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1.
J Fluoresc ; 30(3): 679-685, 2020 May.
Article in English | MEDLINE | ID: mdl-32367338

ABSTRACT

Chirality plays a very important role in medicine, biochemistry and other fields. Because the enantiomers of chiral drugs often show different pharmacology activity, metabolism, and toxicity, therefore, the recognition of chiral molecules is very important, and has become a hot spot and frontier of modern chemical research. In this paper, a new method for recognizing chiral molecular based on naphthalimide dye(NA)⊂cucurbit[5]uril(CB[7]) assembly is developed. NA as guest can be combined with the host CB[7] to form a 1:1 NA⊂CB[7] assembly. Furthermore, this assembly was used as a fluorescent probe to recognize D/L-phenylalanine and D/L-phenylalaninol by fluorescence titration. When D-phenylalanine or D-phenylalaninol was added to NA⊂CB[7] assembly, the fluorescent intensity of assembly was partially quenched, but when L-phenylalanine or L-phenylalaninol was added to NA⊂CB[7], the fluorescence intensity of the assembly almost unchanged. Herein, chiral recognition platform based on achiral NA⊂achiral CB[7] was constructed.


Subject(s)
Bridged-Ring Compounds/chemistry , Fluorescent Dyes/chemistry , Imidazoles/chemistry , Naphthalimides/chemistry , Phenylalanine/analogs & derivatives , Phenylalanine/analysis , Fluorescent Dyes/chemical synthesis , Molecular Conformation , Stereoisomerism
2.
Opt Lett ; 42(1): 171-174, 2017 Jan 01.
Article in English | MEDLINE | ID: mdl-28059206

ABSTRACT

We have experimentally investigated spatial-division multiplexed (SDM) Brillouin optical time-domain analysis in a heterogeneous multicore fiber whose central core and six outer cores are made from different preforms, showing a ∼70 MHz Brillouin frequency shift (BFS) difference between them. It reveals that the heterogeneous central core and the outer cores have different temperature sensitivities, but their strain sensitivities are almost the same. By making use of the distinct temperature coefficients of these two kinds of cores, simultaneous and discriminative temperature and strain measurements are achieved. The bending-induced Brillouin gain spectrum (BGS) broadening issue in off-center cores has been clarified, and a solution has been proposed to eliminate the uncertainty caused by a bending-induced BFS shift, by averaging the BFS variations of two symmetrical outer cores. We show a new perspective for discriminative measurement in Brillouin distributed sensors based on SDM solutions.

3.
Opt Lett ; 41(7): 1514-7, 2016 Apr 01.
Article in English | MEDLINE | ID: mdl-27192275

ABSTRACT

We proposed and demonstrated a few-mode fiber (FMF) based optical-fiber sensor for distributed curvature measurement through quasi-single-mode Brillouin frequency shift (BFS). By central-alignment splicing FMF and single-mode fiber (SMF) with a fusion taper, a SMF-components-compatible distributed curvature sensor based on FMF is realized using the conventional Brillouin optical time-domain analysis system. The distributed BFS change induced by bending in FMF has been theoretically and experimentally investigated. The precise BFS response to the curvature along the fiber link has been calibrated. A proof-of-concept experiment is implemented to validate its effectiveness in distributed curvature measurement.

4.
Opt Express ; 24(8): 8978-87, 2016 Apr 18.
Article in English | MEDLINE | ID: mdl-27137328

ABSTRACT

We have demonstrated a new approach for developing very large mode area silica-based microstructured Ytterbium (Yb)-doped fibers. The microstructured region acting as pump cladding around the core is composed by periodically arranged low-index Fluorine-doped silica inclusions with an extremely low filling ratio of 0.088. To the best of our knowledge, we achieved the most accurate controlling on cladding index by 1 × 10-5 via our passively doped cladding (PDC) method. Two fibers with 127µm and 50µm core diameter respectively were fabricated from the same final preform designed by this approach. It is verified that our 50µm core diameter fiber can maintain robust single mode behavior at 1064nm wavelength. The advantage of an all-solid structure along with a much simpler fabrication process makes our approach very suitable for realizing very large mode area fibers for high power fiber laser application.

