Engineering metal-carbide hydrogen traps in steels.

Hydrogen embrittlement reduces the durability of the structural steels required for the hydrogen economy. Understanding how hydrogen interacts with the materials plays a crucial role in managing the embrittlement problems. Theoretical models have indicated that carbon vacancies in metal carbide precipitates are effective hydrogen traps in steels. Increasing the number of carbon vacancies in individual metal carbides is important since the overall hydrogen trapping capacity can be leveraged by introducing abundant metal carbides in steels. To verify this concept, we compare a reference steel containing titanium carbides (TiCs), which lack carbon vacancies, with an experimental steel added with molybdenum (Mo), which form Ti-Mo carbides comprising more carbon vacancies than TiCs. We employ theoretical and experimental techniques to examine the hydrogen trapping behavior of the carbides, demonstrating adding Mo alters the hydrogen trapping mechanism, enabling hydrogen to access carbon vacancy traps within the carbides, leading to an increase in trapping capacity.

Predictions and Experiments on the Distortion of the 20Cr2Ni4A C-ring during Carburizing and Quenching Process.

This paper focuses on the effect of gear steel on distortion due to phase transformation in carburizing and quenching. The carburizing and quenching process of C-rings under suspension was studied by using the finite element method based on the thermo-mechanical theory, considering phase transformation. The phase transformation kinetics parameters, depending on different carbon contents, were measured by Gleeble-3500. The distortion behavior of the carburized C-ring during the cooling stage was analyzed, as well as the carbon concentration distribution and martensite volume fractions. The accuracy of the simulation was also verified by comparing the experimental data with the simulated result of the distortion and microstructure. A reliable basis is provided for predicting the distortion mechanism of gear steels in carburizing and quenching.

The scale identification associated with priority zone management of the Yangtze River Estuary.

Watershed and catchment area-based water quality management are important methods for comprehensive management of rivers and lakes. The impacts of land use/land cover (LULC) on river water quality vary with spatial scales, such as watersheds, catchments, and riparian zones. Achieving an effective spatial scale relationship between LULC and water quality, determining priority management areas, and reaching sustainable development of large estuarine deltas remain problematic. In this study, buffering analysis on the water quality data of the Yangtze River Estuary from 2009 to 2018 was conducted based on LULC, and the priority management areas of the basin were identified. Also, we infer that future river restoration or management efforts should focus on priority management area construction of a 1500 m riparian zone and a 150 km reach zone. Conclusively, establishing a priority management area within the effective buffer zone is key to watershed water quality management.

Characterization of the microstructure and hardness of case-carburized gear steel.

The microstructure and hardness of case-hardened steel were investigated after carburizing and austenitizing at 820-900 °C, and oil quenching and tempering at 180 °C. The carburized case had a multiphase microstructure consisting of martensite, carbides, and retained austenite, and the maximum content of the retained austenite was 30%; the particle size range was 2-3 µm. The nano-hardness decreased from about 12 GPa near the surface to about 7 GPa in the core, and the microhardness decreased from 800 HV0.2 to 450 HV0.2. The in-depth distribution of the microhardness and nano-hardness showed a similar trend, and the ratio of nano-hardness to microhardness was about 15. The results were attributed to the fine particle size of the retained austenite and its even distribution in the martensite matrix and it could not lower the nano-hardness. The nano-hardness was relatively low in areas of the retained austenite (about 5.5 GPa), and pop-in effects were observed, indicating the phase transformation of the retained austenite during nanoindentation loading.

Sources and ecological risk assessment of the seawater potentially toxic elements in Yangtze River Estuary during 2009-2018.

The purpose of this paper is to understand the sources of potentially toxic elements (PTE) and provide some suggestions to control PTE pollution. For this purpose, data from 30 monitoring stations for 2009-2018 were used to assess the PTE concentrations of Hg, Cu, Pb, Cd, Zn, and As in the Yangtze River Estuary. The PTE concentrations varied significantly (P < 0.05) by one-way ANOVA in the ranges of 0.002-0.224 (Hg, 0.043 ± 0.032), 0-9.700 (Cu, 1.600 ± 1.000), 0-3.900 (Pb, 1.000 ± 0.700), 0.002-0.370 (Cd, 0.050 ± 1.000), 0.100-85.000 (Zn, 14.000 ± 13.000), and 0.998-3.290 µg/L (As, 1.857 ± 0.455). Generally, the PTE concentrations decreased from year to year and were consistently satisfied the "grade-one seawater" quality standard after 2014. The concentrations of Cu, Cd, Zn, and As decreased as far from inshore, while increased closer to land in the estuary. Concentrations of Pb and Hg showed differences because of local industrial and aquacultural activities. This study identified three clusters and two PTE sources and provided some constructive suggestions for pollution control in PTE.

Theory of scale-dependent feedback: An experimental validation and its significance for coastal saltmarsh restoration.

Theory of self-organization, i.e., scale-dependent feedback (SDF), has been widely used to explain mechanisms of spatial patterns in different ecosystems. Studies have demonstrated that self-organization is one of the mechanisms through which ecosystem resilience is maintained. However, the application of SDF in real ecological restoration practices is a challenge due to the lack of a controlled experimental validation. In the present study, multiple scales of vegetation patches were constructed along an elevation gradient in the saltmarsh ecosystem on Nanhui coasts and were investigated to verify if there was an effect of SDF. Results of the density-variation curves analyses revealed that most constructed self-organized patches could survive and an optimal curve was found of which the density-dependent feedback was proven through fitting with the asymptotic regression model. The large vegetation patches exhibited considerable increases in density when compared to the small vegetation patches, which occurred in challenging environments, i.e., on the verges of elevation thresholds, and with a tendency to shrink. Analyses using one-way ANOVA revealed that there was an optimal patch scale and elevation in the study area, i.e., 1 m × 1 m scale and 3.2 m, respectively. Optimal scale and elevation provide a comprehensively explanations of SDF, although with the positive effects gradually decreased along the distance away from the optimal condition. The present study provides novel insights on applying the theory of SDF in facilitating the restoration process of coastal saltmarshes.