Advanced Optical Information Encryption Enabled by Polychromatic and Stimuli-Responsive Luminescence of Sb-Doped Double Perovskites.

The smart materials with multi-color and stimuli-responsive luminescence are very promising for next generation of optical information encryption and anti-counterfeiting, but these materials are still scarce. Herein, a multi-level information encryption strategy is developed based on the polychromatic emission of Sb-doped double perovskite powders (SDPPs). Cs2NaInCl6:Sb, Cs2KInCl6:Sb, and Cs2AgInCl6:Sb synthesized through coprecipitation methods exhibit broadband emissions with bright blue, cyan, and orange colors, respectively. The information transmitted by specific SDPP is encrypted when different SDPPs are mixed. The confidential information can be decrypted by selecting the corresponding narrowband filter. Then, an encrypted quick response (QR) code with improved security is demonstrated based on this multi-channel selection strategy. Moreover, the three types of SDPPs exhibit three different water-triggered luminescence switching behaviors. The confidential information represented by Cs2NaInCl6:Sb can be erased/recovered through a simple water spray/drying. Whereas, the information collected from the green channel is permanently erased by moisture, which fundamentally avoids information leakage. Therefore, different encryption schemes can be designed to meet a variety of encryption requirements. The multicolor and stimuli-responsive luminescence greatly enrich the flexibility of optical information encryption, which leaps the level of security and confidentiality.

Room-Temperature High-Performance Photodetector and Phototransistor Based on PdSe2/ZnIn2S4 Alloy Heterojunctions.

Various semiconductor devices have been developed based on 2D heterojunction materials owing to their distinctive optoelectronic properties. However, to achieve efficient charge transfer at their interface remains a major challenge. Herein, an alloy heterojunction concept is proposed. The sulfur vacancies in ZnIn2S4 are filled with selenium atoms of PdSe2. This chemically bonded heterojunction can significantly enhance the separation of photocarriers, providing notable advantages in the field of photoelectric conversion. As a demonstration, a two-terminal photodetector based on the PdSe2/ZnIn2S4 heterojunction materials is fabricated. The photodetector exhibits stable operation in ambient conditions, showcasing superior performance in terms of large photocurrent, high responsivity (48.8 mA W-1) and detectivity (1.98 × 1011 Jones). To further validate the excellent optoelectronic performance of the heterojunction, a tri-terminal phototransistor is also fabricated. Benefiting from gate voltage modulation, the photocurrent is amplified to milliampere level, and the responsivity is increased to 229.14 mA W-1. These findings collectively demonstrate the significant potential of the chemically bonded PdSe2/ZnIn2S4 alloy heterojunction for future optoelectronic applications.

Co-multiplexing spectral and temporal dimensions based on luminescent materials.

Optical multiplexing is a pivotal technique for augmenting the capacity of optical data storage (ODS) and increasing the security of anti-counterfeiting. However, due to the dearth of appropriate storage media, optical multiplexing is generally restricted to a single dimension, thus curtailing the encoding capacity. Herein, the co-multiplexing spectral and temporal dimensions are proposed for optical encoding based on photoluminescence (PL) and persistent-luminescence (PersL) at four different wavelengths. Each emission color comprises four luminescence modes. The further multiplexing of four wavelengths leads to the maximum encoding capacity of 8 bits at each pixel. The wavelength difference between adjacent peaks is larger than 50 nm. The well-separated emission wavelengths significantly lower the requirements for high-resolution spectrometers. Moreover, the information is unable to be decoded until both PL and PersL spectra are collected, suggesting a substantial improvement in information security and the security level of anti-counterfeiting.

Design of a dynamic multi-topological charge graphene orbital angular momentum metalens.

