Advanced Packaging Techniques-A Mini-Review of 3D Printing Potential.

Packaging and packaging technology constitute a pivotal industry deeply intertwined with our daily lives and prevalent in various settings, including grocery stores, supermarkets, restaurants, and pharmacies. The industry is constantly evolving thanks to technological advances. This article delves into the dynamic landscape of 3D printing in packaging, exploring its profound implications and potential. While this article highlights the advantages of traditional packaging approaches, it also highlights the many benefits of 3D printing technology. It describes how 3D printing enables personalization, rapid prototyping, and low-cost production, streamlining packaging design and manufacturing processes. Offering innovative solutions in design, functionality, and accessibility, the potential of 3D printing in packaging is promising.

Innovative Cellular Insulation Barrier on the Basis of Voronoi Tessellation-Influence of Internal Structure Optimization on Thermal Performance.

The optimization of structure and thermal properties in 3D-printed insulation materials remains an underexplored area in the literature. This study aims to address this gap by investigating the impact of 3D printing on the thermal properties of manufactured cellular composites. The materials studied were closed-cell foams with a complex cell structure based on the Voronoi cell model, manufactured using incremental technology (3D printing). The influence of the cellular structure of the composite, the type of material used, and the number of layers in the composite structure on its thermal properties, i.e., thermal conductivity coefficient, thermal resistance, and coefficient of heat transfer, was analyzed. Samples of different types of thermosetting resins, characterized by different values of emissivity coefficient, were analyzed. It was shown that both the type of material, the number of layers of the composite, and the number of pores in its structure significantly affect its thermal insulating properties. Thermal conductivity and permeability depended on the number of layers and decreased up to 30% as the number of layers increased from one to four, while thermal resistance increased to 35%. The results indicate that material structure is key in regulating thermal conduction. Controlling the number of cells in a given volume of composite (and thus the size of the air cells) and the number of layers in the composite can be an effective tool in designing materials with high insulation performance. Among the prototype composites produced, the best thermal performance was that of the metalized four-layer cellular composites (λ = 0.035 ± 0.002 W/m·K, Rc = 1.15 ± 0.02 K·m2/W, U = 0.76 ± 0.01 W/m2·K).

Comparative Analysis of Crosslinking Methods and Their Impact on the Physicochemical Properties of SA/PVA Hydrogels.

Hydrogels, versatile materials used in various applications such as medicine, possess properties crucial for their specific applications, significantly influenced by their preparation methods. This study synthesized 18 different types of hydrogels using sodium alginate (SA) and two molecular weights of polyvinyl alcohol (PVA). Crosslinking agents such as aqueous solutions of calcium (Ca2+) and copper (Cu2+) ions and solutions of these ions in boric acid were utilized. The hydrogels were subjected to compression strength tests and drying kinetics analysis. Additionally, six hydrogel variants containing larger PVA particles underwent Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) post-drying. Some samples were lyophilized, and their surface morphology was examined using scanning electron microscopy (SEM). The results indicate that the choice of crosslinking method significantly impacts the physicochemical properties of the hydrogels. Crosslinking in solutions with higher concentrations of crosslinking ions enhanced mechanical properties and thermal stability. Conversely, using copper ions instead of calcium resulted in slower drying kinetics and reduced thermal stability. Notably, employing boric acid as a crosslinking agent for hydrogels containing heavier PVA molecules led to considerable improvements in mechanical properties and thermal stability.

Valorization of poultry slaughterhouse waste into fertilizers with designed properties.

