A large and overlooked Cd source in karst areas: The migration and origin of Cd during soil formation and erosion.

There is increasing concern regarding the substantial enrichment of Cd during the weathering of carbonate rocks and subsequent risks posed to the ecological environment and food security in karst areas. However, the incomplete understanding of Cd migration mechanisms and material sources restricts soil pollution control and land management. This study investigated the migration regulation of Cd during soil formation and erosion in karst areas. The results demonstrate that soil Cd concentration and bioavailability are both significantly higher in alluvium compared with those in eluvium. This increase is primarily attributed to the chemical migration of active Cd, rather than the mechanical migration of inactive Cd. Additionally, we analyzed the Cd isotopic characteristics of rock and soil samples. The isotopic composition of the alluvial soil was -0.18 ‰ ± 0.01 ‰, which is obviously heavier than the δ114/110Cd value of the eluvium (-0.78 ‰ ± 0.06 ‰). The Cd isotopic fingerprint revealed that the active Cd in the alluvium of the study profile was probably derived from the corrosion of carbonate rocks rather than by eluviation of the eluvium. Moreover, Cd tends to occur in soluble mineral components of carbonate rocks rather than in residues, which suggests that carbonate weathering has a great potential to release active Cd into the environment. It is estimated that the Cd release flux caused by carbonate weathering is 5.28 g Cd km-2 yr-1, accounting for 9.30 % of the anthropogenic Cd flux. Therefore, the corrosion of carbonate rocks is a substantial natural Cd source and poses significant potential risks to the ecological environment. It is suggested that the contribution of Cd from natural sources should be considered during ecological risk assessments and studies of the global Cd geochemical cycle.

Geochemical characteristics of heavy metals of bedrock, soil, and tea in a metamorphic rock area of Guizhou Province, China.

Through field surveys, sampling, and laboratory experiments, the content, enrichment, and migration characteristics of heavy metals in the rock-soil-tea system in the Guizhou metamorphic rock area were analyzed herein. The results show that the As and Hg contents in metamorphic sandstone in the study area are higher than those in slate, while the Mn, Zn, Pb, and Ni contents in slate are higher. The content of heavy metals in the sandstone of the Jialu formation of the Xiajiang group in Neoproterozoic is the highest, and that of the slate of the Fanzhao formation is the lowest. The content of As in the rock samples in the study area is higher than that in the Epicontinental crust, while Cd is found to be deficient. The heavy metals at some soil points exceed the standard, but this does not affect the growth and development of tea. The content of heavy metals in most tea is lower than the safety limit standards, and the THQ value is less than 1, indicating that the heavy metals in tea in Guizhou metamorphic rock areas pose no concern for human health. In the metamorphic rock distribution areas of Guizhou, tea does not enrich As, Cr, Hg, and Pb in soil, but enriches Mn, Cu, Ni, and Zn to varying degrees, with the enrichment of Mn being the strongest.

Tracing the Origins of Blueberries by Their Mineral Element Contents and 87Sr/86Sr Ratios.

This study investigated the feasibility of using the mineral element contents and 87Sr/86Sr ratios of blueberries to trace their origins. The contents of 28 mineral elements, including K, Al, and Mg, were determined in 104 blueberry samples from three blueberry-producing areas in Guizhou Province, China. Also determined were both the 87Sr/86Sr ratios in 48 blueberry samples as well as the type of soil in which the blueberries were grown. Cluster analysis of 87Sr/86Sr ratios, stepwise discriminant analysis of mineral element contents, and combined discriminant analyses of 87Sr/86Sr ratios and mineral element contents were done. The results show that ten elements (Ca, Cr, Cs, Mg, Mn, P, Rb, Sb, Th, and Y) were selected by linear discriminant analysis, which could be used to establish the provenance traceability model of blueberries in Guizhou. The original accuracy of linear discriminant analysis was 89.4%, and the accuracy of cross-validation was 83.6%. When 87Sr/86Sr ratios were used for tracing, the accuracies of both the original discrimination and the cross-validation were 81.3% as determined by linear discriminant analysis, and the accuracy rate of origin discrimination was 81.25% by cluster analysis. The results of combined discrimination were the best: the accuracy of the original discrimination was 95.8%, and the accuracy of cross-validation was 93.8%. Mineral element contents and 87Sr/86Sr ratios can be used to trace the origins of blueberries, and combining them can significantly improve the discrimination accuracy. Fisher linear discriminant analysis had the greatest accuracy followed by cluster analysis, while principal component analysis was relatively poor in the research of Guizhou blueberry origin traceability.