Traditional OAM generation devices are bulky and can generally only create OAM with one specific topological charge. Although metasurface-based devices have overcome the volume limitations, no tunable metasurface-based OAM generators have been demonstrated to date. Here, a dynamically tunable multi-topological charge OAM generator based on an ultrathin integrable graphene metalens is demonstrated by simulation using the detour phase technique and spatial multiplexing. Different topological charges can be designed on different focal planes. Stretching the OAM graphene metalens allows the focal plane and the topological values to be changed dynamically. This design method paves an innovative route toward miniaturization and integrating OAM beam-type photonic devices for practical applications.

Effect of the focused gap-plasmon mode on tip-enhanced Raman excitation and scattering.

As a powerful molecular detection approach, tip-enhanced Raman scattering (TERS) spectroscopy has the advantages of nanoscale spatial resolution, label-free detection and high enhancement factor, therefore has been widely used in fields of chemistry, materials and life sciences. A TERS system enhanced by the focused gap-plasmon mode composed of Surface Plasmon Polariton (SPP) focus and the metal probe has been reported, however, its underlying enhancement mechanism for Raman excitation and scattering remains to be deeply explored. Here, we focus on the different performances of optical focus and SPP focus in the TERS system, and verify that the cooperation of these two focuses can produce maximum enhancement in a local electromagnetic field. Further, the Purcell effect on sample scattering in such a system is studied for the enhancement of Raman scattering collection in the far field. Finally, the local field enhancement and the sample far-field scattering enhancement are combined to show a full view of the whole process of TERS enhancement. This research can be applied to optimize the excitation and collection of Raman signals in TERS systems, which is of great value for the research and development of TERS technology.

Gelation properties and protein conformation of grass carp fish ball as influenced by egg white protein.

Dried egg white powder (EWP) and purified ovalbumin (OVA, 98%) were used as supplements to improve grass carp (GC) fish balls (FB) quality. The effects of EWP and/or OVA contents on the gel strength, water holding capacity (WHC), moisture migration and distribution, and rheological properties of GC-FB, as well as on myofibrillar protein (MfP) structures in the GC-FB were evaluated. The results showed that with the increase of EWP addition from 0 to 4% (w/w), the gel strength, and WHC of the GC-FB samples were increased from 34.28 to 66.63 N × mm, and 83.02 to 88.36%, respectively, but the increases were insignificant between 3 and 4% EWP-added GC-FBs (p > .05). As the EWP increased, the T2 relaxation time shifted toward lower values, indicating a general decline in water mobility. The effects of EWP on rheological properties were insignificant. Addition of OVA and/or EWP led to changes in secondary structural units in the FB, with α-helix (27.53%) reaching the highest value in OVA-added GC-FB, ß-sheet (46.07%) reaching the highest value in GC-FB, and ß-turn (33.54%) reaching the highest value in EWP-added GC-FB, respectively. Raman spectroscopy revealed that OVA-added GC-FB had the lowest hydrophobic interlinkages. Protein pattern analysis suggested that the OVA (1.58%) might contribute to the decrease in the myosin heavy chain band intensity through cross-linked with MfP. These results suggested that EWP could improve the quality of GC-FBs and OVA played an important role with MfP gelation.

A Varifocal Graphene Metalens for Broadband Zoom Imaging Covering the Entire Visible Region.

The ever-increasing demand for miniaturized optical systems has placed stringent requirements on the core element: lenses. Developing ultrathin flat lenses with a varifocal capability and broadband spectral response is critical for diverse applications, but remains challenging and has been the focus of intensive research. The recent demonstration of tunable focal length for a single wavelength with metalenses marked an important milestone for transforming the complex and bulky tunable lens kit into a single flat lens. However, achieving color imaging with desired tunability over the entire visible spectrum essential for practical applications still remains elusive. Here we propose and demonstrate experimentally a broadband varifocal graphene metalens (250 nm in thickness) covering the entire visible spectrum. It is able to simultaneously tune the focal lengths for different wavelengths continuously. By laterally stretching the lens, an over 20% focal length tuning range can be achieved for red (650 nm), green (550 nm), and blue (450 nm) light as three example wavelengths. Zoom imaging of different objects located along the axial direction has been demonstrated at these wavelengths by simply controlling the stretch ratio of the graphene metalens. This broadband graphene zoom lens enables enormous applications in miniaturized imaging devices such as cell phones, wearable displays, and compact optical or communication systems with multi-color-channel functionalities.