Climate change, soil erosion, air and water pollution, or problems related to waste management are just some of the many problems in the modern world. Comprehensive solutions are sought to reduce the effects of progressive environmental degradation according to the assumptions of the concept of sustainable development. The paper presents a technological concept that may be a response to these problems. The presented solution assumes full utilization of slaughterhouse waste with the simultaneous recovery of nutrients and the production of functional fertilizing products with designed properties. Four liquid fertilizer formulations with the following composition were prepared: N - 2.30-3.64%, P2O5 - 2.18-9.66%, and K2O - 0.11-4.49%. The manufactured products were characterized by a high sulfur content and the addition of microelements. The tests carried out on plants confirmed their effectiveness similar to commercial mineral fertilizers. An increase in green matter yield of peas by 5 t/ha and maize by 2 t/ha was observed. The lack of microbiological risk associated with their use has been proven. Good efficiency with a simultaneous reduction in production costs resulting from the use of waste materials, as well as limiting the negative impact of poultry farms on the environment, make this solution an attractive alternative to mineral fertilizers, in line with the assumptions of the circular economy.

Three-Dimensional Printing of Multifunctional Composites: Fabrication, Applications, and Biodegradability Assessment.

Additive manufacturing, with its wide range of printable materials, and ability to minimize material usage, reduce labor costs, and minimize waste, has sparked a growing enthusiasm among researchers for the production of advanced multifunctional composites. This review evaluates recent reports on polymer composites used in 3D printing, and their printing techniques, with special emphasis on composites containing different types of additives (inorganic and biomass-derived) that support the structure of the prints. Possible applications for additive 3D printing have also been identified. The biodegradation potential of polymeric biocomposites was analyzed and possible pathways for testing in different environments (aqueous, soil, and compost) were identified, including different methods for evaluating the degree of degradation of samples. Guidelines for future research to ensure environmental safety were also identified.

Waste Valorization towards Industrial Products through Chemo- and Enzymatic- Hydrolysis.

This paper reviews the scientific literature on the latest technologies for treating waste by chemical hydrolysis, enzymatic hydrolysis and supporting processes. Particular attention is focused on wastes of biological origin, especially high-protein materials and those containing fats and sugars, as valuable components can be extracted from these recyclables to produce plant growth-stimulating compounds and animal feed, chemicals, biofuels or biopolymers. The wastes with the greatest potential were identified and the legislative regulations related to their processing were discussed. Chemical and enzymatic hydrolysis were compared and their main applications directions and important process parameters were indicated, as well as the need to optimize them in order to increase the efficiency of extraction of valuable components.

Maximizing the potential of leachate from sewage sludge as a sustainable nutrients source to alleviate the fertilizer crisis.

Leachate from separate digesters in biological wastewater treatment plants contains valuable biogenic compounds that can serve as fertilizer nutrients. In this study, a method was developed to utilize leachate from sewage sludge dewatering as a raw material for the preparation of a plant conditioner, providing water, nutrients, and growth-stimulating amino acids. A chemical conditioning procedure (65% HNO3) was used to prepare the leachate solution for fertilization. The feasibility of producing an amino acid-based fertilizer using shrimp shells and inorganic acids (96% H2SO4 and 85% H3PO4) was also demonstrated. Microbiological analysis confirmed the safety of the formulations, and chelation of micronutrients with available amino acids was proven (up to 100% chelating degree). The bioavailability of all nutrients was confirmed through extraction tests (extraction in neutral ammonium citrate). Germination tests showed similar fresh plant masses to those with commercial preparations, demonstrating the effectiveness of the developed technology. This approach aligns with circular economy principles and sustainable development and contributes to mitigating the impacts of climate change.

Tannery waste as a renewable source of nitrogen for production of multicomponent fertilizers with biostimulating properties.

The studies presented in this work show that solid tannery waste-like shavings can be used as high-protein materials for fertilizer production following the concept of the circular economy. To select appropriate process parameters (mass ratio of shavings meal to the hydrolyzing agent (S:L), hydrolysis medium concentration, temperature) and to ensure the highest possible hydrolysis efficiency, it is useful to apply the well-known response surface methodology (RSM). The analyses revealed that chromium shavings (SCr) were most preferably treated with 10% KOH in a ratio of S:L 1:1 with the process being carried out at 160 °C (6.59% N). The optimal hydrolysis conditions for non-chromium (S) shavings were: S:L ratio 1:2, 10% H2SO4, and temperature 160 °C (4.08% N). Chromium concentrations in hydrolysates from S and SCr shavings obtained under optimal conditions were 15.2 mg/kg and 9483 mg/kg, respectively. Hydrolysate samples were analyzed by reversed-phase high-pressure liquid chromatography (RP-HPLC) that revealed that the type of hydrolysis (acidic/alkaline) affects the amino acid profile. Approximately 4.5 times more amino acids were extracted in the KOH environment than during acidic treatment. The hydrolysates contained mainly glycine, alanine, and proline, which are primarily responsible for stimulating plant growth by supporting chlorophyll synthesis, chelating micronutrients, improving pollen fertility, or resistance to low temperatures. The conversion of tannery waste into fertilizer requires the control of contaminant levels, especially chromium, which can oxidize to the carcinogenic form Cr(VI) that is hazardous to humans and the environment.

