LCs.

This work proposes a mid-infrared polarization rotator that incorporates a twisted nematic liquid crystal (TNLC) cell with a photo-controllable alignment layer. The TNLC device with a sufficient phase retardation can act as an achromic polarization rotation device over a wide wavelengths range and thus can rotate the polarization of a mid-IR laser beam. The photo-alignment technique enables TNLCs with arbitrary twisting angles to be generated by the use of visible polarized addressing light to control the directors of the photo-alignment layer. Therefore, arbitrary rotation angles of the polarization axis of a linearly polarized mid-IR laser beam can be realized. Moreover, the rewritable property and reliability of this polarization rotator are experimentally verified. The flexibility of polarization control for broadband mid-IR opens up a large range of potential mid-IR applications.

Full-color reflectance-tunable filter based on liquid crystal cladded guided-mode resonant grating.

This work proposes a tunable reflective guided-mode resonant (GMR) filter that incorporates a 90° twisted nematic liquid crystal (TNLC). The GMR grating acts as an optical resonator that reflects strongly at the resonance wavelength and as an alignment layer for LC. The 90° TNLC functions as an achromic polarization rotator that alters the polarization of incident light. The resonance wavelength and reflectance of such a filter can be controlled by setting the angle of incidence and driving the 90° TNLC, respectively. The designed filter exhibits a very large spectral shift in resonance wavelength from 710 to 430 nm, which covers the entire visible spectrum. The transmittance can be tuned to within 10 V at various resonance wavelengths. The hybrid GMR - LC filter is compact, has a simple design, and is easy to fabricated. It can therefore be used in practical applications.

All-optical transistor- and diode-action and logic gates based on anisotropic nonlinear responsive liquid crystal.

In this paper, we show that anisotropic photosensitive nematic liquid crystals (PNLC) made by incorporating anisotropic absorbing dyes are promising candidates for constructing all-optical elements by virtue of the extraordinarily large optical nonlinearity of the nematic host. In particular, we have demonstrated several room-temperature 'prototype' PNLC-based all-optical devices such as optical diode, optical transistor and all primary logic gate operations (OR, AND, NOT) based on such optical transistor. Owing to the anisotropic absorption property and the optical activity of the twist alignment nematic cell, spatially non-reciprocal transmission response can be obtained within a sizeable optical isolation region of ~210 mW. Exploiting the same mechanisms, a tri-terminal configuration as an all-optical analogue of a bipolar junction transistor is fabricated. Its ability to be switched by an optical field enables us to realize an all-optical transistor and demonstrate cascadability, signal fan-out, logic restoration, and various logical gate operations such as OR, AND and NOT. Due to the possibility of synthesizing anisotropic dyes and wide ranging choice of liquid crystals nonlinear optical mechanisms, these all-optical operations can be optimized to have much lower thresholds and faster response speeds. The demonstrated capabilities of these devices have shown great potential in all-optical control system and photonic integrated circuits.

Highly sensitive optical temperature sensor based on a SiN micro-ring resonator with liquid crystal cladding.

This work develops a sensitivity-enhanced optical temperature sensor that is based on a silicon nitride (SiN) micro-ring resonator that incorporates nematic liquid crystal (NLC) cladding. As the ambient temperature changes, the refractive index of the NLCs, which have a large thermal-optical coefficient, dramatically varies. The change in the refractive index of the NLC cladding that is caused by the temperature shift can alter the effective refractive index of the micro-ring resonator and make the resonance wavelength very sensitive to the ambient temperature. The temperature-sensitivity of the device with 5CB cladding for TM-polarized light was measured to be as high as 1nm/°C between 25 and 33 °C and over 2nm/°C at temperatures close to clearing temperature of the 5CB cladding. The temperature-sensitivity of the proposed device is at least 55 times that of the micro-ring resonator with air cladding, whose temperature-dependent wavelength shift for TM-polarized light is 18pm/ °C.

Electrically tunable high Q-factor micro-ring resonator based on blue phase liquid crystal cladding.

This work demonstrates an electrically tunable silicon nitride (SiN) micro-ring resonator with polymer-stabilized blue phase liquid crystals (PSBPLCs) cladding. An external vertical electric field is applied to modulate the refractive index of the PSBPLCs by exploiting its fast-response Kerr effect-induced birefringence. The consequent change in the refractive index of the cladding can vary the effective refractive index of the micro-ring resonator and shift the resonant wavelength. Crystalline structures of PSBPLCs with a scale of the order of hundreds of nanometers ensure that the resonator has a very low optical loss. The measured tuning range is 0.45 nm for TM polarized light under an applied voltage of 150V and the corresponding response time is in the sub-millisecond range with a Q-factor of greater than 20,000.