Active sorting of orbital angular momentum states of light with a cascaded tunable resonator.

The orbital angular momentum (OAM) of light has been shown to be useful in diverse fields ranging from astronomy and optical trapping to optical communications and data storage. However, one of the primary impediments preventing such applications from widespread adoption is the lack of a straightforward and dynamic method to sort incident OAM states without altering the states. Here, we report a technique that can dynamically filter individual OAM states and preserve the incident OAM states for subsequent processing. Although the working principle of this technique is based on resonance, the device operation is not limited to a particular wavelength. OAM states with different wavelengths can resonate in the resonator without any additional modulation other than changing the length of the cavity. Consequently, we are able to demonstrate a reconfigurable OAM sorter that is constructed by cascading such optical resonators. This approach does not require specially designed components and is readily amenable to integration into potential applications.

Data on the preparation of chitosan-tripolyphosphate nanoparticles and its entrapment mechanism for egg white derived peptides.

The data article refers to the paper "A study on the preparation of chitosan-tripolyphosphate nanoparticles and its entrapment mechanism for egg white derived peptides" [1]. Data presented here include impact factors (chitosan molecular weights, pH values, chitosan-tripolyphosphate mass ratio, and chitosan concentration) on the preparation and colloidal properties of chitosan-tripolyphosphate nanoparticles. Data also refer to the effect of impact factors (chitosan molecular weight, chitosan concentration, peptides-chitosan mass ratio and pH values) on the entrapment efficiency and entrapment capacity of chitosan-tripolyphosphate nanoparticles loading with egg white derived peptides. Data also involve the size and zeta potential change after the egg white derived peptides entrapped in chitosan-tripolyphosphate nanoparticles. Additionally, data exhibit the free amino group and surface hydrophobicity of egg white derived peptides with different molecular weights.

Visualization and measurement of the local absorption coefficients of single bilayer phospholipid membranes using scanning near-field optical microscopy.

Here we report the results of shear-mode thicknesses and absorption coefficient measurements made on neat membranes using scanning near-field optical microscopy (SNOM). Biomimic neat membranes composed of two different types of phoshpholipid molecules: 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 1,2- dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) were found to exhibit different absorption coefficients under the SNOM. The localization of the lipids could be identified and correlated to the morphology of the membrane domains indicating that SNOM can be an effective and accurate approach for the label-free characterization of the structure-function relationships in cell membranes.

Spin-orbit coupling controlled near-field propagation and focusing of Bloch surface wave.

Bloch surface wave (BSW) can be considered as the dielectric analogue of surface plasmon polariton (SPP) with less loss since it is sustained at the surface of a truncated dielectric multilayer. As dielectric materials show nearly no ohmic loss, BSW can propagates much farther compared to SPP, and thus is beneficial for planar optical devices. In this paper, we study the spin-orbital interaction between incident beam and BSW. We demonstrate that due to the spin-orbital coupling, the near-field properties of generated BSW can be controlled with a meta-antenna structure. The meta-antenna is composed of two gold nano-antennas oriented at 45° and 135° as a near-field coupler. By careful design of the meta-antenna, the generated BSW can be guided and focused depending on the chirality of the incident beam. Three examples of meta-antennas are demonstrated for chiral sensitive focusing, directional switching and asymmetric focusing. The proposed method can be applied as a design method for low-loss on-chip photonic devices.

Resilient Graphene Ultrathin Flat Lens in Aerospace, Chemical, and Biological Harsh Environments.