Processing of nuisance animal waste into agricultural products.

A technological solution was developed to process slaughter waste and farm manure and transform them into organic and mineral fertilizers. It has been shown that the formation of an enclosure on a goose farm from nitrogen-binding substances (brown coal, a mixture of brown coal with magnesite, used ash substrate) has a positive effect on reducing nitrogen emissions, even to about 80%. The presented solution is in line with ecological trends and ensures comprehensive management of agri-food waste. It reduces the loss of valuable nutrients from renewable sources, increases the efficiency of fertilizers and reduces the environmental nuisance of poultry farms. Organic-mineral fertilizers made from slaughterhouse waste and poultry manure were as effective as expensive commercial mineral fertilizers. New fertilizers helped to obtain a yield similar to the groups fertilized with mineral fertilizers: 11 t per ha for maize (grain), 0.8 t per ha for mustard (seed), 10 kg per 1 m2 of radish (all), and 18.5 kg per 1 m2 of beet (whole) while reducing production costs thanks to the use of waste materials.

Management of biological sewage sludge: Fertilizer nitrogen recovery as the solution to fertilizer crisis.

In the current situation of a serious raw material crisis related to the disruption of supply chains, the bioeconomy is of particular significance. Rising prices and the problem with the availability of natural gas have made N fertilizers production very expensive. It is expected that due to natural gas shortages, conventional production of nitrogen fertilizers by chemical synthesis will be hindered in the coming season. An important alternative and an opportunity to solve the problems of fertilizer nitrogen availability are biological wastewater treatment plants, which can be treated as a renewable biological nitrogen mines. Sewage sludge (including activated sludge) contains up to 6-8% DM. N. Considering the quantity of sewage sludge generated in wastewater treatment plants, it can become an important raw material for the sustainable production of organic-mineral fertilizers from renewable resources available locally, with a low carbon footprint. Furthermore, the sewage sludge management method should take nitrogen retention into account and should not allow the emission of greenhouse gases containing nitrogen. This article analyzes the technological solutions of nitrogen recovery for fertilization purposes from biological wastewater treatment plants in the context of a new and difficult resource situation. Conventional and new nitrogen recovery methods were analyzed from the perspective of the current legal situation. An attempt was made to evaluate the possibility of implementing the assumptions of the circular economy through the recovery of renewable nitrogen resources from municipal wastewater treatment plants.

Innovative bio-waste-based multilayer hydrogel fertilizers as a new solution for precision agriculture.

The aim of the research work was to present a multilayer hydrogel capsule with controlled nutrient release properties as an innovative fertilizer designed for sustainable agriculture. Preparation of the capsules included the following steps: sorption of micronutrients (Cu, Mn, Zn) on eggshells (1) and their immobilization in sodium alginate, with the crosslinking agent being the NPK solution (2). The capsules were coated with an additional layer of a mixture of biopolymers (0.79% alginate, 0.24% carboxymethylcellulose and 8.07% starch)by means of dipping and spraying techniques. The biocomposites were characterized by limited (<10% within 100 h for the structures encapsulated by the dipping method) release of fertilizer ions (except for small K+ ions). The hydrogel fertilizer formulations were analyzed for physicochemical properties such as macro- and micronutrient content, surface morphology analysis, coating structure evaluation, mechanical properties, swelling and drying kinetics. High nutrient bioavailability was confirmed in vitro (extraction in water and neutral ammonium citrate). Germination and pot tests have revealed that the application of multicomponent hydrogel fertilizers increases the length of cucumber roots by 20%, compared to the commercial product.