5.
Opt Express ; 23(26): 33001-7, 2015 Dec 28.
Article in English | MEDLINE | ID: mdl-26831968

ABSTRACT

We report on a compact sensor by integrating a Mach-Zehnder interference and a cladding Bragg grating in a same section of all-solid photonic bandgap fiber. Theoretical investigation reveals that the Bragg grating resonance stems from the coupling of counter-propagating cladding LP01-like supermodes and the Mach-Zehnder interference works between a LP01-like supermode and LP01 core mode. Compared with the interference fringe, such supermode grating dip responses to axial strain in a more sensitive and opposite-direction manner. Whereas, the interference fringe shows a higher temperature sensitivity than the supermode grating dip. By means of these different responses, this device finds a useful application in the discrimination of temperature and axial strain.

6.
Opt Express ; 22(22): 27515-23, 2014 Nov 03.
Article in English | MEDLINE | ID: mdl-25401898

ABSTRACT

A temperature compensated magnetic field strength optical fiber sensor has been proposed and experimentally demonstrated. A fiber Bragg grating (FBG) is cascaded to modal interferometer (MI), which is fabricated by dual S-bend splicing between thin fiber (TF) and single mode fiber (SMF) with intentionally controlled misalignment between cores. We established a modified numerical model to describe the multi-mode interference of this exceptional S-bend and misalignment structure, together with the simulation based on beam propagation method to gain insight into its operation mechanism. The FBG is used to interrogate the temperature change, and then compensate the perturbation of temperature on transmission of the MI. Thanks to the proposed dual S-bend structure and the diameter-thinned TF used here; we have obtained high magnetic sensitivity of -0.0678 dB/Oe using only 4 mm TF after the elimination of ambient temperature change.

7.
Opt Express ; 22(12): 14127-34, 2014 Jun 16.
Article in English | MEDLINE | ID: mdl-24977511

ABSTRACT

The mitigation of both crosstalk and its wavelength dependent sensitivity for homogeneous multicore fiber (MCF) is theoretically investigated using an analytical evaluation approach. It is found there exists a performance trade-off between the crosstalk mitigation and its wavelength dependent sensitivity suppression. After characterizing the fabricated homogeneous MCFs, we verify that although the increasing core pitch can mitigate the crosstalk, the wavelength dependent sensitivity is drastically degraded from 0.07dB/nm to 0.11dB/nm, which is harmful to the dense wavelength division multiplexing (DWDM) transmission over C + L band using MCF.

8.
Opt Express ; 22(3): 2675-80, 2014 Feb 10.
Article in English | MEDLINE | ID: mdl-24663559

ABSTRACT

We propose a new technique to perform precise selective infiltration of an air hole in the photonic crystal fiber (PCF). To carry out the infiltration process, the end face of the PCF is covered by a mask, which is fabricated by femtosecond laser inscription from the lateral direction. This proposed method overcomes the conventional limitation of maximum mask thickness. An analytical model is further proposed and demonstrated accurate determinations of the fabricated channel diameter in the mask.

9.
Opt Express ; 21(20): 23812-21, 2013 Oct 07.
Article in English | MEDLINE | ID: mdl-24104292

ABSTRACT

A novel, simple, and compact optical fiber directional bending vector sensor based on Mach-Zehnder interferometer (MZI) is proposed and experimentally demonstrated. The device consists of a piece of seven-core photonic crystal fiber (PCF) sandwiched between two single mode fibers (SMFs) with a lateral offset splicing joint that covering two cores of PCF. Bending sensitivity of the seven-core PCF based MZI is changed by an axial rotation angle, which shows its capacity for recognizing positive and negative directions. Within a curvature range of -7.05 m-1 to 7.05 m-1, the calculated bending sensitivities of two resonant central wavelengths with opposite fiber orientations are 1.232 nm/m-1 and 1.174 nm/m-1, respectively. This novel MZI is formed by invoking interference between the LP01-like supermode and other higher order supermodes in the core, which leads to insensitive to ambient refractive index (ARI). We have also investigated the transmission characteristics of the sensor with the temperature change.

10.
Opt Lett ; 38(3): 269-71, 2013 Feb 01.
Article in English | MEDLINE | ID: mdl-23381407

ABSTRACT

A temperature-insensitive micro Fabry-Pérot (FP) cavity based on simplified hollow-core (SHC) photonic crystal fiber (PCF) is demonstrated. Such a device is fabricated by splicing a section of SHC PCF with single mode fibers at both cleaved ends. An extremely low temperature sensitivity of ~0.273 pm/°C is obtained between room temperature and 900°C. By drilling vertical micro-channels using a femtosecond laser, the micro FP cavity can be filled with liquids and functions as a sensitive refractometer and the refractive index sensitivity obtained is ~851.3 nm/RIU (refractive index unit), which indicates an ultra low temperature cross-sensitivity of ~3.2×10(-7) RIU/°C.

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