The development of ultrathin flat lenses has revolutionized the lens technologies and holds great promise for miniaturizing the conventional lens system in integrated photonic applications. In certain applications, the lenses are required to operate in harsh and/or extreme environments, for example aerospace, chemical, and biological environments. Under such circumstances, it is critical that the ultrathin flat lenses can be resilient and preserve their outstanding performance. However, the majority of the demonstrated ultrathin flat lenses are based on metal or semiconductor materials that have poor chemical, thermal, and UV stability, which limit their applications. Herein, we experimentally demonstrate a graphene ultrathin flat lens that can be applied in harsh environments for different applications, including a low Earth orbit space environment, strong corrosive chemical environments (pH = 0 and pH = 14), and biochemical environment. The graphene lenses have extraordinary environmental stability and can maintain a high level of structural integrity and outstanding focusing performance under different test conditions. Thus, it opens tremendous practical application opportunities for ultrathin flat lenses.

Broadband High-Efficiency Chiral Splitters and Holograms from Dielectric Nanoarc Metasurfaces.

Simultaneous broadband and high efficiency merits of designer metasurfaces are currently attracting widespread attention in the field of nanophotonics. However, contemporary metasurfaces rarely achieve both advantages simultaneously. For the category of transmissive metadevices, plasmonic or conventional dielectric metasurfaces are viable for either broadband operation with relatively low efficiency or high efficiency at only a selection of wavelengths. To overcome this limitation, dielectric nanoarcs are proposed as a means to accomplish two advantages. Continuous nanoarcs support different electromagnetic resonant modes at localized areas for generating phase retardation. Meanwhile, the geometric nature of nanoarc curvature endows the nanoarcs with full phase coverage of 0-2π due to the Pancharatnam-Berry phase principle. Experimentally incorporated with the chiral-detour phase principle, a few compelling functionalities are demonstrated, such as chiral beamsplitting, broadband holography, and helicity-selective holography. The continuous nanoarc metasurfaces prevail over plasmonic or dielectric discretized building block strategies and the findings lead to novel designs of spin-controllable metadevices.

A study on the preparation of chitosan-tripolyphosphate nanoparticles and its entrapment mechanism for egg white derived peptides.

The entrapment of peptides can effectively improve their bioavailability and commercial application. This research sought to investigate the mechanism of entrapment of egg white derived peptides (EWDP) loaded in chitosan-tripolyphosphate (CS-TPP) nanoparticles (NPs). It was shown that CS molecular weight (MW), pH, CS-TPP mass ratio and CS concentration can all affect the size, polydispersity index and zeta potential of CS-TPP NPs. Moreover, these factors, as well as different MW and CS mass ratio of peptides also had an influence on entrapment efficiency (EE). Furthermore, peptides influenced the zeta potential after they were loaded in the CS-TPP NPs. This suggested that the peptide charged groups were in different locations relative to the CS-TPP NPs surfaces. FTIR analysis indicated that the peptides interacted with CS-TPP NPs through strong hydrogen bonds and electrostatic interactions. These findings are important for designing delivery systems used for commercial production of entrapped peptides with enhanced attributes.

Angular-momentum nanometrology in an ultrathin plasmonic topological insulator film.

Complementary metal-oxide-semiconductor (CMOS) technology has provided a highly sensitive detection platform for high-resolution optical imaging, sensing and metrology. Although the detection of optical beams carrying angular momentum have been explored with nanophotonic methods, the metrology of optical angular momentum has been limited to bulk optics. We demonstrate angular-momentum nanometrology through the spatial displacement engineering of plasmonic angular momentum modes in a CMOS-compatible plasmonic topological insulator material. The generation and propagation of surface plasmon polaritons on the surface of an ultrathin topological insulator Sb2Te3 film with a thickness of 100 nm is confirmed, exhibiting plasmonic figures of merit superior to noble metal plasmonics in the ultraviolet-visible frequency range. Angular-momentum nanometrology with a low crosstalk of less than -20 dB is achieved. This compact high-precision angular-momentum nanometrology opens an unprecedented opportunity for on-chip manipulation of optical angular momentum for high-capacity information processing, ultrasensitive molecular sensing, and ultracompact multi-functional optoelectronic devices.