Recent innovations in various methods of harmful gases conversion and its mechanism in poultry farms.

Poultry breeding takes place in intensive, high-production systems characterized by high animal density, which is a source of harmful emission of odorous volatile organic compounds (VOCs), ammonia (NH3), hydrogen sulfide (H2S) and greenhouse gases, which in turn sustain animal welfare. This study identified and examined the characteristics of chemical compounds emitted in intensive poultry farming (laying hens, broilers) and their toxicity, which led to recommending methods of deodorization. Emphasis was placed on the law relative to air purification in poultry farms. Various methods of air treatment in poultry farms have been described: the modification of animal diet to improve nutrient retention and decrease the amount of their excrement; chemical oxidation technologies (ozonation, photocatalysis, Fenton reaction); various types/brands of biofilters, bioscrubbers and membrane reactors. Numerous studies show that biofilters can reduce ammonia emissions by 51%, hydrogen sulfide by 80%, odors by 67%, while scrubbers brings down ammonia emissions by 77% and odors by 42%, and the application of UV light lowers ammonia emissions by 28%, hydrogen sulfide by 55%, odors by 69% and VOCs by 52%. The paper presents both the solutions currently used in poultry farming and those which are currently in the research and development phase and, as innovative solutions, could be implemented in the near future.

From hazardous waste to fertilizer: Recovery of high-value metals from smelter slags.

This work proposes a method to valorize lead slag for fertilizer purposes. The research concept was to selectively recover valuable microelements (Cu(II), Fe(II), Zn(II) in an amount of at least 0.2% m/v of each) by chemical leaching while retaining toxic elements in the slag (i.e. As and Pb). Among acids, hydroxides, salts and their mixtures tested for slag treatment, it was potassium hydrogen sulfate and ammonia liquor under strongly oxidizing conditions (in the presence of hydrogen peroxide) that proved to be the most effective leaching agents. Response Surface Methodology applied to optimize the slag leaching conditions set the most favorable process parameters (concentration of leaching agents, slag to reagent weight ratio, and temperature). As a result, the concentration of Cu(II) in the extract was 3751 mg/L (for ammonia liquor) and Fe(II) and Zn(II) concentrations in potassium hydrogen sulfate were 4738 mg/L and 6102 mg/L, respectively. To close the life cycle of the waste, immobilization in polyethylene and binding to cement were indicated as methods to manage the solid waste material after leaching. The mixed extracts rich in Cu(II), Fe(II) and Zn(II) ions were tested in germination tests on cucumber. No phytotoxic effect was observed, which raises the possibility of utilizing the solutions after chemical leaching of slag as an alternative source of micronutrients for the production of multicomponent fertilizers. The results are promising and fit in the assumptions of circular economy.

Biochar in environmental friendly fertilizers - Prospects of development products and technologies.

According to the circular economy concept, the production of fertilizers should be closed in a loop, which prevents excessive emissions and harmful effects to the environment. Biological wastes are problematic to collect and transport. They undergo a biological transformation that causes greenhouse gases emission and sanitary hazards. Biomass sources used for organic or organo-mineral fertilizers must be free of pathogens and rich in macro and microelements. Solid residues can be processed thermally. Biochar is a carbon produced by biomass pyrolysis without oxygen presence and has been used for many years to improve soil quality and enhance the efficiency of fertilization. There are many research works on the use of biochar in fertilization. This study is also extended by the latest developments and technologies from the patent database (recent year) and biochar-based fertilizers market. To the best of our knowledge, there is no such review currently available in scientific databases. Based on the collected data, the best method of biochar management was proposed - soil application. Biochar applied to soil has several advantages: it improves soil structure and its sorption capacity, enhances soil-nutrient retention and water-holding capacity, immobilizes contaminants from soil (sorption), reduces greenhouse gas emissions and soil nutrient leaching losses while stimulating the growth of a plant.