Geochemical Characteristics of Heavy Metals in Soil and Blueberries of the Core Majiang Blueberry Production Area.

By using field survey, sampling, and indoor analysis, we analyzed the geochemical characteristics of heavy metals in the blueberries and soil of the core blueberry production area of Majiang in Guizhou, China. Analyses were based on national standards for soil pollution risk control on agricultural land (GB15618-2018) and pollution index limits in food (GB2762-2017/2012). The results demonstrated that heavy metal content in the soil profile of this area exceeds standards, but standards were exceeded mainly in the lower layer of the profile, and blueberry growth was not substantially affected. Except for in Lanmenggu, heavy metals in the cultivation soil layer of Majiang Blueberry Farms did not considerably exceed standards. The content of heavy metals in blueberry did not exceed the standard, so it was a safe fruit. These results can provide a reference for the safe cultivation of Majiang blueberries.

Distribution, accumulation, and potential risks of heavy metals in soil and tea leaves from geologically different plantations.

Risk assessment regarding heavy metals in tea is crucial to ensure the health of tea customers. However, the effects of geological difference on distribution of heavy metals in soils and their accumulation in tea leaves remain unclear. This study aimed to estimate the impacts of geological difference on distribution of cadmium (Cd), lead (Pb), thallium (Tl), mercury (Hg), arsenic (As), antimony (Sb), chromium (Cr), nickel (Ni), and manganese (Mn) in soils and their accumulation in tea leaves, and further evaluate their health risks. 22 soils and corresponding young tea leaves (YTL) and old tea leaves (OTL), from geologically different plantations, were sampled and analyzed. Results showed that heavy metals concentrations in soils, derived from Permian limestone and Cambrian weakly mineralized dolomite, were obviously greater than those from Silurian clastic rock. The geological difference controlled the distribution of soil heavy metals to a large extent. Contents of Cd, Tl, and Mn in tea leaves mainly depended on their contents in soils. Soil Hg, Pb, As, and Sb contents may not be the only influencing factors for their respective accumulation in tea leaves. More attentions should be paid to soil acidification of tea plantations to ensure the tea quality security. Target hazard quotients (THQ) of Cd, Pb, Tl, Hg, As, Sb, Cr, and Ni and hazard index (HI) via tea intake were below one, indicating no human health risk. The non-mineralized Silurian area was less at risk of heavy metals accumulation in tea leaves than the Cambrian metallogenic belt and the Permian Cd-enriched zone. This study could provide an important basis to understand and mitigate the potential risks of heavy metals in tea.

Use of mineral multi-elemental analysis to authenticate geographical origin of different cultivars of tea in Guizhou, China.

BACKGROUND: The geographical origin of tea (Camellia sinensis) can be traced using mineral elements in its leaves as fingerprints. However, the role that could be played by soil mineral elements in the geographical authentication of tea leaves has been unclear. In this study, 22 mineral elements in 73 pairs of tea leaves and soils from three regions (Pu'an, Duyun, and Liping) in Guizhou, China, were determined using inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES). The mineral element concentrations were processed by multivariate statistical analysis, including one-way analysis of variance (ANOVA), correlation analysis, principal component analysis (PCA), and stepwise linear discriminant analysis (S-LDA). RESULTS: Based on a one-way ANOVA, tea leaves and soils with different origins possessed unique mineral element fingerprints. Sixteen mineral element concentrations in tea leaves were significantly correlated with those in soils (P < 0.05). The geographical origins of tea leaves were effectively differentiated using the 16 correlated mineral elements combined with PCA. The S-LDA model offered a 100% differentiation rate, and six indicative elements (phosphorus, Sr, U, Pb, Cd, and Cr) were selected as important fingerprinting markers for the geographic traceability of tea leaves. The accurate discrimination rate of geographical origin was unaffected by the cultivars of tea in the S-LDA model. CONCLUSIONS: Mineral elements in soils played an important role in the geographical authentication of tea leaves. Mineral elemental concentrations with significant correlations between tea leaves and soils could be robust, and could be used to trace the geographical origins of tea leaves. © 2020 Society of Chemical Industry.

Geographical origin discrimination of pepper (Capsicum annuum L.) based on multi-elemental concentrations combined with chemometrics.

