ABSTRACT
The CO2 released upon calcination of limestone accounts for the largest portion of the emissions from the cement, lime, and slaked lime manufacturing industries. Our previous works highlighted the possibility for a no-combustion decarbonisation of CaCO3 through reaction with NaOH solutions to produce Ca(OH)2 at ambient conditions, while sequestrating the process CO2 in a stable mineral Na2CO3·H2O/Na2CO3. In this study, the effect of temperature was assessed within the range of 45-80 °C, suggesting that the process is robust and only slightly sensitive to temperature fluctuations. The proportioning of the precipitated phases Na2CO3·H2O/Na2CO3 was also assessed at increasing NaOH molalities and temperatures, with the activity of water playing a crucial role in phase equilibrium. The activation energy (E a) of different CaCO3 : NaOH : H2O systems was assessed between 7.8 kJ·mol-1 and 32.1 kJ·mol-1, which is much lower than the conventional calcination route. A preliminary energy balance revealed that the chemical decarbonisation route might be â¼4 times less intensive with respect to the thermal one. The present work offers a further understanding of the effect of temperature on the process with the potential to minimise the emissions from several energy-intensive manufacturing processes, and correctly assess eventual industrial applicability.
ABSTRACT
Decarbonizing calcium carbonate (CaCO3) is a crucial step for a wide range of major industrial processes and materials, including Portland cement (PC) production. Apart from the carbon footprint linked to fuel combustion, the process CO2 embodied within CaCO3 represents the main concern for the sustainability of production. Our recent works demonstrated that it is possible to avoid both the fuel and process CO2 by reacting CaCO3 with aqueous NaOH and obtain Ca(OH)2 and Na2CO3·xH2O (x = 0 and 1). This present study provides a further understanding of the process by testing different raw calcareous sources. A high decarbonization (â¼80%) of CaCO3 was achieved for silica-rich chalk, whereas a lower extent was obtained (â¼50%) for limestone. To understand the difference in their reaction behavior, the effect of impurities was studied. The effects of the major impurities (Si, Al, and Fe) were found to be marginal, which is advantageous to process industrial grade materials, while the morphology of the raw materials presents a significant impact. The applicability of our decarbonization technology was also demonstrated on magnesite (MgCO3).
ABSTRACT
The decarbonisation of CaCO3 is essential for the production of lime (Ca(OH)2 and CaO), which is a commodity required in several large industries and the main precursor for cement production. CaCO3 is usually decarbonised at high temperatures, generating gaseous CO2 which will require post-process capture to minimise its release into the environment. We have developed a new process that can decarbonise CaCO3 under ambient conditions, while sequestering the CO2 as Na2CO3·H2O or Na2CO3 in the same stage. Here, the effects of increasing stirring rates and residence times on reaction efficiency of the key reaction occurring between CaCO3 and NaOH solution are studied. It is shown that the reaction is enhanced at lower stirring rates and longer residence times up to 300 seconds of contact between the reactants. The mass balance performed for Ca and CO2 revealed that up to the 95% of the process CO2 embodied in CaCO3 was sequestered, with maximum capture rate assessed at nn moles CO2 captured per second of reaction progress. A deeper insight into the precipitation of Na2CO3·H2O or Na2CO3 under different reaction conditions was gained, and SEM-EDX analysis enabled the observation of the reaction front by detection of Na migrating towards inner regions of partially-reacted limestone chalk particles.