Biodegradation of pharmaceuticals in photobioreactors - a systematic literature review.

This work is a systematic review that reports state-of-the-art in removal of pharmaceuticals from water and wastewater by photosynthetic organisms in photobioreactors. The PRISMA protocol-based review of the most recent literature data from the last 10 years (2011-2021) was reported. Articles were searched by the combination of the following keywords: photobioreactor, pharmaceuticals, drugs, hormones, antibiotics, biodegradation, removal, wastewater treatment. The review focuses on original research papers (not reviews), collected in 3 scientific databases: Scopus, Web of Knowledge, PubMed. The review considered the following factors: type of microorganisms, type of micropollutants removed, degradation efficiency and associated products, types of photosynthetic organisms and photobioreactor types. The conclusion from the systematic review is that the main factors that limit widespread pharmaceuticals removal in photobioreactors are high costs and the problem of low efficiency related with low concentrations of pharmaceuticals. The review indicated a need for further research in this area due to increasing amounts of metabolites in the food chain, such as p-aminophenol and estrone, which can cause harm to people and ichthyofauna. Pharmaceuticals removal can be improved by adapting the type of microorganism used to the type of contamination and implementing photoperiods, which increase the removal efficiency of e.g. sulfamethazine by up to 28%. In the future, it is necessary to search for new solutions in terms of the construction of photobioreactors, as well as for more effective species in terms of pharmaceuticals biodegradation that can survive the competition with other strains during water and wastewater treatment.

The challenges and perspectives for anaerobic digestion of animal waste and fertilizer application of the digestate.

The increase in livestock production creates a serious problem of managing animal waste and by-products. Among the wide range of waste valorization methods available, anaerobic digestion is very promising. It is a form of material recycling that also produces renewable energy in the form of biogas, which is reminiscent of energy recycling. The effluent and digestate from the anaerobic digestion process need to be processed further. These materials are widely used in agriculture due to their composition. Both the liquid and solid fractions of digestate are high in nitrogen, making them a valuable source for plants. Before soil or foliar application, conditioning (e.g., with inorganic acids) and neutralization (e.g., with potassium hydroxide) is required to eliminate odorous compounds and microorganisms. Various methods of conducting the process by anaerobic digestion (use of additives increasing activity of microorganisms, co-digestion, multiple techniques of substrate preparation) and the possibility of controlling process parameters such as optimal C/N ratio (15-30), optimal temperature (psychrophilic (<20 °C), mesophilic (35-37 °C) and thermophilic (55 °C) for microorganism activity ensure high efficiency of the process. Literature data describing tests of various digestates on different plants prove high efficiency, determined by yield increase (even by 28%), nitrogen uptake (by 20%) or phosphorus recovery rate (by 43%) or increase of biometric parameters (e.g., leaf area).

Tannery waste-derived biochar as a carrier of micronutrients essential to plants.

The leather tannery industry generates about 33 Mt/year of solid waste with different properties, turning its management into a challenge. One of the valorization methods of tannery wastes is the production of biochar by pyrolysis of leather scratches. Biochar's sorption properties and its high nitrogen content (10%) make it suitable for its application as a soil conditioner or carrier of microelements for fertilizers. The paper presents an innovative spray method to enrich biochar with cationic micronutrients: Cu, Mn, Zn. Enriched biochar contained 1095 mg/kg Cu(II), 1334 mg/kg Mn(II) and 1205 mg/kg Zn(II). The high bioavailability of nutrients and the effectiveness of the new fertilizer were demonstrated in extraction in vitro tests - the analysis of leachability of elements to water and bioavailability of micro-nutrients. The functional properties of enriched biochar were examined in vivo (germination, pot) tests. A high biomass increase (approximately 10%) was observed compared to the group fertilized with a commercial product. The proposed solution benefits the environment in that it is made from alternative resources from which innovative fertilizers are produced according to the circular economy concept.