The concentrations of twenty-four elements in twenty-five peppers from three cultivated regions in Guizhou Province (China) were analyzed. The chemometric data processing, including one-way analysis of variance, principal component analysis, linear discriminant analysis (LDA), and orthogonal partial least squares discriminant analysis (OPLS-DA) were executed to differentiate the peppers. Consequently, the contents of 16 elements (Arsenic, Ba, Cu, Co, Cr, Ni, Pb, Sn, Sb, Mo, Sr, Y, Zn, Ca, P, and Fe) were significantly different among the three regions (p < 0.05). The correct discrimination rates of 25 peppers were 92.0% for LDA and 96.0% for OPLS-DA. The variable importance in the projection (VIP) values were ranged from 1.063 to 1.262 for seven elements (Tin, Fe, Zn, Y, Cr, Sr, and Mo) indicating that they played an important role for the geographical origin traceability of pepper. To sum up, multi-element concentrations together with chemometric data-processing can be promising for the geographical origin differentiation of pepper.

Accumulation of Heavy Metals in Tea Leaves and Potential Health Risk Assessment: A Case Study from Puan County, Guizhou Province, China.

This study features a survey of the concentrations of aluminum (Al) and heavy metals (Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn) in tea leaves and the corresponding cultivation soils (0-30 cm), carried out in Puan County (Guizhou Province, China). The average concentrations of Al, Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn in the soil were 106 × 10³, 214, 20.9, 0.09, 0.12, 17.5, 121, 27.8, 131.2, and 64 mg·kg-1, respectively. The heavy metals' pollution indexes in the soil can be ranked as follows: Cu > Cr > Hg > As > Ni > Zn > Pb > Mn > Cd. The soil was moderately polluted by Cu because of the high geochemical background value of Cu in the area. The potential environment risk index (RI) showed that 7.69% out of the total sample sites were within the moderate level. Moreover, the ranges of Al, Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn concentrations in young tea leaves were 250-660, 194-1130, 0.107-0.400, 0.012-0.092, 0.014-0.085, 0.073-0.456, 0.33-1.26, 6.33-14.90, 14.90-26.10, and 35.8-50.3 mg·kg-1, respectively. While in mature tea leaves, they were 4300-10,400, 536-4610, 0.560-1.265, 0.040-0.087, 0.043-0.089, 0.189-0.453, 0.69-2.91, 3.43-14.20, 6.17-16.25, and 9.1-20.0 mg·kg-1, respectively. Furthermore, the concentrations of Pb, Cu, As, Hg, Cd, and Cr in young tea leaves and mature tea leaves were all lower than the standard limit values (5.0, 30, 2.0, 0.3, 1.0, and 5.0 mg·kg-1 for Pb, Cu, As, Hg, Cd, and Cr, respectively) in China. Besides, the accumulation ability of tea leaves to Mn was the strongest, and the average bioconcentration factor (BCF) of Mn in mature tea leaves was 12.5. In addition, the average target hazard quotients (THQ) were all less than one for the young tea leaves and the average aggregate risk hazard index (HI) to adults was 0.272, indicating that there was not a potential health risk for adults through the consumption of the infusions brewed by young tea leaves. However, for mature tea leaves, the percentage which HI values were above one was 38.46%, and the risk to adults via the consumption of mature tea infusions were mainly contributed by Mn and Al.

Recovery of metals from waste printed circuit boards by a mechanical method using a water medium.

Research on the recycling of waste printed circuit boards (PCB) is at the forefront of environmental pollution prevention and resource recycling. To effectively crush waste PCB and to solve the problem of secondary pollution from fugitive odors and dust created during the crushing process, a wet impacting crusher was employed to achieve comminution liberation of the PCB in a water medium. The function of water in the crushing process was analyzed. When using slippery hammerheads, a rotation speed of 1470 rpm, a water flow of 6m(3)/h and a sieve plate aperture of 2.2mm, 95.87% of the crushed product was sized less than 1mm. 94.30% of the metal was in this grade of product. Using smashed material graded -1mm for further research, a Falcon concentrator was used to recover the metal from the waste PCB. Engineering considerations were the liberation degree, the distribution ratio of the metal and a way to simplify the technology. The separation mechanism for fine particles of different densities in a Falcon concentrator was analyzed in detail and the separation process in the segregation and separation zones was deduced. Also, the magnitude of centrifugal acceleration, the back flow water pressure and the feed slurry concentration, any of which might affect separation results, were studied. A recovery model was established using Design-Expert software. Separating waste PCB, crushed to -1mm, with the Falcon separator gave a concentrated product graded 92.36% metal with a recovery of 97.05%. To do this the reverse water pressure was 0.05 MPa, the speed transducer frequency was set at 30 Hz and the feed density was 20 g/l. A flow diagram illustrating the new technique of wet impact crushing followed by separation with a Falcon concentrator is provided. The technique will prevent environmental pollution from waste PCB and allow the effective recovery of resources. Water was used as the medium throughout the whole process.