Toward broadband, dynamic structuring of a complex plasmonic field.

The ability to tailor a coherent surface plasmon polariton (SPP) field is an important step toward many new opportunities for a broad range of nanophotonic applications. Previously, both scanning a converging SPP spot and designing SPP profiles using an ensemble of spots have been demonstrated. SPPs, however, are normally excited by intense, coherent light sources, that is, lasers. Hence, interference between adjacent spots is inevitable and will affect the overall SPP field distributions. We report a reconfigurable and wavelength-independent platform for generating a tailored two-dimensional (2D) SPP field distribution by considering the coherent field as a whole rather than as individual spots. With this new approach, the inherent constraints in a 2D coherent field distribution are revealed. Our design approach works not only for SPP waves but also for other 2D wave systems such as surface acoustic waves.

Generation and detection of broadband multi-channel orbital angular momentum by micrometer-scale meta-reflectarray.

We theoretically demonstrate the generation and detection of broadband multi-channel Orbital Angular Momentum(OAM) by a micrometer-scale meta-reflectarray. The meta-reflectarray composed of patterned silicon bars on a silver ground plane can be designed to realize phase modulation and work as chip-level OAM devices. Compared to traditional methods of OAM generation and detection, our approach shows superiorities of very compact structure size, broadband working wavelength (1250-1750 nm), high diffraction efficiency (~70%), simultaneously handling multiplex OAMs, and tunable reflection angle (0-45°). These fascinating advantages provides great potential applications in photonic integrated devices and systems for high-capacity and multi-channel OAM communication.

Sub-100nm resolution PSIM by utilizing modified optical vortices with fractional topological charges for precise phase shifting.

We demonstrate an all-optical plasmonic structured illumination microscopy (PSIM) technique. A set of plasmonic standing-wave patterns is excited by amplitude-modified optical vortices (OVs), which have fractional topological charges for precise phase shift of {-2π/3, 0, 2π/3}. A specially designed optical aperture is introduced to modify the OVs in order to improve the uniformity of interference patterns. The imaging results of fluorescent beads reveal a sub-100nm resolving capability in aqueous environment. This PSIM technique as a structure-free, wide-field and super-resolved imaging technique is of great potential for low-cost biological dynamic imaging applications.

Dynamic cosine-Gauss plasmonic beam through phase control.

We carry out an approach to dynamic manipulation of a nondiffracting cosine-Gauss plasmonic beam (CGPB) illuminated with an incident phase modulation within nanostructures by a spatial light modulator (SLM). By changing the hologram addressed on the SLM, dynamic control on the lobe width and the propagating direction of the CGPB is experimentally verified. Finally, we demonstrate an application example of this dynamic CGPB in routing optical signals to multichannel subwavelength wave guides through numerical simulation.

Plasmonic petal-shaped beam for microscopic phase-sensitive SPR biosensor with ultrahigh sensitivity.

Differential phase measurement between radially polarized (RP) and azimuthally polarized (AP) beams is an important technique in microscopic surface plasmon resonance (SPR) biosensors as reported in our earlier works [Opt. Lett.37, 2091 (2012); Appl. Phys. Lett.102, 011114 (2013)]. However, such a technique suffers complex beam splitting, detection, and data processing procedures for RP and AP beams which may lower the accuracy of phase measurement. In this Letter, a novel plasmonic petal-shaped vector beam is proposed instead of RP and AP beams, greatly simplifying the sensor system and enabling single measurement in differential interferometry. Moreover, an improved ultrahigh sensitivity on the order of 10(-7) refractive index units (RIUs) is experimentally verified in the proposed system.