Valorization of poultry slaughterhouse waste for fertilizer purposes as an alternative for thermal utilization methods.

Slaughterhouse waste and dead animals are mainly disposed of by incineration, which generates greenhouse gases and NOx. These wastes are a source of nutrients that can be recovered by circular economy techniques if material recycling is given a priority over energy recovery. To valorize high-protein animal waste (containing bones, meat, feather) for fertilizer purposes, the waste was processed by acid solubilization and neutralized with potassium hydroxide solution, which yielded a liquid fertilizer with plant growth biostimulating properties (due to the amino acids presence). The composition analysis showed that new fertilizers met all quality requirements set by the law, contain ~0.5% m/m amino acids and are microbiologically pure. The fertilizer was enriched with microelements to the level of 0.2% m/m and tested for biological effectiveness in germination tests and field studies. Compared with the commercial formulation, the fertilizer increased stem length and chlorophyll content (by 8.2% and 27.0%, respectively), wheat crop yield and grain micronutrients density (Cu by 31.2%, Mn by 10.5%, Zn by 33.9%) and improved the wheat flour baking properties. The described solution propose a safe way to utilize hazardous waste via technological mobile installation, enabling no transportation of waste, which is an important aspect of sanitary-epidemiological risk minimization.

Phosphorus recovery from wastewater and bio-based waste: an overview.

Phosphorus is one of the most important macronutrients needed for the growth of plants. The fertilizer production market uses 80% of natural, non-renewable phosphorus resources in the form of phosphate rock. The depletion of those deposits forces a search for other alternatives, including biological waste. This review aims to indicate the most important ways to recover phosphorus from biowaste, with particular emphasis on wastewater, sewage sludge, manure, slaughter or food waste. A comparison of utilized methods and directions for future research based on the latest research is presented. Combining biological, chemical, and physical methods with thermal treatment appears to be the most effective way for the treatment of wastewater sludge in terms of phosphorus recovery. Hydrothermal, thermochemical, and adsorption on thermally treated adsorbents are characterized by a high phosphorus recovery rate (over 95%). For animal by-products and other biological waste, chemical methods seems to be the most optimal solution with a recovery rate over 96%. Due to its large volume and relatively low phosphorus content, wastewater is a resource that requires additional treatment to recover the highest possible amount of phosphorus. Pretreatment of wastewater with combined methods seems to be a possible way to improve phosphorus recovery. A compressive evaluation of combined methods is crucial for future research in this area.

Hydrogel Alginate Seed Coating as an Innovative Method for Delivering Nutrients at the Early Stages of Plant Growth.

Seed coating containing fertilizer nutrients and plant growth biostimulants is an innovative technique for precision agriculture. Nutrient delivery can also be conducted through multilayer seed coating. For this purpose, sodium alginate with NPK, which was selected in a preliminary selection study, crosslinked with divalent ions (Cu(II), Mn(II), Zn(II)) as a source of fertilizer micronutrients, was used to produce seed coating. The seeds were additionally coated with a solution containing amino acids derived from high-protein material. Amino acids can be obtained by alkaline hydrolysis of mealworm larvae (Gly 71.2 ± 0.6 mM, Glu 55.8 ± 1.3 mM, Pro 48.8 ± 1.5 mM, Ser 31.4 ± 1.5 mM). The formulations were applied in different doses per 100 g of seeds: 35 mL, 70 mL, 105 mL, and 140 mL. SEM-EDX surface analysis showed that 70 mL of formulation/100 g of seeds formed a continuity of coatings but did not result in a uniform distribution of components on the surface. Extraction tests proved simultaneous low leaching of nutrients into water (max. 10%), showing a slow release pattern. There occurred high bioavailability of fertilizer nutrients (even up to 100%). Pot tests on cucumbers (Cornichon de Paris) confirmed the new method's effectiveness, yielding a 50% higher fresh sprout weight and four times greater root length than uncoated seeds. Seed coating with hydrogel has a high potential for commercial application, stimulating the early growth of plants and thus leading to higher crop yields.